PRACTICE PROBLEMS UNIT 11 - 11A. Provide IUPAC names for
PRACTICE PROBLEMS UNIT 11. 11A. Provide IUPAC names for ethers. 11A.1 Name the following compounds a) b) c) propoxy cyclopentane. -O 2-ethoxy propane. (ethyl
Chapter 3 Alcohols Phenols
https://www.angelo.edu/faculty/kboudrea/index_2353/Chapter_03_2SPP.pdf
Basic IUPAC Nomenclature V
Simple ethers may be given common names as alkyl alkyl ethers where the Practice Alcohol and Ether Nomenclature Key: Compound A: 3-methyl-4-heptanol.
Chem 124 PAL Worksheet Alcohols Ethers Phenols Page 1 Write
2. Write the structure for each IUPAC name. a. (R)-Butane-12
ETHERS WORKSHEET
ETHERS WORKSHEET. 1. Give the correct name either IUPAC or common
Organic Chemistry 2 Week 3 9/7/2022 Sebastian Alberti TOPIC OF
Sep 7 2022 Naming Ethers: Ethers are special in that they can be named in two ... PRACTICE PROBLEMS! Provide an efficient synthesis for this reaction ...
Ethers-Worksheet-Key.pdf
ETHERS WORKSHEET KEY. 1. Names: a. methoxyethane b. 2-methoxybutane c. ethoxybenzene d. 3-ethoxy-5-chlorohexane e. 34-diethoxy-6- methylheptane f
Chapter 5 Carboxylic Acids and Esters
The boiling points of carboxylic acids compared to 1° alcohols aldehydes and ketones
Alcohols & Ethers Worksheet Name: Part A The focus of this chapter
Alcohols & Ethers Worksheet. Name: Part A. The focus of this chapter can be Read the section 11.1B about naming ethers – I have a little to add. For a ...
Chapter 3 Alcohols Phenols
https://www.angelo.edu/faculty/kboudrea/index_2353/Chapter_03_2SPP.pdf
Naming Ethers and Thiols (Naming and Properties)
Cyclic ethers (heterocyclic compounds) are often given common names. The IUPAC nomenclature system adds the ending –thiol to the name of the alkane ...
14.1 Introduction to Ethers 14.1 Introduction to Ethers 14.2 Naming
Practice with CONCEPTUAL CHECKPOINT 14.4. 14.4 Crown Ethers. Copyright 2012 John Wiley & Sons Inc. Klein
Chem 124 PAL Worksheet Alcohols Ethers Phenols Page 1 Write
2. Write the structure for each IUPAC name. a. (R)-Butane-12
Alcohols Phenols and Ethers
name alcohols phenols and ethers according to the IUPAC system of nomenclature;. • discuss the reactions involved in the preparation of alcohols from.
CBSE NCERT Solutions for Class 12 Chemistry Chapter 11
Practice more on Alcohols Phenols and Ethers Name the following compounds according to IUPAC system. ... IUPAC name: 2
Basic IUPAC Nomenclature V
Alcohols and Ethers. Alcohols: In IUPAC ethers are named as alkoxy- substituents with the smaller side ... Practice Alcohol and Ether Nomenclature:.
O-Chem II_Week 4
13-Sept-2021 In these sessions I will provide practice problems and be available for specific ... Nomenclature: There are 2 ways to name Ethers.
leep511.pdf
155 Alcohols Phenols and Ethers. 23/04/18 Name the factors responsible for the solubility of alcohols in water. 26. What is denatured alcohol?
GRE Chemistry Test Practice Book
If you need additional accessible practice material for the GRE Chemistry Test contact ETS Disability alcohols
[PDF] ETHERS WORKSHEET
ETHERS WORKSHEET 1 Give the correct name either IUPAC or common to each of the following ethers: a b c (hint: alkoxy group takes priority over
[PDF] Basic IUPAC Nomenclature V
In IUPAC ethers are named as alkoxy- substituents with the smaller side being the substituent and the larger side being the main chain As substituents they
Worksheets On Naming Ethers PDF - Scribd
Ethers Worksheet Print this worksheet and give it a try! Answers For the following molecules give the correct name Good luck! 1) 2) CH
[PDF] chem-124-pal-worksheet-alcohols-ethers-phenolspdf
Chem 124 PAL Worksheet Alcohols Ethers Phenols Page 1 Write out the answers on separate sheets of paper 1 Give the IUPAC name for the following
[PDF] Naming ethers worksheet with answers pdf - Squarespace
Naming compounds worksheet answer key pdf How to name ethers Naming ethers practice with answers Ethers are named by both common and systematic nomenclature
[PDF] Naming and drawing ethers worksheet with answers - Squarespace
Russell Print the PDF: Simple Interest Worksheet No 1 In this exercise students will answer 10 word problems about calculating interest These exercises will
[PDF] Alcohols & Ethers Worksheet Name: Part A
Read the section 11 1B about naming ethers – I have a little to add For a complicated ether we can look at the two R groups and choose the parent by selected
[PDF] PRACTICE PROBLEMS UNIT 11
following ether using the Williamson ether synthesis a) Any halide is ok Br e)
[PDF] Chapter 3 Alcohols Phenols and Ethers - Angelo State University
Chapter Objectives: • Learn to recognize the alcohol phenol and ether functional groups • Learn the IUPAC system for naming alcohols phenols
[PDF] Chapter 11 Alcohols and Ethers t Nomenclature:
l Nomenclature of Alcohols (Given in Chapter 4) IUPAC §Ethers are named as having an alkoxyl substituent on the PDF Creator - PDF4Free v2 0
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -1
O14.1IntroductiontoEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -2
•Commonnamesareusedfrequently:1.Nameeach-Rgroup.
2.Arrangethemalphabetically.
3.Endwiththeword"ether."
14.2NamingEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -3
14.2NamingEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -4•Namethefollowingmolecule.14.2NamingEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -5
waterandinalcohols. •Istheoxygenatominanethersp 3 ,sp 2 ,orsp hybridized?14.3StructureandPropertiesof
Ethers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -6
boilingpoints. canhave? ether canhave?14.3StructureandPropertiesof
Ethers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -7
boilingpoints. elevatedsimilartoalcohols? •WHYorWHYnot?14.3StructureandPropertiesof
Ethers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -8
intermolecularattractions. -Trend1: -Trend2:14.3StructureandPropertiesof
Ethers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -9
afterthereactioniscomplete. partiallychargedtransitionstates.HOW? inmanyreactions?14.3StructureandPropertiesof
Ethers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -10
stabilizedbyethersolvents. reactions. •Giveanotherreasonwhyanethermakesa goodsolventinthisreaction.14.4CrownEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -11
strongattractionstometalatoms.WHY? •WhyaretheycalledCROWNethers?14.4CrownEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -12
toformastrongattraction. •18ͲcrownͲ6fitsaK ionjustright.14.4CrownEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -13
solvents.WHY? inlowpolaritysolvents.WHY? polarityorganic substrates.14.4CrownEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -14
•TheF ionbelowisreadytoreactbecausetheK ionis sequesteredbythecrownether. isminiscule.14.4CrownEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -15
•Generally,theF ionisnotusedasanucleophile solvent,theF ionissolubleenoughthatitcanreadily attackanelectrophile.14.4CrownEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -16
14.4CrownEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -17
catalyzeddehydrationofethanol. •Howisitadehydration?14.5PreparationofEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -18
manyasymmetricalethers. •Whathappenstothehalide?14.5PreparationofEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -19
manyasymmetricalethers. secondary,ortertiaryalkylhalides?14.5PreparationofEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -20
themethylside.WHY? •PracticewithSKILLBUILDER14.2.14.5PreparationofEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -21
followingmolecule.14.5PreparationofEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -22
•Istheadditionsynoranti?14.5PreparationofEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -23
usedtosynthesizeethers. •Istheadditionsynoranti?14.5PreparationofEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -24
ethersaregenerallyunreactive. •Considertheetherbelow. •Wherearethemostreactivesites? nucleophile,electrophile,etc.?14.6ReactionsofEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -25
14.6ReactionsofEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -26
forthefollowingacidͲpromotedcleavage.14.6ReactionsofEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -27
effective. cleavage. strengthofthehalidenucleophiles. thanacidͲcatalyzed?14.6ReactionsofEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -28
completemechanism.14.6ReactionsofEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -29
autooxidation. hydroperoxidesbeforetheyareused. mechanism.14.6ReactionsofEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -30
14.6ReactionsofEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -31
propagationsteps:14.6ReactionsofEthers
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -32
parentnameofthemolecule. •Oxiranesarealsoknownasepoxides. reactive?WHY?14.7NamingEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -33
•Anepoxidecanhaveupto4-Rgroups. commonlyinnature.14.7NamingEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -34
givenasitslocants.2.Oxiraneisusedastheparentname.
14.7NamingEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -35
14.7NamingEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -36
whenanalkeneistreatedwithaperoxyacid.14.8PreparationofEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -37
14.8PreparationofEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -38
•Whatisahalohydrin? reactioncanoccur.14.8PreparationofEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -39
14.8PreparationofEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -40
•PracticewithSKILLBUILDER14.3.14.8PreparationofEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -41
NOTenantioselective.
•Drawtheproducts.14.9EnantioselectiveEpoxidation
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -42
flatalkenecanreactoneitherface.14.9EnantioselectiveEpoxidation
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -43
thecatalyst)inareactionmustbechiral. anallylicalcohol.14.9EnantioselectiveEpoxidation
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -44
ischosen.Notethepositionofthe-OHgroup. •PracticewithCONCEPTUALCHECKPOINT14.16.
14.9EnantioselectiveEpoxidation
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -45
greatsyntheticutilityasintermediates. epoxidetoalterthecarbonskeleton.14.10RingͲopeningofEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -46
favored,andexplainWHY.14.10RingͲopeningofEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -47
potentialenergymakingitmorereactive.14.10RingͲopeningofEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -48
thermodynamicallyfavored.WHY?14.10RingͲopeningofEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -49
nucleophilesaswell. considered.14.10RingͲopeningofEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -50
N2,predictthe
outcomeofthefollowingreactions. WHY. •PracticewithSKILLBUILDER14.4.14.10RingͲopeningofEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -51
O14.10RingͲopeningofEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -52
underacidicconditions. •Antifreeze(ethyleneglycol)ismade industriallybythismethod.14.10RingͲopeningofEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -53
observations.14.10RingͲopeningofEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -54
S N 1orS N 2? likelyS N 1orS N 2?14.10RingͲopeningofEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -55
•Whenthenucleophileattacksatertiary centeroftheepoxide,theintermediateit attackstakesonsomecarbocationcharacter (S N1),butnotcompletely.
•PracticewithSKILLBUILDER14.5.14.10RingͲopeningofEpoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -56
the-OHgroupinalcohols. "thiol" ratherthan"ol." •Notethatthe"e" ofbutaneisnotdroppedin thenameof thethiol.14.11ThiolsandSulfides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -57
•Thiolsarealsoknownasmercaptans. groupratherthanaspartoftheparentchain. complexmercury. mercurypoisoning.WHY?Draw itsstructure.14.11ThiolsandSulfides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -58
gasleakscanbedetected. •Thehydrosulfideion(HS )isastrongnucleophileanda weakbase. •HS promotesS N2ratherthanE2.
14.11ThiolsandSulfides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -59
drawacompletemechanism.14.11ThiolsandSulfides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -60
•ThiolshaveapK a ofabout10.5. •RecallthatwaterhasapK a of15.7. productsorreactantsanddrawthemechanism. •Thiolatesareexcellentnucleophiles.14.11ThiolsandSulfides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -61
thiolate ion •Onceathiolateforms,itcanattackBr 2 toproducea disulfide. •Howdoestheoxidationnumberchange?14.11ThiolsandSulfides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -62
Proposeamechanism.
about53kcal/mol.WHYisthatsignificant?14.11ThiolsandSulfides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -63
THIOETHERS.
14.11ThiolsandSulfides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -64
athiolateonanalkylhalide. •Howarethiolatesgenerallyprepared?14.11ThiolsandSulfides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -65
•Sulfidesundergoanumberofreactions:1.Attackonanalkylhalide:
addanalkylgrouptoavarietyofnucleophiles.14.11ThiolsandSulfides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -66
•Sulfidesundergoanumberofreactions:2.Sulfidescanalsobeoxidized.
14.11ThiolsandSulfides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -67
•Sulfidesundergoanumberofreactions:2.Sulfidescanalsobeoxidized.
14.11ThiolsandSulfides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -68
character. contributor,andWHY?14.11ThiolsandSulfides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -69
reducingagents.14.11ThiolsandSulfides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -70
reactionsequencebelow. productabove.14.11ThiolsandSulfides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -71
Br HS1) NaOH
2) adjacentcarbons. •PracticewithSKILLBUILDER14.6.14.12SyntheticStrategiesInvolving
Epoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -72
carbonskeletoncanbemodified.14.12SyntheticStrategiesInvolving
Epoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -73
•Recallthatacarbonylcanbe usedtoinstallaonecarbon chainbetweenanRgroupand anOHgroup. betweenanRgroupandanOHgroup.14.12SyntheticStrategiesInvolving
Epoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -74
•PracticewithSKILLBUILDER14.7.14.12SyntheticStrategiesInvolving
Epoxides
Copyright2012JohnWiley&Sons,Inc.
Klein, Organic Chemistry 1e14 -75
quotesdbs_dbs14.pdfusesText_20[PDF] naming of aldehydes and ketones pdf
[PDF] naming organic compounds worksheet with answers pdf
[PDF] nanaimo bc obituaries archives
[PDF] naoh hydrolysis of amides
[PDF] naoh hydrolysis of ester
[PDF] napoleonic code vs common law
[PDF] napso valuepoint
[PDF] naresh technologies advanced java material pdf
[PDF] narrated powerpoint presentation example
[PDF] narrow band to 1/3 octave matlab
[PDF] narrow band vs 1/3 octave
[PDF] nascent delta function
[PDF] nashua nh assessor
[PDF] nashua nh assessor database