[PDF] organocopper allylic substitution

What are organocopper compounds?

The most widely used organocopper compounds are the lithium diorganocuprates, which are prepared by the reaction between organolithium reagents (RLi) and copper (I) halides (CuX); for example, ArLi gives Ar 2 CuLi. The copper (I) salt is normally the iodide or bromide.

What are the organic substituents of organosilanes?

Most of the widely used organosilanes have one organic substituent and three hydrolyzable substituents . In the vast majority of surface treatment applications, the alkoxy groups of the trialkoxysilanes are hydrolyzed to form silanol-containing species . Reaction of these silanes involves four steps .

Is organo-copper effective against algae?

This unique organo-copper complex is effective against most common algae and safe for all pool surfaces. There are over 30,000 species of algae. Some algae, like blue-green algae, float in the water while others, like mustard algae and black algae, cling to the surface and thrive in cracks and crevices.

What are allylic couplings in organic chemistry?

HH ) couplings between hydrogens on carbon atoms ? to the double! bond and hydrogens at the opposite end of the double bond called allylic couplings! • 3Apparently, orbital overlap between the ? orbital of the double bond and the hybrid sp-C-H! orbital enable the nuclear interactions that result in the coupling!