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Properties of solutions that depend on the number of molecules present and not on the kind ofmolecules are called colligative properties These properties include boiling point elevation freezingpoint depression and osmotic pressure Historically colligative properties have been one meansfor determining the molecular weight of unknown compounds



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Many salts and solutes will change the properties of the solvent in which they are dissolved This phenomenon is called colligative properties of a solution Most often colligative properties take the form of lowering the freezing point of the solvent or raising the boiling point of the solvent



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Colligative property 1: Vapor pressure depression ?P = P0? mole fraction which is the amount of solute added depression constant which is the vapor pressure of pure solvent at a given T of pure solvent in vapor pressure For H 2O at 25 oC the pure vapor pressure is 23 8 torr



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Colligative Properties Solutions! CHEM 102! T Hughbanks! Colligative Properties! Depend solely on relative numbers of solvent and solute molecules in solutions not on their chemical identity ! The speci?cs of intermolecular interactions are not important for determining these properties! Typical examples:!



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Colligative Properties of Solutions Liquids solutions experience the following four colligative properties: • Vapor Pressure Reduction • Boiling Point Elevation • Freezing Point Depression and • Osmotic Pressure over that of the pure solvent © 2010 High School Chem Solutions All rights reserved Vapor Pressure Reduction Pure Solvent



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COLLIGATIVE PROPERTIES OF SOLUTIONS July 15 2004 3 solvent freezes (or boils) Notwithstanding throughout this and the subsequent paper we will adopt the language of salted water and refer to the solid phase of the solvent as ice to the liquid phase as liquid-water and to the solute as salt 1 2 General Hamiltonian

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