preparation of alcohol pdf


How are alcohols prepared?

    Alcohols may be prepared (1) by hydration of alkenes (i) in presence of anacid and (ii) by hydroboration-oxidation reaction (2) from carbonyl compounds by(i) catalytic reduction and (ii) the action of Grignard reagents.

How are phenols prepared?

    Phenols may beprepared by (1) substitution of (i) halogen atom in haloarenes and (ii) sulphonicacid group in aryl sulphonic acids, by –OH group (2) by hydrolysis of diazoniumsalts and (3) industrially from cumene. Alcohols are higher boiling than other classes of compounds, namelyhydrocarbons, ethers and haloalkanes of comparable molecular masses.

What is the intermediate in reaction of secondary and tertiary alcohols with hydrogen halides?

    The key intermediate in reaction of secondary and tertiary alcohols with hydrogen halides is a carbocation. The overall reaction mechanism involves three elementary steps; the first two steps lead to the carbocation intermediate, the third step is the conversion of this carbocation to the alkyl halide.

Does dehydration of alcohol give alkenes?

    Dehydration of alcohols gives alkenes. On oxidation, primary alcoholsyield aldehydes with mild oxidising agents and carboxylic acids with strongoxidising agents while secondary alcohols yield ketones. Tertiary alcohols areresistant to oxidation.
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