all formulas of electrochemistry class 12
What is the difference between electrochemistry and electrolysis?
Electrochemistry: A field of chemistry that focuses on the interchange between electrical and chemical energy Electricity: Flow of electrons over a wire that is affected by the presence and flow of electric charge. Electrolysis: The decomposition of a substance by means of electric current.
What is electron chemistry?
Electrochemistry is the study of chemical processes that cause electrons to move. This movement of electrons is called electricity, which can be generated by movements of electrons from one element to another in a reaction known as an oxidation-reduction ("redox") reaction.
What is the simplest form of an electrochemical cell?
The simplest form of the electrochemical cell is Daniel Cell. The reaction that occurs at the two electrodes are as follows: At cathode: Cu 2+ (aq) + 2e – ⟶ Cu (s). When a metal is placed in a solution of its ions, the metal acquires either a positive or negative charge with respect to the solution.
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Key Information
Electrochemistry is the branch of chemistry that deals with the study of the interchange of chemical and electrical energy. It encompasses a wide range of topics, including redox reactions, electrochemical cells, and the principles of electrochemical measurements.
Examples
Examples of electrochemical processes include the electrolysis of water, the corrosion of metals, and the operation of batteries.
Exercises
Practice 1: Calculate the standard cell potential for the following reaction: Zn(s) + Cu2+(aq) → Zn2+(aq) + Cu(s)
Solution 1: The standard cell potential can be calculated using the standard reduction potentials of the half-reactions involved.
Practice 2: Determine the equilibrium constant for the following redox reaction: 2CrO4^2-(aq) + 2H3O+(aq) + 3Pb(s) → 2Cr3+(aq) + 3Pb^2+(aq) + 7H2O(l)
Solution 2: The equilibrium constant can be calculated using the Nernst equation and the standard reduction potentials of the half-reactions.
Practice 3: Calculate the cell potential at nonstandard conditions for the following electrochemical cell: Pt(s) | H2(g, 0.50 atm) | H+(aq, 0.10 M) || Cu2+(aq, 0.020 M) | Cu(s)
Solution 3: Use the Nernst equation to calculate the cell potential at nonstandard conditions.
Subcategories
Electrochemistry encompasses multiple subcategories, including redox reactions, electrolysis, electrochemical cells, and electrode potentials.
Notes
1. Electrochemical cells involve the conversion of chemical energy to electrical energy.
2. The standard hydrogen electrode (SHE) is often used as a reference in electrochemistry.
3. Electrolysis is the process of using electrical energy to drive non-spontaneous chemical reactions.
4. The Nernst equation relates the measured cell potential to the concentrations of reactants and products in nonstandard conditions.
Step-by-Step Guide
- Identify the oxidation and reduction half-reactions in the given electrochemical process.
- Balance the chemical equation for the overall reaction and the half-reactions.
- Calculate the standard cell potential using the standard reduction potentials of the half-reactions.
- For nonstandard conditions, use the Nernst equation to calculate the cell potential.
Cases and Scenarios
Case 1: Determining the products of electrolysis of molten sodium chloride.
Case 2: Calculating the cell potential for a galvanic cell based on given half-reactions.
Case 3: Analyzing the corrosion of iron and its prevention using electrochemical methods.
Questions & Answers
Q: What is the relationship between the standard cell potential and the equilibrium constant?
A: The standard cell potential is directly related to the equilibrium constant through the equation ΔG° = -nFE°, where ΔG° is the standard Gibbs free energy change, n is the number of moles of electrons transferred, F is the Faraday constant, and E° is the standard cell potential.
Q: How does the concentration of reactants and products affect the cell potential under nonstandard conditions?
A: According to the Nernst equation, the cell potential is logarithmically related to the concentrations of reactants and products, such that an increase in product concentration or a decrease in reactant concentration leads to a higher cell potential.
Q:
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