does esters react with sodium metal


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  • Hence, the ester enolate anion resonance structure IV plays a smaller role and the enolate anion is less stabilized in the ester compared to the ketone.
    Consequently, the ester is less acidic than the ketone.

  • Do aldehydes react with sodium metal?

    The reaction is called a Na/NH3 reduction.
    The aldehyde is typically dissolved in the solvent, and a small piece of sodium metal is added to the mixture.
    The sodium metal reacts with the solvent to form a complex called a sodamide, which can then reduce the aldehyde to an alcohol.

  • When esters are refluxed with metallic sodium in an aprotic solvent like ether, α- hydroxy ketones are formed. This reaction is known as: Acyloin condensation.
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