acetic anhydride production from acetic acid


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PDF Utilization of dilute acetic for manufacturing of acetic anhydride

Dilute Acetic Acid (25-30 acidity) generated from manufacturing process of Pharmaceutical/Pesticide/Chemical Industry are categorized as hazardous waste at 

  • How do you convert acetic acid to acetic anhydride?

    Acetic anhydride (CH3CO-O-COCH3) can be made from acetic acid (CH3COOH) by treating it with phosphorus pentachloride (PCl5) or dicyclohexylcarbodiimide (DCC).
    With PCl5, the reaction is a two step process.

  • How is acetic anhydride produced from acetic acid?

    It is known that acetic anhydride can be prepared via the reaction of acetic acid and ketene.
    Ketene, a valuable intermediate for the synthesis of many organic compounds, may be prepared by the thermal decomposition (continuous cracking) of acetic acid in the presence of a catalyst, e.g., triethyl phosphate.

On an industrial scale acetic anhydride is currently produced either by reaction of ketene and acetic acid, the ketene being obtained either by dehydration of acetic acid or by decomposition of acetone, or by oxidation of acetaldehyde which also yields acetic acid.
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