chemical test to distinguish between chlorobenzene and benzyl chloride
How to distinguish between chlorobenzene and cyclohexyl chloride?
The dipole moment of chloro-benzene is less than cyclo hexyl chloride as in chloro benzene C-Cl bond is sp2 hybridised where as in cyclohexyl chloride the C − C l bond is Sp3 Hybridised .
As sp2 has more s character and more electronegative than sp3.
Chlorobenzene is less polar than cyclohexyl chloride.How to distinguish test between chlorobenzene and n hexyl chloride?
Which is known as nucleophilic substitution reaction.
Hence, chlorobenzene on reaction with $ KOH $ , will not undergo the nucleophilic substitution and does not form benzyl alcohol.
But n-hexyl chloride undergoes nucleophilic substitution or hydrolysis to form n-hexyl alcohol.20 sept. 2021How to chemically distinguish between phenol and chlorobenzene?
Answer: We can distinguish between phenol and chlorobenzene by ferric chloride test which is a traditional colorometric test for phenols.
Phenol forms violet coloured complex with iron ion, which confirms presence of phenol while chlorobenzene does not give any colour.On reaction with NaOH, Chloromethane reacts giving methanol and Sodium chloride.
This sodium chloride on further reaction with Silver nitrate solution will give a white precipitate of Silver chloride. Chlorobenzene does not give this test.
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Chlorobenzene (C6H5Cl) and Benzyl chloride (C6H5CH2Cl) Benzyl chloride give white ppt, when treated with aq KOH and acidified AgNO3 solution While chlorobenzene does not give this test |
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