chemical test to distinguish between chlorobenzene and benzyl chloride


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  • How to distinguish between chlorobenzene and cyclohexyl chloride?

    The dipole moment of chloro-benzene is less than cyclo hexyl chloride as in chloro benzene C-Cl bond is sp2 hybridised where as in cyclohexyl chloride the C − C l bond is Sp3 Hybridised .
    As sp2 has more s character and more electronegative than sp3.
    Chlorobenzene is less polar than cyclohexyl chloride.

  • How to distinguish test between chlorobenzene and n hexyl chloride?

    Which is known as nucleophilic substitution reaction.
    Hence, chlorobenzene on reaction with $ KOH $ , will not undergo the nucleophilic substitution and does not form benzyl alcohol.
    But n-hexyl chloride undergoes nucleophilic substitution or hydrolysis to form n-hexyl alcohol.20 sept. 2021

  • How to chemically distinguish between phenol and chlorobenzene?

    Answer: We can distinguish between phenol and chlorobenzene by ferric chloride test which is a traditional colorometric test for phenols.
    Phenol forms violet coloured complex with iron ion, which confirms presence of phenol while chlorobenzene does not give any colour.

  • On reaction with NaOH, Chloromethane reacts giving methanol and Sodium chloride.
    This sodium chloride on further reaction with Silver nitrate solution will give a white precipitate of Silver chloride. ​Chlorobenzene does not give this test.

1) Chlorobenzene and Benzyl chloride Take both the compounds in a test tube. Add 1 - 2 ml of aqueous KOH to each of the test tubes. Acidify with dilute HNO3 and add AgNO3. Benzyl chloride gives white precipitate while chlorobenzene does not.
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