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PDF Chemistry of Sea water

composition of sea water Dittmar (1884) made careful determinations on 77 water samples representative of all oceans which had been collected on the voyage around the world of H M S Challenger He determined the halides sulphate magnesium calcium and potassium On composite samples

PDF Lecture 12

The composition of average seawater and river water in mmol kg-1 Element Na Mg Ca K Sr Cl SO4 HCO3 Br Seawater (mmol kg-1) 468 0

PDF COMPOSITION OF SEAWATER

1 COMPOSITION OF SEAWATER Ocean water is a combination of freshwater and a variety of dissolved substances Salinity is a measure of the amount of dissolved salts in seawater measured in parts per thousand (ppt) To change the salinity of an ocean three different things can occur: evaporation precipitation or freezing

PDF Lecture 4: Major Ions Conservative Elements and Dissolved

11 major ions all other elements in seawater are present in concentrations less than 1ppm (1mg/kg seawater) at S = 35 000 (from Pilson) Ion Formula g/Kg mmol/Kg Sodium Na+ 10 781 468 96 Magnesium Mg2+ 1 284

PDF Seawater: Composition and Properties 3

Seawater contains an abundance of organic and inorganic constituents These are present in dissolved suspended very finely distributed or colloidal form The dissolved constituents of seawater can be assigned to the following main categories: Inorganic main constituents that form the salt content of seawater with its cationic and anionic compone

  • What are the saline components of seawater?

    These saline components account for over 99% of the total salt content of seawater (see Fig. 3.1). The remaining around 1% of salt content consists mainly of the cations strontium and barium and the anions bicarbonate, carbonate, bromide, borate, uoride, and nitrate.

  • What elements are found in seawater?

    All naturally occurring elements on Earth have been found in seawater, both in high concentrations, such as in the main constituents of seawater salt content, and also in very low and tiny concentrations in trace substances in seawater. The salt content in the Earth’s seas and oceans differs very widely (see Table 3.1).

  • How much salt is in seawater?

    42 g/kg in the Red Sea and sometimes even up to 49 g/kg in the Arabian Gulf. The salt contained in seawater consists mainly of six saline components, namely, the cations sodium, magnesium, calcium, and potassium and the anions chloride and sulphate. These saline components account for over 99% of the total salt content of seawater (see Fig. 3.1).

3.1.1 Composition

Seawater contains an abundance of organic and inorganic constituents. These are present in dissolved, suspended, very finely distributed, or colloidal form. The dissolved constituents of seawater can be assigned to the following main categories: Inorganic main constituents that form the salt content of seawater with its cationic and anionic compone

Chlorinity and Salinity

The salt content (S) of seawater is de ned as the quantity of dissolved inorganic fi substance per kilogram of seawater, i.e. the mass proportion of dissolved inorganic substance. The salt content includes not only ionogenic but also neutral undissoci-ated and weakly dissociated inorganic components. However, it does not include dissolved organic s

3 :2 ð Þ

Chlorinity is measured by Knudsen-Mohr titration of a seawater sample with silver nitrate solution. This determines all the halogenides present in the sample, i.e. not only chloride but also the concentrations of bromide and iodide (of which there is a negligibly small concentration in seawater): Agþ seawater AgCl AgBr AgJ þ ð Þ þ S ð Þ þ s s ð Þ

(K or K0

sp sp ) characterizes the solubility limit of a low-solubility compound in a solution. With knowledge of the activity coef ficients of the components involved in the reaction and with knowledge of the value of the stoichiometric solubility product (K sp), the thermodynamic solubility product (K0 sp) can be calculated as link.springer.com

ADH

ffiffiffiffiffi Im bi BDH ai p ffiffiffiffiffi Im þ þ link.springer.com

Φ0 a,a0

E-parameter equations for single anion activity coefcient ( γX): fi Nc link.springer.com

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