dibasic base examples


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  • What is the difference between a di acid and a polyacidic base?

    Click ‘Start Quiz’ to begin! Di and Polybasic Acid and Base- Polybasic acids are those acids which are capable of yielding more than one hydronium ion per molecule,Similarly for polyacidic bases are those which are capable of yielding more than one hydroxyl ion in aqueous solution.

  • What is the difference between acids and bases?

    Bases have properties that mostly contrast with those of acids. Aqueous solutions of bases are also electrolytes. Bases can be either strong or weak, just as acids can. Bases often have a bitter taste and are found in foods less frequently than acids. Many bases, like soaps, are slippery to the touch. Bases also change the color of indicators.

  • What is an example of a dibasic acid?

    Sulfuric acid, one of the best-known and most widely used acids, is a good example of a dibasic acid. It can form two types of salts, known as sulfates and hydrogen sulfates, sometimes called bisulfates. Carbonic acid is another common dibasic acid that can, similarly, form carbonates and hydrogen carbonates.

Overview

Definition of Arrhenius acids and bases, and Arrhenius acid-base reactions •An Arrhenius acid is any species that increases the concentration of H+‍  in aqueous solution. •An Arrhenius base is any species that increases the concentration of OH−‍  in aqueous solution. •In aqueous solution, H+‍  ions immediately react with water molecules to form hydronium ions, H3O+‍ . khanacademy.org

Key points

•An Arrhenius acid is any species that increases the concentration of H+‍  in aqueous solution. •An Arrhenius base is any species that increases the concentration of OH−‍  in aqueous solution. •In aqueous solution, H+‍  ions immediately react with water molecules to form hydronium ions, H3O+‍ . •In an acid-base or neutralization reaction, an Arrhenius acid and base usually react to form water and a salt. khanacademy.org

Introduction

From the vinegar in your kitchen cabinet to the soap in your shower, acids and bases are everywhere But what does it mean to say that something is acidic or basic? In order to answer this question, we need to examine some of the theories describing acids and bases. In this article, we will focus on the Arrhenius theory. khanacademy.org

Arrhenius acids

The Arrhenius theory of acids and bases was originally proposed by the Swedish chemist Svante Arrhenius in 1884. He suggested classifying certain compounds as acids or bases based on what kind of ions formed when the compound was added to water. An Arrhenius acid is any species that increases the concentration of H+‍  ions—or protons—in aqueous solution. For example, let's consider the dissociation reaction for hydrochloric acid, HCl‍ , in water: HCl(aq)→H+(aq)+Cl−(aq)‍  When we make an aqueous solution of hydrochloric acid, HCl‍  dissociates into H+‍  ions and Cl−‍  ions. Since this results in an increase in the concentration of H+‍  ions in solution, hydrochloric acid is an Arrhenius acid. khanacademy.org

Hydrogen or hydronium ions?

Let's say we made a 2M‍  aqueous solution of hydrobromic acid, HBr‍ , which is an Arrhenius acid. Does that mean we have 2M‍  of H+‍  ions in our solution? Actually, no. In practice, the positively charged protons react with the surrounding water molecules to form hydronium ions, H3O+‍ . This reaction can be written as follows: H+(aq)+H2O(l)→H3O+(aq)‍  Even though we often write acid dissociation reactions showing the formation of H+(aq)‍ , there are no free H+‍  ions floating around in an aqueous solution. Instead, there are primarily H3O+‍  ions, which form immediately when an acid dissociates in water. The following picture illustrates the formation of hydronium from water and hydrogen ions using molecular models: In practice, most chemists talk about the concentration of H+‍  and the concentration of H3O+‍  interchangeably. When we want to be more accurate—and less lazy—we can write the dissociation of hydrobromic acid to explicitly show the formation of hydronium instead of protons: HBr(aq)+H2O(l)→H3O+(aq)+Br−(aq)        More accuratevs.HBr(aq)→H+(aq)+Br−(aq)    Shorter and easier to write‍  khanacademy.org

Arrhenius bases

An Arrhenius base is defined as any species that increases the concentration of hydroxide ions, OH−‍ , in aqueous solution. An example of an Arrhenius base is the highly soluble sodium hydroxide, NaOH‍ . Sodium hydroxide dissociates in water as follows: NaOH(aq)→Na+(aq)+OH−(aq)‍  In water, sodium hydroxide fully dissociates to form OH−‍  and Na+‍  ions, resulting in an increase in the concentration of hydroxide ions. Therefore, NaOH‍  is an Arrhenius base. Common Arrhenius bases include other Group 1 and Group 2 hydroxides such as LiOH‍  and Ba(OH)2‍ . [Wait, aren't most metal hydroxides insoluble?] Note that depending on your class—or textbook or teacher—non-hydroxide-containing bases may or may not be classified as Arrhenius bases. Some textbooks define an Arrhenius base more narrowly: a substance that increases the concentration of OH−‍  in aqueous solution and also contains at least one unit of OH−‍  in the chemical formula. While that doesn't change the classification of the Group 1 and 2 hydroxides, it can get a little confusing with compounds such as methylamine, CH3NH2‍ . When methylamine is added to water, the following reaction occurs: khanacademy.org

Acid-base reactions: Arrhenius acid + Arrhenius base = water + salt

When an Arrhenius acid reacts with an Arrhenius base, the products are usually water plus a salt. These reactions are also sometimes called neutralization reactions. For example, what happens when we combine aqueous solutions of hydrofluoric acid, HF‍ , and lithium hydroxide, LiOH‍ ? If we think about the acid solution and base solution separately, we know the following: •An Arrhenius acid increases the concentration of H+(aq)‍ : HF(aq)⇌H+(aq)+F−(aq)‍  •An Arrhenius base increases the concentration of OH−(aq)‍ : LiOH(aq)→Li+(aq)+OH−(aq)‍  khanacademy.org

Limitations of the Arrhenius definition

The Arrhenius theory is limited in that it can only describe acid-base chemistry in aqueous solutions. Similar reactions can also occur in non-aqueous solvents, however, as well as between molecules in the gas phase. As a result, modern chemists usually prefer the Brønsted-Lowry theory, which is useful in a broader range of chemical reactions. The

Summary

•An Arrhenius acid is any species that increases the concentration of H+‍  in aqueous solution. •An Arrhenius base is any species that increases the concentration of OH−‍  in aqueous solution. •In aqueous solution, H+‍  ions immediately react with water molecules to form hydronium ions, H3O+‍ . •In an acid-base or neutralization reaction, an Arrhenius acid and base usually react to form water and a salt. khanacademy.org

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