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  • Why is the Diels-Alder reaction faster?

    The Diels-Alder reaction is faster when there is an electron-withdrawing group on the pi bond (“dienophile”) and electron donating groups on the diene. Don’t Be Underwhelmed! Four Key Things, Part 3: Substituents On The Diene Or Dienophile Do NOT Affect The Bond-Forming / Bond-Breaking Pattern Of The Diels-Alder Four Key Things, Part 4.

  • Does 1,3-butadiene undergo a Diels-Alder reaction?

    The diene must be conjugated to participate in a Diels-Alder reaction. No conjugation, no Diels-Alder. So while 1,3-butadiene readily undergoes the Diels-Alder reaction, 1,4 pentadiene (below) does not. (If you’re not clear about what constitutes a “conjugated” diene, you might want to visit this post .) 8.

  • What is an example of a Diels Alder reaction?

    One example occurs in the biosynthesis of the cholesterol-lowering drug lovastatin (trade name Mevacor) isolated from the bacterium Aspergillus terreus. The key step is the intramolecular Diels–Alder reaction of a triene, in which the diene and dienophile components are within the same molecule.

  • How can a diene predict a Diels-Alder reaction?

    predict the stereochemistry of the product obtained from the reaction of a given diene with a given dienophile. recognize that in order to undergo a Diels-Alder reaction, a diene must be able to assume an s -cis geometry, and determine whether or not a given diene can assume this geometry.

Diels-Alder reaction  Organic chemistry  Khan Academy

Diels-Alder reaction Organic chemistry Khan Academy

Diels Alder Reaction

Diels Alder Reaction

Diels-Alder Reaction  Organic Chemistry Lessons

Diels-Alder Reaction Organic Chemistry Lessons

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226assign-12html


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Perfluorobicyclo[220]hex-1(4)-ene as unique partner for Diels


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