Abstract: Convenient, efficient preparation of aromatic sec-amides from esters has been accomplished using dilithium amides which are easily prepared by treatment of aromatic amines with 2 equiv of BuLi in THF This new method allows a facile formation of amide bond even with sterically hindered esters
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reaction of esters with amines and many different protocols including a recent nickel catalyzed protocol[13] for the amide formation have been described
Manuscript Accepted
amide synthesis, and assess new catalytic amide formation methods in the context of esters (D), oxidative amidation of primary alcohols or aldehydes (E), and
Sheppard A green chemistry perspective on catalytic amide bond formation AAM
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herein report a general methodology malonic ester amide synthesis (MEAS)