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The reactivity of the active metal oxo and hydroxo intermediates and

17 ???. 2014 ?. 7 In a typical rate determining hydrogen abstraction step the value of the H/D kinetic isotope effect (KIE) is generally in the range of 2~7



Oxidative Reactivity Difference among the Metal Oxo and Metal

Metal Hydroxo Moieties: pH Dependent Hydrogen Abstraction for the same redox active metal ion in identical structures and oxidation states that is



Hydrogen Atom Transfer Reactions and the Effects of Non-Redox

rates for abstraction of a hydrogen from a C H bond by the CumO radical are Finally the effect of non-redox active metal cations on HAT reactions ...



Zn-MOF assisted dehydrogenation of ammonia borane: Enhanced

29 ???. 2011 ?. Metal-organic framework. Nanoconfinement. Dehydrogenation kinetics. Hydrogen storage abstract. We report controllable and enhanced hydrogen ...





On the Influence of the Extent of Oxidation on the Kinetics of the

of the Hydrogen Electrode Reactions on Polycrystalline Nickel. Alexandr G. Oshchepkov1 platinum-group metal-free electrocatalysts for the HOR/HER.



Seawater Splitting for Hydrogen Generation Using Zirconium and Its

3 ??? ????? Abstract: Hydrogen production is produced for future green energy. ... active metal that reacts with oxygen nitrogen



Kinetic Study on CO-Selective Methanation over Nickel-Based

24 ????. 2021 ?. Catalysts for Deep Removal of CO from Hydrogen-Rich ... drogenation reaction follows possibly at the active metal–support interface so CO2 ...



Cobalt-Based Fischer–Tropsch Synthesis: A Kinetic Evaluation of

24 ????. 2019 ?. Abstract: Metal–support interactions in the cobalt–alumina system are ... the catalytic active phase [10–12] and the particle morphology ...



Semiclassical Approach to the Nonlocal Kinetic Model of Metal

23 ????. 2021 ?. Abstract: A semiclassical approach based on the WKB–Maslov method is ... Studies of kinetics of metal vapor active media (MVAM) are ...

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