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Syllabus for 2 year M Sc Program in Materials Science MS in Materials Science for students with Chemistry B Sc /BS Semester-I Name of the course Credit 1

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[PDF] School of Materials Sciences 150536_7Syllabus_School_Materials_Sciences_2018.pdf Syllabus for 2 year M.Sc. Program in Materials Science MS in Materials Science for students with Chemistry B.Sc./BS

Semester-I

Name of the course Credit

1 Quantum Mechanics (CHS4101) 4 (Core)

2 Inorganic Chemistry: Structure and Reactivity 4 (Core)

(CHS4102)

3 Organic Chemistry: Structure, Dynamics and 4 (Core)

Reactivity (CHS4103)

4 Mathematics for Chemists (CHS4104) 4 (Core)

5 Materials Laboratory-I 6

English Communication 2 Semester-II Name of the course Credit

5 Thermodynamics and Statistical Mechanics 4 (Core)

(CHS4201)

6 Chemistry of the Elements (CHS4202) 4 (Core)

7 Organic Chemistry: Reagents and Synthetic 4 (Core)

Methods (CHS4203)

8 Group Theory and Molecular Spectroscopy 4 (Core)

(CHS4204)

9 Materials Laboratory-II 6

Seminar & Colloquium 2 Semester-III Name of the course Credit

10 Materials characterization using microscopy, 4 (Core)

diffraction, and spectroscopy (NP, SR, & PK)

11 Electronic and magnetic properties of 4 (Core)

Solids (SKS and SKD)

12 Materials for Energy (SKS) 4 (DSE)

13 Generic Elective-I (AB) 4 (GE)

14 Project-I 8

Ethics 2

Semester-IV

Name of the course Credit

15 Nanomaterials and Thin films (DD and NP)/ 4 (DSE)

Ceramics and polymers (SKD and AKN)

16 Dielectric, optical, and mechanical properties 4 (DSE)

of materials (AP + SM + DM)/ Semiconductor devices and electronics (PK)

17 Advanced Materials including Biomaterials 4 (DSE)

(NRJ)

18 Generic Elective-II (AP and SR) 4 (GE)

19 Project -II 8

Seminar & Colloquium *********************************************************************** MS in Materials Science for students with Physics B.Sc./BS

Semester-I

Name of the course Credit

1 Classical Mechanics (Physics core) 4 (Core)

2 Quantum Mechanics-I (Physics core) 4 (Core)

3 Mathematical Methods-I (Physics core) 4 (Core)

4 Electronics (Physics core) 4 (Core)

5 Materials Laboratory-I 6

Semester-II

Name of the course Credit

5 Quantum Mechanics-II (Physics core) 4 (Core)

6 Mathematical Methods-II (Physics core) 4 (Core)

7 Electromagnetic Theory (Physics core) 4 (Core)

8 Statistical Mechanics (Physics core) 4 (Core)

9 Materials Laboratory-II 6

Semester-III

Name of the course Credit

10 Materials characterization using microscopy, 4 (Core)

diffraction, and spectroscopy (NP, SR, & PK)

11 Electronic and magnetic properties of 4 (Core)

Solids (SKS and SKD)

12 Materials for Energy (SKS) 4 (DSE)

13 Generic Elective-I (AB) 4 (GE)

14 Project-I 8

Semester-IV Name of the course Credit

15 Nanomaterials and Thin films (DD and NP)/ 4 (DSE)

Ceramics and polymers (SKD and AKN)

16 Dielectric, optical, and mechanical properties 4 (DSE)

of materials (AP + SM + DM)/ Semiconductor devices and electronics (PK)

17 Advanced Materials including Biomaterials 4 (DSE)

(NRJ)

18 Generic Elective-II (AP and SR) 4 (GE)

19 Project -II 8

* The number given as credit indicates the number of hours to be taught in a week.

Detailed Syllabus

Materials Laboratory-I (MS4105):

1. Synthesis and Characterization of oxides: Solid State Reaction, High temperature

Furnace, Structural (XRD) and Microstructural (SEM) studies. 2. Preparation by wet chemical methods: Sol-gel, Slvothermal/Hydrothermal, FTIR,

TGA/DSC, Sample purification, Structural and Microstructural studies. 3. Preparation of thin films: Thermal evaporation, Thickness measurement, Structural

(XRD) and Microstructural (SEM, AFM) studies. 4. Synthesis and Characterization of Polymers: To be decided by AKN.

Materials Laboratory-II (MS4205):

1. Optical characterizations: Absorption, Emission and Life time measurements.

2. Electrical characterizations: Resistance with temperature, Current-Voltage measurements. 3. Dielectric and Impedance measurements.

4. Ferroelectric loop measurements.

Materials characterization using microscopy, diffraction, and spectroscopy (MS5101): Crystalline Crystalline solids - crystal systems - Bravais lattices coordination number packing factors cubic, hexagonal, diamond structures lattice planes Miller indices interplanar distances directions. Types of bonding - lattice energy Madelung constants

Born Haber cycle cohesive energy.

Symmetry elements, operations - translational symmetries - point groups space groups - equivalent positions close packed structures - voids - important crystal structures Paulings rules - defects in crystals, polymorphism and twinning. Diffraction of Waves by crystal-X-ray, neutron electrons-Bragg reciprocal lattice-structure factor-principle of diffraction technique. Crystal Defects: Point defects-types of point defects-thermodynamics of point defects. Geometry of dislocations, evidence of dislocations. Grain boundaries-atomics structure of grain boundaries.

ESCA - EPMA - Auger emission spectroscopy.

Electron beam instruments: Transmission electron and scanning electron microscopes, Auger electron spectroscope, x-ray spectrometers, electron microprobe, electron spectrometers. Interpretation of diffraction information: selected area and convergent beam Electron diffraction patterns. Analysis of micrographs in TEM, SEM, and HRTEM: Theories of diffraction contrast in TEM, analysis of images in TEM and SEM. Interpretation of analytical data: EDS, WDS, Auger, EELS, ESCA, SIMS. Bulk averaging techniques: Thermal analysis, DTA, DSC, TGA, dilatometry, resistivity/conductivity. Optical spectroscopy: Atomic absorption spectroscopy, infrared spectroscopy and Raman spectroscopy. Emission spectrometry Scanning Tunneling and Atomic Force Microscopy. Applications in thin film and nanostructured materials: case studies Mass spectroscopy: Principles and brief account. Metallographic techniques: Optical metallography, image analysis, quantitative phase estimation. NMR: Principles and applications. Electrical Characterization, I-V, C-V, Hall effect, Low and High temperature effect Electronic and magnetic properties of Solids (MS5102): Free electron theory of metals-Drude theory Wiedemann-Franz Law and Lorentz number free electron statistics (Fermi-Dirac) density of states - Sommerfeld theory concentration, chemical potential, Fermi energy and specific heat of free electrons Boltzmann transport theory electrical and thermal conductivity of electrons. Mono atomic and diatomic lattices harmonic approximation - phonon frequencies and density of states Einstein and Debye theories of lattice energies and phonon dispersion curves anharmonic effects - thermal expansion - thermal conductivity - normal and

Umklapp processes - scattering experiments.

Bloch- nearly free electron approximation - formation of energy bands and gaps - Brillouin zones and boundaries - effective mass of electrons and concept of holes - classification into insulators, conductors, semiconductors and semimetals - Fermi surface -

Cyclotron resonance.

Semiconductors direct and indirect gaps carrier statistics (intrinsic and extrinsic) law of mass action and chemical potential of semiconductors electrical conductivity and its temperature variation - III - V and II VI compound semiconductors excitons and polarons. Superconductivity critical parameters anomalous characteristics isotope effect, Meissner effect type I and II superconductors - BCS theory (elementary) - Josephson junctions and tunneling SQUID - High temperature superconductors - applications. Classification - dia, para, ferro, antiferro and ferrimagnetism Langevin and Weiss theories - Curie equation, Curie -Weiss law - spin and orbital effects, spin-orbit

coupling, Lande interval rule, energies of J levels, first order and second order Zeeman

effects, temperature independent paramagnetism, simplification and application of van Vleck susceptibility equation, quenching of orbital moment, magnetic properties of transition metal complexes, low spin, high-spin crossover, magnetic behavior of lanthanides and actinides - exchange interaction - magnetic anisotropy - magnetic domains - molecular theory hysterisis - hard and soft magnetic materials - ferrite structure and uses - magnetic bubbles - magnetoresistance - GMR materials - magnetism in particles of reduced size and dimensions - variations of magnetic moment with size - magnetism in clusters of non magnetic solids - magnetic behaviour of small particles - diluted magnetic semiconductors (DMS) - Fe- DMS and IV -VI Mn DMS and their applications - intermetallic compounds - binary and ternaries and their magnetic properties. Small particle magnetism, magnetic anisotropy, magneto crystalline anisotropy, shape anisotropy, single domain particles, Superparamagnetism, Blocking temperature, Effect of inter particle interaction and surface effects, spin polarized charge transport, Giant magnetoresistance, tunneling magnetoresistance.

Materials for Energy (MS5103):

Photovoltaics: Solar energy and energy conversion, Fundamentals of semiconductor physics and

photovoltaic cells, Generation-recombination in semiconductors, p-n junction, metal- semiconductor and hetero junction, Photovoltaic device fabrication and characterization, Current status of silicon based solar cells, Advancement in photovoltaic research and design of new generation solar cells (hybrid, quantum dot, dye-sensitized and perovskite solar cells)

Batteries & Supercapacitors: Basic concepts of Batteries, Supercapacitors and Fuel cells, Thermodynamics and kinetics

involved in electrochemical reactions, Primary and rechargible batteries, Li-ion Battery, Components and processes in batteries (Battery operations), Cell characterization: (Charging/discharging cycles, overpotential, battery capacity, state of charge, state of health,

impedance spectroscopy), Large scale applications, Plot of Energy Vs Power Densitiy, Different types of supercapacitors (Electrochemical

double layer capacitor, pseudocapacitor and hybrid capacitor), Components of supercapacitors, Elecetrochemical properties (Charging/discharging cycles, Cyclic Voltametry and impedance spectroscop, lifetime stability), Different applications.

Thermoelectric Materials: Fundamentals of thermoelectricity (Seebeck, Peltier and Thomson effects), Thermoelectric

Effects and Transport Properties, Basics of Thermoelectric devices, Heat Conduction in Bulk Thermoelectric Materials (Heat Conduction by Phonons, Heat Conduction by Electrons), Progress in Thermoelectric Materials (Bulk Thermoelectric Materials, Nanostructured

Thermoelectric Materials), Reduction of Thermal Conductivities in Bulk and Nanostructured Materials), Thermoelectric Devices.

Fuel Cells: Why Fuel cells, Thermodynamics of Fuel Cells, Basic principles and reaction kinetics, Charge and Mass transport, Cell characterization, Different types of Fuel Cells (Phosphoric acid fuel cell (PAFC), polymer electrolyte membrane fuel cell (PEMFC), alkaline fuel cell (AFC), molten carbonate fuel cell (MCFC) and solidǦoxide fuel cell (SOFC).

Catalysis: Concepts of Electrocatalysis and Photocatalysis, Thermodynamics and reaction kinetics for

water splitting, Basic principles and properties for photocatalytic and electrocatalytic water splitting, Few examples of Electro and photocatalysts, Cell fabrication and measurement techniques. Microporous and Mesoporous Materials (MS5104) (GE-I): Zeolites, metallosilicates, silicalites and related microporous materials: synthesis and

characterizations. Metallo phosphates/phosphonates, incorporation of heteroelements in microporous inorganic

frameworks and their potential utilities. Mesoporous silica, metal oxides and related functionalized mesoporous materials: synthesis,

characterizations and support for metallic nanoparticles. Heterogeneous catalysis: advantages, liquid and gas phase catalytic reactions, C-C bond

formation reactions, partial oxidation reactions, biofuel synthesis, CO2 fixation reactions for

the synthesis of fuels and fine chemicals. Introduction of nanoscale porosity in organic and inorganic materials, surface acidity and

basicity measurements.Impact of nanoscale porosity and surface acidity/basicity in the energy

and environmental research. Covalent organic frameworks, porous organic polymers and related organic porous materials: sensing, adsorption and gas storage applications. Organic-Inorganic hybrid materials,

periodic mesoporous organosilicas,metal organic frameworks: H2 /CO2 gas storage and catalytic applications.

Nanomaterials and Thin films (MS5201-I):

Length, energy, and time scales - Quantum confinement of electrons in semiconductor nanostructures: Quantum confinement in 3D, 2D, 1D and zero dimensional structures -Size effect and properties of nanostructures- Landauer- Buttiker formalism for conduction in confined geometries - Top down and Bottom up approach. . Quantum dots: Excitons and excitonic Bohr radius difference between nanoparticles and quantum dots - Preparation through colloidal methods - Epitaxial methods- MOCVD and MBE growth of quantum dots - current-voltage characteristics - magneto tunnelling measurements - spectroscopy of Quantum Dots: Absorption and emission spectra - photo luminescence spectrum - optical spectroscopy - linear and nonlinear optical spectroscopy. Synthesis- Gas phase condensation Colloidal synthesis - Vacuum deposition -Physical

vapor deposition (PVD) - chemical vapor deposition (CVD) laser ablation- Sol-Gel- Ball milling Electro deposition-

electroless deposition spray pyrolysis plasma based synthesis process (PSP) - hydrothermal synthesis. Applications of nanoparticles, quantum dots, nanotubes and nanowires for nanodevice fabrication Single electron transistors, coulomb blockade effects in ultrasmall metallic tunnel junctions - nanoparticles based solar cells and quantum dots based white LEDs CNT based transistors principle of dip pen lithography. Thin Film- Physical methods: thermal evaporation - vapour sources - Wire, crucible and electron beam gun - sputtering mechanism and methods - epitaxy - MBE. Chemical methods: chemical vapour deposition and chemical solution deposition techniques spray pyrolysis - laser ablation. Mechanical pumps - Diffusion pump - measurement of vacuum - gauges production of ultra high vacuum - thin film vacuum coating unit - substrate cleaning Thickness measurement- Multiple beam interference - quartz crystal - ellipsometric - stylus

techniques. Growth: General features - Nucleation theories - Post-nucleation growth Thin film

structures-Structural defects. Applications of thin film- reflection and anti-reflection coatings - interference filters - thin film solar cells - electrophotography. Electrical and dielectric behaviour of thin films - components - thin film diode and transistor - strain gauges and gas sensors. Electrical and dielectric behaviour of thin films - components - thin film diode and transistor - strain gauges and gas sensors. Anisotropy in magnetic films - domains in films - computer memories - superconducting thin films - SQUID - mechanical properties: testing methods - adhesion - surface and tribological coatings.

Ceramics and Polymers (MS5201-II):

Oxide ceramics zirconia, alumina, silica, magnesia and, titania, mullite carbides vsilicon carbide, boron carbide, tungsten carbide, titanium carbide nitrides silicon nitride, boron nitride, titanium nitride, borides, silicides, - sialon. Ceramic insulators and capacitors ferroelectric ceramics barium titanate, PZT, PLZT materials magnetic ceramics spinel ferrites, zinc ferrites, garnets superconducting ceramics varistors and fuel cells. Silica, alumina Bioceramic materials-high temperature applications-silica refractories special refractories alumina, mullite, carbide based and nitride based refractories, cordierite, zirconia, fusion cast refractories ceramic fibers. Glass forming processes glass composition, heat treatment schedule, crystal nucleation in glass, nucleation agent high purity silica glass, laser glasses, fiber glasses, optical glasses, fiber glass, non-oxide glasses. Classification of polymers copolymers tacticity geometric isomerism molecular

weight distribution and averages Measurement of molecular weight synthesis of polymers step growth polymerisation chain growth polymerisation polymerisation techniques .

Polymer conformation and chain dimensions Freely oriented perpendicular chains-Gaussian model amorphous state glass transition temperature the crystalline state ordering of polymer chains crystalline melting temperature techniques to determine crystallinity Mechanical properties Introduction to viscoelasticity dynamic mechanical analysis

mechanical models of viscoelastic behaviour Boltzmann superposition principle Introduction to rubber elasticity.

Dielectric, optical, and mechanical properties of materials (MS5202-I): Factors affecting mechanical properties-fundamentals of elasticity-anelasticity, viscoelasticity of materials-plastic deformation of single crystalline and polycrystalline materials- mechanical tests - tensile, hardness, impact, creep and fatigue-plastic deformation of Single crystalline and Polycrystalline materials- shear strength - work hardening and recovery - fracture - Griffith's theory - slip and twinning - creep resistant materials -diffusion Fick Dielectric constant and polarizability - different kinds of polarization - Internal electric field in a dielectric -Clausius- Mossatti equation - dielectric in a ac field - dielectric loss - ferroelectric - types and models of ferro electric transition - electrets and their applications piezoelectric and pyroelectric materials - applications of dielectric, ferroelectric, piezoelectric and pyroelectric materials. Optical absorption in insulators, semiconductors and metals band to band absorption luminescence - photoconductivity. Injection luminescence and LEDs - LED materials - superluminescent LED materials - liquid crystals properties and structure - liquid crystal displays-comparison between LED and LC displays. Semiconductor Devices and Electronics (MS5202-II): Introduction Physics of Materials, Confinement and Quantization, Fermi-Dirac Statistics Energy bands in solids, the E-k diagram, Density of states, Bands: Free Electron and Tight

Binding Approximation Occupation probability, Carried Concentration, Fermi level and quasi-Fermi levels, Fermi

Energy, Fermi Surface Semiconductor materials, Bandgap modification, Heterostructures, Lattice Matching,

Strained Layer Epitaxy and Quantum Well structures Heterostructure p-n junction, Schottky junction and Ohmic contacts, Physics of Nano Scale

Materials

Metal-Semiconductor contacts, Ohmic Contacts on Semiconductors, Fermi Level Pinning,

Schottky Barrier Diodes, Causes of Non-Idealities-Schottky Barrier Diodes Fabrication of heterostructured Devices: LED, Lasers, Photodiode, Schottky diode, FETs,

HEMTs, MOSFET, Solar cells, Photoelectrodes and Sensors Advanced materials including Biomaterials (MS5203): Composites-Metal matrix composites- polymer matrix composites - ceramic matrix composites -reinforcements - whisker reinforced ceramics - carbon-carbon composites - design of composite materials - hybrid composites - angled plied composites- unidirectional fiber composites - discontinuous fiber composites - applications of composites in electrical components and nuclear industry. Light weight materials-Properties and structure of Titanium - alloying elements- manufacture of titaniumwrought products - mechanical properties and microstructure correlation and + alloys, aerospace and medical applications - yttrium based iron-chromium aluminum alloy- mechanical alloying process of MA 956 alloy - MAODS super alloys - high temperature and medical applications. Electrets - properties and applications - metallic glasses - properties and applications - SMART materials - piezoelectric, magnetostrictive, electrostrictive materials - shape memory alloys - rheological fluids - CCD device materials and applications single crystalline solar cells - amorphous silica solar cells -thin film polycrystalline solar cells -surface acoustic wave and sonar transducer materials and applications.

Biomaterials: Biocompatibility- introduction to the biological environment material response: swelling and leaching, corrosion and dissolution, deformation and failure, friction

and wear host response: the inflammatory process - coagulation and hemolysisapproaches to thrombo- resistant materials development. Different biomaterials-Orthopaedic materials, cardiovascular materials, dental materials, ophthalmic materials etc.

Carbon Nanotechnology (MS5204) (GE-II):

THE GEOMETRY OF NANOSCALE CARBON: Introduction Carbon molecules-nature of the carbon bond-new carbon structures-discovery of C60-structure of C60 and its crystal- From a Graphene Sheet to a Nanotube Single wall and Multi walled Nanotubes - Zigzag and Armchair Nanotubes - Euler's Theorem in Cylindrical and Defective Nanotubes.Structure and Bonding. FULLERENES: Structure and Bonding- Nomenclature, The Structure of C60, Structure of Higher Fullerenes - Growth Mechanisms; Production and Purification- Fullerene Preparation by Pyrolysis of Hydrocarbons, Partial Combustion of Hydrocarbons, Arc Discharge Methods, Production by Resistive Heating, Rational Syntheses; Physical Properties-, Spectroscopic Properties, Thermodynamic Properties; Chemical Properties- Hydrogenation and Halogenation, Nucleophilic Addition to Fullerenes. CARBON NANOTUBES: The Structure of Carbon Nanotubes- Nomenclature, Structure of Single-Walled Carbon Nanotubes and Structure of Multiwalled Carbon Nanotubes; Structure and Production of Further Tubular Carbon Materials- Spectroscopic Properties of Carbon Nanotubes- Raman and Infrared Spectroscopy of Carbon Nanotubes, Absorption and Emission Spectroscopy of Carbon Nanotubes, ESR-Spectroscopic Properties of Carbon

Nanotubes.

GRAPHENE: Structure of graphene; Preparation of graphene synthesis of graphene by various physical and chemical methods and Purification; Electronic Properties - Band Structure of Graphene - Mobility and Density of Carriers - Quantum Hall Effect - Spectroscopic Properties of graphene - Raman Spectroscopy, Infrared Spectroscopy, X-Ray Diffraction and EELS, Absorption and Photoluminescence Spectroscopy. APPLICATIONS OF CARBON NANOMATERIALS: Application of Fullerene, CNT, Graphene and other carbon nanomaterials - Mechanical, Thermal Applications, Electronic

Applications and biological Applications.

TEXT BOOKS 1. Anke Krueger,

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