[PDF] Advanced Inorganic Chemistry - Chem 471/571 Fall 2020 Professor





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[PDF] Advanced Inorganic Chemistry - Chem 471/571 Fall 2020 Professor

Text: Inorganic Chemistry (5th Ed ) by Miesslar, Fischer, and Tarr known elements exhibit significant variation in their individual properties and the types of

[PDF] Advanced Inorganic Chemistry (Part 1) Basic Solid State Chemistry

Importance of structural chemistry • knowledge of several structure types • understanding of structures • Physical methods for the characterization of solids

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Scheduled office hours: Wednesday (following class) 1:20- 2:20 pm or by illustrated by examples linking Inorganic Chemistry with e g materials science and

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[PDF] Advanced Inorganic Chemistry - Chem 471/571 Fall 2020 Professor 99675_7160_471_571_Fall20.pdf

Advanced Inorganic Chemistry - Chem 471/571

Fall 2020

Monday 10:40am ʹ 12pm/ Wednesday 10:40am ʹ 12pm Presented over Webex

Professor Mark Lipke

Office: CCB 2202

Office Hours: Friday 11am ʹ noon

E-mail: ml1353@chem.rutgers.edu

Prerequisites (for undergraduates enrolled in 471): Chem 371 Inorganic Chemistry Text: Inorganic Chemistry (5th Ed.) by Miesslar, Fischer, and Tarr.

Other suggested texts: ͞ƌďŝƚĂůŶƚĞƌĂĐƚŝŽŶƐŝŶŚĞŵŝƐƚƌLJ͟ďLJůďƌŝŐŚƚ͕ƵƌĚĞƚƚ͕ĂŶĚŚĂŶŐďŽ͖͞ŚĞŵŝĐĂů

ƚƌƵĐƚƵƌĞĂŶĚŽŶĚŝŶŐ͟ďLJĞŽĐŬĂŶĚƌĂLJ͖͞ƚŬŝŶƐ͛ŚLJƐŝĐĂůŚĞŵŝƐƚƌLJ͟ďLJƚŬŝŶƐĂŶĚĞĂƵůĂ͘

Sections of these textbooks are useful for providing a better/deeper understanding of some course material, and will be used as references for material covered in lecture.

Other Resources: Lecture slide will be posted on the Canvas site, usually shortly before the start of each lecture.

Lectures will partially follow the content of the text by Miesslar and Tarr, but will include a significant amount of material that draws from other texts or the primary literature.

Grading: A total of 475 points are possible. Points are distributed as follows: Class Participation: 75 pts Exams 1 - 3: 3

00 pts (100 pts each)

Final Presentation: 100 pts Total: 475 pts

Course Description:

The >100 known elements exhibit significant variation in their individual properties and the types of

bonds/structures they form with each other. Understanding the rich chemistry of the elements is an

enticing intellectual challenge with practical benefits that arise from the useful properties of many

elements and compounds. This course will build upon previous courses in inorganic and physical chemistry

ƚŽĚĞĞƉĞŶƐƚƵĚĞŶƚƐ͛ƵŶĚĞƌƐƚĂŶĚŝŶŐŽĨƚŚĞĐŽŶĐĞƉƚƐŽĨĞůĞĐƚƌŽŶŝĐƐƚƌƵĐƚƵƌĞĂŶĚĐŚĞŵŝĐĂůďŽŶĚŝŶŐƚŚĂƚunderlie the diverse behavior of the elements. The physical and mathematical foundations of atomic

orbitals and their use in constructing molecular orbitals will be examined, including the use of group

theory to predict the form of molecular orbitals in various molecular symmetries. These concepts will be

illustrated with classic examples of inorganic compounds along with recent examples drawn from the

primary literature. Thus, students will develop a strong intuitive understanding of molecular orbital theory

as it applies in many common areas of research.

Specific Objectives

1) ĞŝŶĨŽƌĐĞƐƚƵĚĞŶƚƐ͛ƵŶĚĞƌƐƚĂŶĚŝŶŐŽĨŵĂƚĞƌŝĂůĨƌŽŵƵŶĚĞƌŐƌĂĚƵĂƚĞĐŽƵƌƐĞƐŝŶŝŶŽƌŐĂŶŝĐĐŚĞŵŝƐƚƌLJ

and chemical bonding (e.g. atomic structure, molecular orbital theory, acid/base chemistry,

spectroscopy, coordination chemistry of transition metals, solid state chemistry, etc.)

2) Develop a stronger understanding of the mathematical and physical foundations of atomic

structure and quantum mechanical theories of chemical bonding

3) Develop a stronger understanding of molecular orbital theory as it applies to a wide range of

elements, especially those in the d-block of the periodic table (i.e. transition metals).

4) Demonstrate mastery of the course material by using knowledge gained in this course to analyze

the primary chemical literature.

Course Policies

Grades, Presentations, and Examinations: There will be three exams, each worth 100 pts towards a 450

pt total in this course. The exams can be completed on your own time, with a specific date listed below.

Exams will be released at least one week before the due date.

Part of the course grade will also consist of class participation and in-class presentations, worth a total of

175 pts. Students will be required to present solutions to select suggested homework questions (75 pts).

Each student will also be required to give a final presentation of a paper from the recent or classic

literature, worth 100 pts.

Tentative Class Schedule Fall Semester 2018

Day Date Lecture # Topic Chapter (Sections)

W 9/2 1 Introduction 2.1

T 9/8 2 Quantum Mechanics and Atomic Structure 2.2

W 9/9 3 QM/Atomic Structure/Periodic Trends 2.3

M 9/14 4 Molecular Orbital Theory 5.1

W 9/16 5 Molecular Orbital Theory 5.2 5.3

M 9/21 6 Acidity 6.3 6.4

W 9/23 7 Lewis Acids 6.4 6.6

M 9/28 8

Group Theory

(no class one of these dates, tbd)

4.1 4.2

W 9/30

M 10/5 9 Group Theory 4.3 4.4

W 10/7 10 Group Theory and Molecular Orbitals 5.4

M 10/12 11 Exam 1 Due / Ligand Field Theory 10.3

W 10/14 12 Ligand Field Theory in Other Geometries 10.3 M 10/19 13 Jahn-Teller Distortion 10.5, supplement

W 10/21 14 Substitution Mechanisms 12.1 12.4

M 10/26 15 Mechanisms 12.6 12.7

W 10/28 16 Electron Transfer Mechanisms 12.8, supplement

M 11/02 17 Electronic Spectra 11.1, 11.2

W 11/04 18 Electronic Spectra 11.3

M 11/09 19 Characterization of Unpaired e- Supplement

W 11/11 20 review

M 11/16 21 Exam 2 due / Solid State Chemistry 7.1

W 11/18 22 Solid State Chemistry 7.2, 7.3

M 11/23 23 Solid State Chemistry

W 11/25 No Class

M 11/30 24 Additional Topics / Student Presentations TBA W 12/2 25 Additional Topics / Student Presentations TBA M 12/7 26 Additional Topics / Student Presentations TBA W 12/9 27 Additional Topics / Student Presentations TBA

W 12/16 Exam 3 Exam 3 due


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