Material Safety Data Sheet

Butanol

21 Jan 2009 1. Identification. Product Name. 1-Butanol (Spectranalyzed). Cat No. : ... Category 1. Specific target organ toxicity (single exposure).

Right to Know Hazardous Substance Fact Sheet

Chemical Name: 1-Butanol Sheet (MSDS) and the label to determine product ... Very toxic chemicals or those that are reproductive hazards or.

Environmental Health Criteria 65 BUTANOLS: FOUR ISOMERS - 1

However some protozoa are slightly sensitive to 1-butanol and it should be managed in the environment as a slightly toxic compound.

Biopesticides Fact Sheet for 2-Methyl-1-butanol

on file with the Agency confirm its non-toxic mode of action as a biochemical pesticide. As a biochemical active ingredient 2-Methyl-1-butanol is intended

Technical Document for 2-Methyl-1-butanol also referred to as a BRAD

19 Jan 2010 registration of 2-Methyl-1-butanol. Acute toxicity data from the Hazardous Substances Data. Bank provided sufficient information to satisfy ...

3-Methoxy-3-methyl-1-butanol CAS N°: 56539-66-3

08 Dec 2004 In an acute oral toxicity study [OECD TG 401] Crj:CD SD rats (5 animals/sex/dose) were given MMB by gavage at 0

Butyl Alcohol (n-) (1-Butanol)

https://www.columbuschemical.com/MSDS/SDS/Butyl%20Alcohol

Hazardous Substance Fact Sheet

Chemical Name: 1-Butanol 3-Methyl- National Response Center: 1-800-424-8802 ... Very toxic chemicals

Material Safety Data Sheet - 1-Butanol MSDS

10 Oct 2005 1-Butanol MSDS. Section 1: Chemical Product and Company Identification. Product Name: 1-Butanol. Catalog Codes: SLB3157 SLB1489.

SAFETY DATA SHEET

25 Nov 2021 SECTION 1: Identification of the substance/mixture and of the company/ ... Specific target organ toxicity - single exposure (Category 3) ...

13_81_butanol.pdf

MaterialSafety DataSheet

1-ButanolMSDS

Section1: ChemicalProductand CompanyIdentification

ProductName: 1-Butanol

CatalogCodes: SLB3157,SLB1489

CAS#:71-36-3

RTECS:EO1400000

TSCA:TSCA8(b) inventory:1-Butanol

CI#:Notapplicable.

Synonym:Propylcarbinol

ChemicalName: N-Butylalcohol

ChemicalFormula: CH3(CH2)2CH2OH

ContactInformation:

Sciencelab.com,Inc.

14025Smith Rd.

Houston,Texas 77396

USSales: 1-800-901-7247

InternationalSales: 1-281-441-4400

OrderOnline: ScienceLab.com

CHEMTREC(24HR EmergencyTelephone),call:

1-800-424-9300

InternationalCHEMTREC, call:1-703-527-3887

Fornon-emergency assistance,call:1-281-441-4400

Section2: CompositionandInformation onIngredients

Composition:

NameCAS# %by Weight

{1-}Butanol71-36-3100

ToxicologicalData onIngredients:1-Butanol:ORAL (LD50):Acute:790 mg/kg[Rat.].DERMAL (LD50):Acute:3400 mg/kg

[Rabbit.].

Section3: HazardsIdentification

PotentialAcute HealthEffects:

Veryhazardous incaseof skincontact(irritant, permeator),ofeye contact(irritant),of ingestion,ofinhalation.

Slightlyhazardous incaseof skincontact(sensitizer). Inflammationofthe eyeischaracterized byredness, watering,and itching.Skininflammation ischaracterizedby itching,scaling,reddening, or,occasionally, blistering.

PotentialChronic HealthEffects:

CARCINOGENICEFFECTS: Notavailable.

MUTAGENICEFFECTS: Notavailable.

TERATOGENICEFFECTS: Notavailable.

DEVELOPMENTALTOXICITY: Notavailable.

Repeatedor prolongedexposureis notknownto aggravatemedicalcondition. p.1

Section4: FirstAidMeasures

EyeContact:

Checkfor andremoveany contactlenses.Immediately flusheyeswith runningwaterfor atleast15 minutes, keepingeyelids open.Coldwater maybeused. Getmedicalattention immediately.

SkinContact:

Incase ofcontact,immediately flushskinwith plentyofwater foratleast 15minuteswhile removingcontaminated

clothingand shoes.Coverthe irritatedskinwith anemollient.Cold watermaybe used.Washclothingbefore reuse.Thoroughly cleanshoesbefore reuse.Getmedical attentionimmediately.

SeriousSkin Contact:

Washwith adisinfectantsoap andcoverthe contaminatedskinwith ananti-bacterialcream. Seekimmediate medicalattention.

Inhalation:

Ifinhaled, removetofresh air.Ifnot breathing,giveartificial respiration.Ifbreathing isdifficult,give oxygen.Get

medicalattention ifsymptomsappear.

SeriousInhalation:

Evacuatethe victimtoa safeareaas soonaspossible. Loosentightclothing suchasa collar,tie,belt or

waistband.If breathingisdifficult, administeroxygen.If thevictimis notbreathing,perform mouth-to-mouth

resuscitation.Seek medicalattention.

Ingestion:

DoNOT inducevomitingunless directedtodo sobymedical personnel.Nevergive anythingbymouth toan

unconsciousperson. Iflargequantities ofthismaterial areswallowed,call aphysicianimmediately. Loosentight

clothingsuch asacollar, tie,beltor waistband.

SeriousIngestion: Notavailable.

Section5: FireandExplosion Data

Flammabilityof theProduct:Flammable.

Auto-IgnitionTemperature: 343°C(649.4°F)

FlashPoints: CLOSEDCUP: 28.9°C(84°F).OPEN CUP:36.1°C(97°F) (Cleveland).

FlammableLimits: LOWER:1.4% UPPER:11.2%

Productsof Combustion:Theseproducts arecarbonoxides (CO,CO2).

FireHazards inPresenceof VariousSubstances:

Highlyflammable inpresenceof openflamesand sparks. Flammablein presenceofheat, ofoxidizingmaterials, ofreducingmaterials, ofcombustiblematerials.

ExplosionHazards inPresenceof VariousSubstances:

Risksof explosionofthe productinpresence ofmechanicalimpact: Notavailable. Risksof explosionofthe productinpresence ofstaticdischarge: Notavailable.

FireFighting MediaandInstructions:

Flammableliquid, solubleordispersed inwater.

SMALLFIRE: UseDRYchemical powder.

LARGEFIRE: Usealcoholfoam, watersprayor fog.Coolcontaining vesselswithwater jetinorder toprevent pressurebuild-up, autoignitionorexplosion. SpecialRemarks onFireHazards: Mayform explosivemixtureswith air.CAUTION:MAY BURNWITHNEAR INVISIBLE FLAME

SpecialRemarks onExplosionHazards: Notavailable.

p.2

Section6: AccidentalReleaseMeasures

SmallSpill:

Dilutewith waterandmop up,orabsorb withaninert drymaterialand placeinan appropriatewastedisposal container.

LargeSpill:

Flammableliquid.

Keepaway fromheat.Keep awayfromsources ofignition.Stop leakifwithout risk.Absorbwith DRYearth, sandor othernon-combustiblematerial. Donottouch spilledmaterial.Prevent entryintosewers, basementsor confinedareas; dikeifneeded. Becarefulthat theproductis notpresentat aconcentrationlevel aboveTLV.

CheckTLV ontheMSDS andwithlocal authorities.

Section7: HandlingandStorage

Precautions:

Keepaway fromheat.Keep awayfromsources ofignition.Ground allequipmentcontaining material.Donot

ingest.Do notbreathegas/fumes/ vapor/spray.Incase ofinsufficientventilation, wearsuitablerespiratory

equipment.If ingested,seekmedical adviceimmediatelyand showthecontainer orthelabel. Avoidcontactwith

skinand eyes.Keepaway fromincompatiblessuch asoxidizingagents, reducingagents.

Storage:

Storein asegregatedand approvedarea.Keep containerina cool,well-ventilatedarea. Keepcontainertightly

closedand sealeduntilready foruse.Avoid allpossiblesources ofignition(spark orflame).

Section8: ExposureControls/PersonalProtection

EngineeringControls:

Provideexhaust ventilationorother engineeringcontrolsto keeptheairborne concentrationsofvapors belowtheir

respectivethreshold limitvalue.Ensure thateyewashstations andsafetyshowers areproximalto the work-stationlocation.

PersonalProtection:

Splashgoggles. Labcoat.Vapor respirator.Besure tousean approved/certifiedrespiratoror equivalent.

Gloves.

PersonalProtection inCaseof aLargeSpill:

Splashgoggles. Fullsuit.Vapor respirator.Boots.Gloves. Aselfcontained breathingapparatusshould be

usedto avoidinhalationof theproduct.Suggested protectiveclothingmight notbesufficient; consultaspecialist

BEFOREhandling thisproduct.

ExposureLimits:

CEIL:152 (mg/m3)

Consultlocal authoritiesforacceptable exposurelimits.

Section9: PhysicalandChemical Properties

Physicalstate andappearance:Liquid.(Z)

Odor:Vinous.(Slight.)

Taste:Notavailable.

MolecularWeight: 74.12g/mole

Color:Colorless.

pH(1% soln/water):Notavailable. p.3

BoilingPoint: 117.7°C(243.9°F)

MeltingPoint: -89.5°C(-129.1°F)

CriticalTemperature: Notavailable.

SpecificGravity: 0.81(Water= 1)

VaporPressure: 0.6kPa (@20°C)

VaporDensity: 2.55(Air =1)

Volatility:Notavailable.

OdorThreshold: 1.2ppm

Water/OilDist. Coeff.:Notavailable.

Ionicity(in Water):Notavailable.

DispersionProperties: Seesolubility inwater,methanol, diethylether,n-octanol.

Solubility:

Easilysoluble inmethanol,diethyl ether.

Partiallysoluble incoldwater, hotwater,n-octanol.

Section10: StabilityandReactivity Data

Stability:Theproduct isstable.

InstabilityTemperature: Notavailable.

Conditionsof Instability:Notavailable.

Incompatibilitywith varioussubstances:

Highlyreactive withoxidizingagents, reducingagents. Slightlyreactive toreactivewith organicmaterials,acids, alkalis.

Corrosivity:Non-corrosivein presenceofglass.

SpecialRemarks onReactivity:Notavailable.

SpecialRemarks onCorrosivity:Notavailable.

Polymerization:Willnot occur.

Section11: ToxicologicalInformation

Routesof Entry:Dermalcontact. Eyecontact.Inhalation. Ingestion.

Toxicityto Animals:

WARNING:THE LC50VALUESHEREUNDER AREESTIMATEDON THEBASISOF A4-HOUREXPOSURE.

Acuteoral toxicity(LD50):790 mg/kg[Rat.].

Acutedermal toxicity(LD50):3400 mg/kg[Rabbit.].

Acutetoxicity ofthevapor (LC50):80004 hours[Rat.].

ChronicEffects onHumans:Notavailable.

OtherToxic EffectsonHumans:

p.4 Veryhazardous incaseof skincontact(irritant, permeator),ofingestion, ofinhalation. Slightlyhazardous incaseof skincontact(sensitizer). SpecialRemarks onToxicityto Animals:Notavailable. SpecialRemarks onChronicEffects onHumans:Cancause gastrointestinaldisturbances. SpecialRemarks onotherToxic EffectsonHumans: Exposurecan causenausea,headache andvomiting.

Section12: EcologicalInformation

Ecotoxicity:Notavailable.

BOD5and COD:Notavailable.

Productsof Biodegradation:

Possiblyhazardous shorttermdegradation productsarenot likely.However,long termdegradationproducts may

arise. Toxicityof theProductsof Biodegradation:Theproducts ofdegradationare moretoxic. SpecialRemarks ontheProducts ofBiodegradation:Notavailable.

Section13: DisposalConsiderations

WasteDisposal:

Section14: TransportInformation

DOTClassification: CLASS3: Flammableliquid.

Identification::Butanol UNNA:UN1120PG: III

SpecialProvisions forTransport:Notavailable.

Section15: OtherRegulatoryInformation

Federaland StateRegulations:

PennsylvaniaRTK: 1-Butanol

MassachusettsRTK: 1-Butanol

TSCA8(b) inventory:1-Butanol

OtherRegulations: OSHA:Hazardous bydefinitionof HazardCommunicationStandard (29CFR1910.1200).

OtherClassifications:

WHMIS(Canada):

CLASSB-2: Flammableliquidwith aflashpoint lowerthan37.8°C (100°F). CLASSD-2B: Materialcausingother toxiceffects(TOXIC).

DSCL(EEC):

R10-Flammable.

R22-Harmful ifswallowed.

R38-Irritating toskin.

R41-Risk ofseriousdamage toeyes.

HMIS(U.S.A.):

p.5

HealthHazard: 1

FireHazard: 3

Reactivity:0

PersonalProtection: h

NationalFire ProtectionAssociation(U.S.A.):

Health:1

Flammability:3

Reactivity:0

Specifichazard:

ProtectiveEquipment:

Gloves.

Labcoat.

Vaporrespirator. Besureto usean

approved/certifiedrespirator or equivalent.Wear appropriaterespirator whenventilation isinadequate.

Splashgoggles.

Section16: OtherInformation

References:-Manufacturer'sMaterial SafetyDataSheet.

OtherSpecial Considerations:Notavailable.

Created:10/10/200508:15 PM

LastUpdated: 11/06/200812:00 PM

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