[PDF] leay:block;margin-top:24px;margin-bottom:2px; class=tit employeesoneontaeduALCOHOLS: Properties & Preparation





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Alcohols Phenols and Ethers

discuss the reactions for preparation of ethers from. (i) alcohols and (ii) alkyl halides and sodium alkoxides/aryloxides;. • correlate physical properties of.



ALCOHOLS: Properties & Preparation

ALCOHOLS: Properties & Preparation. General formula: R-OH where R is alkyl or substitued alkyl. Ar-OH: phenol - different properties. Nomenclature.



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destabilizing the phenoxide ion (resonance effect). The location of the substituent relative to the phenol is important. 87. 17.4: Preparation of alcohols:.



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leay:block;margin-top:24px;margin-bottom:2px; class=tit employeesoneontaeduALCOHOLS: Properties & Preparation

ALCOHOLS: Properties & Preparation General formula: R-OH where R is alkyl or substitued alkyl Ar-OH: phenol - different properties Nomenclature 1 Common names: Name of alkyl group followed by word alcohol eg ethyl alcohol isopropyl alcohol 2 IUPAC: (a) Parent structure - longest chain containing -OH group: name by replacing -e of alkane



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Preparation of Tertiary Alcohols give a tertiary alcohol Example 2 CH 3 MgBr + (CH 3) 2 CHCOCH 3 O 1 diethyl ether 2 H 3 O+ (CH 3) 2 CHCCH 3 OH CH 3 (73 ) Two



Chapter 15: Alcohols Diols and Thiols 151: Sources of Alcohols

15 2: Preparation of Alcohols by Reduction of Aldehydes and Ketones - add the equivalent of H 2 across the ?-bond of the carbonyl to yield an alcohol RR' C O [H] R' H C O R H aldehyde (R or R´= H) ? 1° alcohol ketone (R and R´? H) ? 2° alcohol Catalytic hydrogenation is not typically used for the reduction of ketones or aldehydes to



ALCOHOLS: Properties & Preparation

ALCOHOLS: Properties & Preparation General formula: R-OH where R is alkyl or substitued alkyl Ar-OH: phenol - different properties Nomenclature 1 Common names: Name of alkyl group followed by word alcohol 2 Carbinol system: Alcohol is considered a derivative of CH3OH Name groups replacing methyl hydrogens add the suffix carbinol 3 IUPAC:



CHAPTER 7 ALCOHOLS THIOLS PHENOLS ETHERS

Both ethyl alcohol and isopropyl alcohol are synthesized by acid-catalyzedaddition of water to ethylene and propylene respectively CH2=CH2 3OCH3CH2OH HCH2=CHCH3 3OCH3CHCH3OHEthanol is also produced as a supplement of for auto fuels by fermentationthe carbohydrates found in grain The process gives ethanol that contains 5 waterafter distillation



Searches related to preparation of alcohol pdf filetype:pdf

7 4 1 Preparation of Alcohols Alcohols are prepared by the following methods: 1 From alkenes (i) By acid catalysed hydration: Alkenes react with water in the presence of acid as catalyst to form alcohols In case of unsymmetrical alkenes the addition reaction takes place in accordance with Markovnikov’s rule Mechanism

How are alcohols prepared?

    Alcohols may be prepared (1) by hydration of alkenes (i) in presence of anacid and (ii) by hydroboration-oxidation reaction (2) from carbonyl compounds by(i) catalytic reduction and (ii) the action of Grignard reagents.

How are phenols prepared?

    Phenols may beprepared by (1) substitution of (i) halogen atom in haloarenes and (ii) sulphonicacid group in aryl sulphonic acids, by –OH group (2) by hydrolysis of diazoniumsalts and (3) industrially from cumene. Alcohols are higher boiling than other classes of compounds, namelyhydrocarbons, ethers and haloalkanes of comparable molecular masses.

What is the intermediate in reaction of secondary and tertiary alcohols with hydrogen halides?

    The key intermediate in reaction of secondary and tertiary alcohols with hydrogen halides is a carbocation. The overall reaction mechanism involves three elementary steps; the first two steps lead to the carbocation intermediate, the third step is the conversion of this carbocation to the alkyl halide.

Does dehydration of alcohol give alkenes?

    Dehydration of alcohols gives alkenes. On oxidation, primary alcoholsyield aldehydes with mild oxidising agents and carboxylic acids with strongoxidising agents while secondary alcohols yield ketones. Tertiary alcohols areresistant to oxidation.
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