[PDF] Chapter 19 Redox Reactions and Electrochemistry Notes (answers)





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Jun 28 2010 · Chapter 20 Worksheet: Redox ANSWERS I Determine what is oxidized and what is reduced in each reaction Identify the oxidizing agent and the reducing agent also 1 2Sr + O2 2SrO Sr 0 to Sr2+; oxidized/reducing agent O0 to O2-; reduced/ox ag 2 2Li + S Li2S Li 0 to Li1+; oxidized/red ag S0 to S2-; reduced/ox ag 3

What is the difference between redox and electrochemistry?

    Electrochemistry is the study of how chemical reactions produce electrical energy and in turn how electrical energy causes chemical reactions. These chemical reactions involve transfer of electrons. A redox reaction is one in which reduction and oxidation processes occur simultaneously. Redox reactions involve electron gain and electron loss.

What are redox reactions?

    Any such reaction involves both a reduction process and a complementary oxidation process, two key concepts involved with electron transfer processes. Redox reactions include all chemical reactions in which atoms have their oxidation state changed; in general, redox reactions involve the transfer of electrons between chemical species.

How do you balance a redox reaction?

    There are two ways of balancing the redox reaction. One method is by using the change in oxidation number of oxidizing agent and the reducing agent, and the other method is based on dividing the redox reaction into two half reactions-one of reduction and another of oxidation.

What is the difference between a cathode and anode redox reaction?

    Each half-reaction that makes up a redox reaction has a standard electrode potential. This potential equals the voltage produced by an electrochemical cell in which the cathode reaction is the half-reaction considered, whereas the anode is a standard hydrogen electrode.
Unit 7: Redox Reactions and Electrochemistry Honour Chemistry Page 234. Copyrighted by Gabriel Tang B.Ed., B.Sc.

Unit 7: Redox Reactions and Electrochemistry

Chapter 19: Redox Reactions and Electrochemistry

4.4: Oxidation-Reduction Reactions

Reduction-Oxidation Reactions

(Redox Rxn): - chemical reactions where there is a transfer of electron(s). Oxidation States (Oxidation Number): - a number that is arbitrary assigned to an atom in an element, molecule, and polyatomic ions to account for the number of electrons in redox reaction.

Rules for Assigning Oxidation Numbers

1. Natural Elements (include diatomic and polyatomics) have an Oxidation Number of 0.

Examples: Na

s), O 2 (g) , O 3 (g) , H 2 (g) , F 2 (g) , P 4 (s) , and Hg (l) all have an oxidation number of 0.

2. Single Atomic Ions have an Oxidation Number Equals to its Charge.

Example: K

has an oxidation number of +1.

3. Oxygen in Binary Compound and Polyatomic Ions has an Oxidation Number of 2.

Examples: CO

2 , CO, SO 3 , SO 2 , CO 32
, SO 42
and H 2

O all have an oxidation number of 2 for oxygen.

An exception occurs in peroxides

(compound containing O 22
) where the oxygen has an oxidation number of 1.

4. Hydrogen in Binary Compounds and Polyatomic Ions has an Oxidation Number of +1.

Examples: H

2

O, HCl, HBr, CH

4 , NH 4+ and H 2 S all has an oxidation number of + 1 for hydrogen.

5. In Binary Compounds, the Atom that has the most attraction to electrons (HIGHER

Electronegativity) is assigned the NEGATIVE Oxidation Number . This Negative Oxidation

Number is the SAME as its Ionic Charge.

Examples: HF: F is more electronegative. Thus, F has an oxidation number of 1. NH 3 : N is more electronegative. Thus, N has an oxidation number of 3. H 2 S: S is more electronegative. Thus, S has an oxidation number of 2.

6. The Sum of all Oxidation Numbers is 0 for all Electrically Neutral Compounds.

Examples: CO: Oxidation numbers: O = 2; C = +2 [(+2) + (

2) = 0]

SO2 : Oxidation numbers: O = 2; S = +4 [(+4) + 2(2) = 0]

7. The Sum of all Oxidation Numbers is Equal to the Overall Charge for all Polyatomic Ions.

Examples: CO

32
: Oxidation numbers: O = 2; C = +4 [(+4) + 3(2) = 2] SO42 : Oxidation numbers: O = 2; S = +6 [(+6) + 4(2) = 2] Note: Same Atom from different chemical species might NOT have the Same Oxidation Number. We write the charges of ionic species as n+ or n. Oxidation numbers are written as +n or n. Honour Chemistry Unit 7: Redox Reactions and Electrochemistry

Copyrighted by Gabriel Tang B.Ed., B.Sc. Page 235.

Example 1: Find the oxidation number for all atoms in each of the following elements or compounds: a. NiO 2 b. P 4 O 10 c. N 2 d. SF 4 e. N 2 H 4 f. Fe 3 O 4 g. KMnO 4 h. Na 2 C 2 O 4 or Na 2

OOCCOO i. XeOF

4 Example 2: Find the oxidation number for all atoms in each of the following polyatomic ions. a. OCl b. ClO 2 c. ClO 3 d. ClO 4 e. NO 2 f. NO 3 g. UO 22+
h. S 2 O 32
i. Cr 2 O 72

Oxidation Reactions

: - reactions that LOSE Electrons (LEO - "Losing Electrons" - Oxidation) or an

INCRESE (Oxidation) in Oxidation Number

- an INCREASE in the number of Oxygen Atoms in the species is a sign of oxidation reaction. - a DECREASE in the number of HYDROGEN atoms in the species is a sign of oxidation reaction.

Examples: Fe

(s) Fe

3+(aq)

+ 3e (Lost 3 Electrons - Oxidation)

0 to +3 (Increased Oxidation Number - Oxidation)

2 Cr

3+(aq)

+ 7 H 2 O (l) Cr 2 O

72(aq)

+ 14 H +(aq) + 6e (Lost 6 Electrons - Oxidation) +3 to +6 (Increased Oxidation Number - Oxidation)

Oxidation Numbers: O = 2

Ni: n + 2(2) = 0 n = +4 Oxidation Numbers: O = 2

P: 4n + 10(2) = 0 n = +5 Oxidation Numbers:

N 2

Diatomic Element n = 0

Oxidation Numbers: F = 1

S: n + 4(1) = 0 n = +4 Oxidation Numbers: H = +1 N: 2n + 4(+1) = 0 n = 2 Oxidation Numbers: O = 2

Fe: 3n + 4(2) = 0 n = +

38

Oxidation Numbers:

O = 2 K = +1

Mn: (+1) + n + 4(2) = 0

n = +7 Oxidation Numbers:

O = 2 Na = +1

C: 2(+1) + 2n + 4(2) = 0

n= +3Oxidation Numbers:

O = 2 F = 1

Xe: n + (2) + 4(1) = 0

n= +6

Oxidation Numbers: O = 2

Cl: (2) + n = 1 n = +1 Oxidation Numbers: O = 2

Cl: n+ 2

(2) = 1n= +3

Oxidation Numbers: O = 2

Cl: n + 3

(2) = 1n= +5

Oxidation Numbers: O = 2

Cl: n + 4(2) = 1 n = +7 Oxidation Numbers: O = 2 N: n + 2(2) = 1 n = +3 Oxidation Numbers: O = 2

N: n + 3(2) = 1 n = +5

Oxidation Numbers: O = 2

U: n + 2

(2) = +2 n = +6

Oxidation Numbers: O = 2

S: 2n+ 3

(2) = 2 n= +2

Oxidation Numbers: O = 2

Cr: 2n + 7(2) = 2 n = +6

Unit 7: Redox Reactions and Electrochemistry Honour Chemistry Page 236. Copyrighted by Gabriel Tang B.Ed., B.Sc. Reduction Reactions : - reactions that GAIN Electrons (GER - "Gaining Electrons" - Reduction) or a

DECRESE (Reduction) in Oxidation Number

- a DECREASE in the number of Oxygen Atoms in the species is a sign of reduction reaction. - an INCREASE in the number of HYDROGEN atoms in the species is a sign of reduction reaction.

Examples: F

2 (g) + 2e 2 F (aq) (Gained 2 Electrons - Reduction)

0 to 1 (Reduced Oxidation Number - Reduction)

MnO

4 (aq)

+ 8 H +(aq) + 5e Mn

2+(aq)

+ 4 H 2 O (l) (Gained 5 Electrons - Reduction) +7 to +2 (Reduced Oxidation Number - Reduction)

Half-Reactions

: - part of the redox reaction where it shows either the oxidation reaction or the reduction reaction. - electrons are usually present in either side of the half-reaction. - Oxidation half-reaction has Electrons on the Product Side (Losing Electrons). - Reduction half-reaction has Electrons on the Reactant Side (Gaining Electrons).

Oxidizing Agent

: - a chemical species that Accepts (Gains) Electrons from an Oxidized species. - it helps another species to oxidize but itself being reduced (gained electrons or decreased in oxidation number). - in another words, Reducing Species = Oxidizing Agent (GER-OA)

Reducing Agent

: - a chemical species that Donates (Lose) Electrons from a Reduced species. - it helps another species to reduce but itself being oxidized (lost electrons or increased in oxidation number). - in another words, Oxidizing Species = Reducing Agent (LEO-RA)

Example 2: Classify if the following reactions are redox reaction. For each of the redox reaction identified,

label the reducing agent and oxidizing agent. Propose a reduction half-reaction and oxidation half-reaction. a. 4 Al (s) + 3 O 2 (g) 2 Al 2 O 3 (s) b. HCl (aq) + NaF (aq) HF (aq) + NaCl (aq) 4 Al (s) + 3 O 2 (g) 2 Al 2 O 3 (s) Oxygen Oxidation #: 0 to 2 (Reduction) Aluminium Oxidation #: 0 to +3 (Oxidation)

Oxidizing Agent = O

2 (g)

Reducing Agent = Al

(s)

Oxidation Half-Reaction: Al

(s) Al 3+ + 3e (Losing Electrons)

Reduction Half-Reaction: O

2 (g) + 4e 2 O 2 (Gaining Electrons) HCl (aq)quotesdbs_dbs6.pdfusesText_12
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