[PDF] CHEMISTRY (043) Class XI b) Study the shift in





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b) Study the shift in equilibrium between [Co(H2O)6]2+ and chloride ions by changing the concentration of either of theions. Page 3. CLASS -XII. S No. Unit.



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CHEMISTRY (043)

Class XI

S No Unit Portion to be Reduced

1 Some Basic

Concepts of

Chemistry Nature of matter, laws of chemical combination, Dalton's atomic theory: concept of elements, atoms and molecules.

2 Structure of Atom Discovery of Electron, Proton and Neutron, atomic number,

isotopes and isobars. Thomson's model and its limitations. Rutherford's model and its limitations 3 Classification of

Elements and

Periodicity in

Properties Significance of classification, brief history of the development of periodic table, 4 Chemical Bonding and Molecular

Structure --

5 States of Matter:

Gases and Liquids liquefaction of gases, critical temperature, kinetic energy and molecular speeds (elementary idea), Liquid State- vapour pressure, viscosity and surface tension (qualitative idea only, no mathematical derivations)

6 Chemical

Thermodynamics Heat capacity and specific heat capacity, Criteria for equilibrium

7 Equilibrium hydrolysis of salts (elementary idea), Henderson Equation

8 Redox Reactions applications of redox reactions 9 Hydrogen Preparation, properties and uses of hydrogen, hydrogen peroxide -

preparation, reactionsand structure and use;

10 s -Block Elements Preparation and Properties of Some Important Compounds:

Sodium Carbonate, Sodium Chloride, Sodium Hydroxide and Sodium Hydrogen carbonate, Biological importance of Sodium and Potassium. Calcium Oxide and Calcium Carbonate and their industrial uses, biological importance of Magnesium and Calcium.

11 Some p -Block

Elements Some important compounds: Borax, Boric acid, Boron Hydrides, Aluminium: Reactions with acids and alkalies, uses. Carbon: uses of some important compounds: oxides. Important compounds of Silicon and a few uses: Silicon Tetrachloride,

Silicones, Silicates and Zeolites, their uses.

12 Organic Chemistry:

Some basic

Principles and

Techniques methods of purification, qualitative and quantitative analysis 13 Hydrocarbons free radical mechanism of halogenation, combustion

and pyrolysis.

14 Environmental

Chemistry Entire chapter

Practical

The following portion to be deleted

C. Experiments based onpH

a) Any one of the following experiments: varied concentrations of acids, bases and salts using pH paper or universal indicator. b) Study the pH change by common-ion in case of weak acids and weak bases.

D. Chemical Equilibrium

One of the following experiments:

a) Study the shift in equilibrium between ferric ions and thiocyanate ions by increasing/decreasing the concentration of either of theions. b) Study the shift in equilibrium between [Co(H2O)6]2+ and chloride ions by changing the concentration of either of theions.

CLASS -XII

S No Unit Portion to be Reduced

1 Solid State Electrical and magnetic properties. Band theory of metals,

conductors, semiconductors and insulators and n and p type semi conductors.

2 Solutions Abnormal molecular mass, Van't Hoff factor

3 Electrochemistr

y Lead accumulator, fuel cells, corrosion, law of electrolysis (elementary idea), dry cell- electrolytic cells and Galvaniccells,

4 Chemical

Kinetics Concept of collision theory (elementary idea, no mathematical treatment), activation energy, Arrhenius equation.

5 Surface

Chemistry emulsion - types of emulsions, catalysis: homogenous and heterogeneous, activity and selectivity of solid catalysts; enzyme catalysis,

6 General

Principles and

Processes of

Isolation of

Elements Entire unit

7 p-Block

Elements Preparation and properties of Phosphine, Sulphuric Acid: industrial process of manufacture, Oxides of Nitrogen (Structure only); Phosphorus - allotropic forms, compounds of Phosphorus: Preparation and properties of Halides and

Oxo acids (elementary idea only).

8 d and f Block

Elements Chemical reactivity of lanthanoids, Actinoids -Electronic configuration, oxidation states and comparison with lanthanoids.

Preparation and properties of KMnO

4 and K 2 Cr 2 O 7

9 Coordination

Compounds Structure and stereoisomerism, importance of coordination compounds (in qualitative analysis, extraction of metals and biological system).

10 Haloalkanes

and Haloarenes Uses and environmental effects of -dichloromethane, trichloromethane, tetrachloromethane, iodoform, freons, DDT.

11 Alcohols,

Phenols and

Ethers uses with special reference to methanol and ethanol.

12 Aldehydes,

Ketones and

Carboxylic

Acid ---

13 Amines Diazonium salts: Preparation, chemical reactions and

importance in synthetic organic chemistry.

14 Biomolecules Oligosaccharides (sucrose, lactose, maltose), polysaccharides

(starch, cellulose, glycogen), importance of carbohydrates. Vitamins- classification and functions. Enzymes. Hormones -

Elementary idea excluding structure.

15 Polymers entire chapter

16 Chemistryin

Everydaylife entire chapter

Practical

Following portions should be considered deleted.

A. Surface Chemistry

a. Preparation of one lyophilic and one lyophobic sol Lyophilic sol - starch, egg albumin and gum Lyophobic sol - aluminium hydroxide, ferric hydroxide, arsenous sulphide. b. Dialysis of sol-prepared in (a)above. c. Study of the role of emulsifying agents in stabilizing the emulsion of different oils.

B. Chemical Kinetics

a. Effect of concentration and temperature on the rate of reaction between Sodium

Thiosulphate and Hydrochloric acid.

b. Study of reaction rates of any one of the following: i) Reaction of Iodide ion with Hydrogen Peroxide at room temperature using different concentration of Iodideions. ii) Reaction between Potassium Iodate, (KIO3) and Sodium Sulphite: (Na2SO3)using starch solution as indicator (clock reaction). C. Thermo chemistry Any one of the following experiments i) Enthalpy of dissolution of Copper Sulphate or Potassium Nitrate. ii) Enthalpy of neutralization of strong acid (HCI) and strong base(NaOH). iii) Determination of enthaply change during interaction (Hydrogen bond formation) between

Acetone and Chloroform.

D. Electrochemistry Variation of cell potential in Zn/Zn 2+|| Cu2+/Cu with change in concentration of electrolytes (CuSO4 or ZnSO4) at room temperature. G. Preparation of Organic Compounds Preparation of any one of the following compounds i) Acetanilide ii) Di-benzal Acetone iii) p-Nitroacetanilide

Aniline yellow or 2 - Naphthol Anilinedye

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