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Benzidine and its salts: supporting documentation provided by

Rotterdam Convention on the Prior Informed. Consent Procedure for Certain Hazardous. Chemicals and Pesticides in International Trade.



Report of the Chemical Review Committee on the work of its first

18 févr. 2005 Rotterdam Convention. C. Notification for benzidine (CAS No 92-87-5) and benzidine dihydrochloride (CAS No. 531 85-1) from Canada.



1 Proposed Control of Chemicals Under Review by Multilateral

Pollutants (POPs)1 and the Rotterdam Convention (RC) on the Prior Informed Consent (PIC). Procedure2. As the Competent Authority (i) Benzidine and its.



L 201/60 Official Journal of the European Union 27.7.2012

4 juil. 2012 in the Convention namely as pesticides or chemicals ... (a) implement the Rotterdam Convention on the Prior ... Benzidine and its salts.



Règlement (UE) no 649/2012 du Parlement européen et du Conseil

4 juil. 2012 a) de mettre en œuvre la convention de Rotterdam sur la procédure de consentement préalable en connaissance ... Dérivés de la benzidine (+).



Publications Office

20 avr. 2022 Le règlement (UE) no 649/2012 met en œuvre la convention de Rotterdam sur la procédure de consentement ... Dérivés de la benzidine (+).



CIRCULAIRE PIC LIII (53) – juin 2021

La dixième réunion de la Conférence des Parties à la Convention de Rotterdam (COP-10) (séance en présentiel) provisoirement prévue en juin 2022 (sous 



ADDITIONAL HAZARDOUS SUBSTANCES CONTROLLED UNDER

20 sept. 2019 Following from updates to the Stockholm Convention (SC) and Rotterdam Convention ... Benzidine and its salts;. (v). Bis(chloromethyl)ether;.



Ordinance on the Rotterdam Convention on the Prior Informed

1 janv. 2021 and in implementation of the Rotterdam Convention on the Prior Informed Consent ... Benzidine and its salts. 92-87-5. Industrial chemical.



COMMISSION REGULATION (EC) No 777/2006 of 23 May 2006

23 mai 2006 of the Parties to the Rotterdam Convention decided to ... Atrazine Azinphos-ethyl

1 Proposed Control of Chemicals Under Review by Multilateral Environmental

Agreements

Introduction

Singapore is a Party to the Stockholm Convention (SC) on Persistent Organic Pollutants (POPs)1 and the Rotterdam Convention (RC) on the Prior Informed Consent (PIC) Procedure2. As the Competent Authority (CA) for the implementation of the obligations to the Conventions, the National Environment Agency (NEA) lists of chemicals of concern, and controls them as Hazardous Substances (HS) under the Environmental Protection and Management Act (EPMA) and EPM (Hazardous Substances) (HS) Regulations. This allows NEA to implement the necessary licensing controls to fulfil

2 The SC and RC have identified 11 new chemicals for review. Singapore would like to

notify WTO Members on the proposal to control these chemicals as HS under the EPMA and

EPM (HS) Regulations.

Proposed Chemicals for Control

3 The 9th Conference of Parties (COP-9) for SC and RC, to be held from 28 Apr to 10

May 2019, will be considering the inclusion of these 11 new chemicals for control. Should would have to take effect within 1 year. The tabulation below shows a summary of the chemicals for listing as (a) a POP under the Annexes of the SC or (b) as a chemical subject to PIC procedure under Annex III of the RC. More details on the chemicals are appended in the Annex. Conventions Stockholm Convention (SC) Rotterdam Convention (RC)

Proposed

Chemicals for

Control

Industrial Chemicals

(i) Pentadecafluorooctanoic acid (PFOA), its salts and

PFOA-related

compounds (ii) Perfluorohexane sulfonic acid (PFHxS), its salts and PFHxS related compounds

Industrial Chemicals

(i) Benzidine and its salts (ii) Bis(chloromethyl) ether

Pesticide/Insecticides/

Herbicides

(i) Acetochlor (ii) Paraquat and its salts (iii) Lambda- cyhalothrin (iv) Atrazine (v) Dinoterb (vi) Amitraz (vii) Hexazinone

1 The Stockholm Convention on POPs is a global treaty to protect human health and the environment from

chemicals that persist for long periods of time in the environment, bio-accumulate through the food chain, have the

potential for long-range transboundary transport, and have harmful impacts on human health or the environment.

Further info and text on the Stockholm Convention on POPs can be found on the website: http://chm.pops.int

2 The Rotterdam Convention on the PIC Procedure aims to promote shared responsibility and cooperative efforts

among parties in the international trade of certain hazardous chemicals in order to protect human health and the

environment from potential harm and to contribute to their environmentally sound use. Further info and text on the

Rotterdam Convention on the PIC Procedure can be found on the website: http://www.pic.int 2

Obligations

under SC and RC (a) Prohibit the production, import, export and use of the chemicals listed in Annex A of SC; (b) Restrict the production and use of chemicals listed in

Annex B of SC; and

(c) Reduce or eliminate the unintentional releases of chemicals listed in Annex C of SC

Regulate the international trade of the

chemicals using the PIC procedure where the transboundary movement of the listed chemicals in Annex III of RC can only take place with the consent of the receiving country.

Proposed Regulatory Control

4 SC and RC when these 11 new

chemicals are included in the Annexes of the Conventions, NEA intends to list these chemicals as HS for licensing control under the EPMA and EPM (HS) Regulations. These chemicals have been assessed by the SC and RC to pose environmental and health impacts which warrant controls to be taken for public health reasons.

5 NEA plans to gazette the control of these 11 new chemicals under the EPMA and EPM

(HS) Regulations by June 2019. The licensing of the chemicals will take effect 6 months from the date of gazette. Importers, manufacturers and distributors of these chemicals and products containing these chemicals will then be required to apply for a HS licence/permit for the import, export, sale, store and use of the chemicals. 3 Annex

S/N Chemical Name &

Identity

Category Additional Information

(*Please note that the list of CAS numbers is not exhaustive)

Common Uses

Review under Stockholm Convention

1 Pentadecafluorooctanoic

acid (PFOA) (CAS No.

335-67-1), its salts and

PFOA-related

compounds

Industrial Examples of PFOA salts*:

acid, ammonium salt (CAS No. 3825-26-1) acid, sodium salt (CAS No. 335-95-5) acid, potassium salt (CAS No. 2395-00-8) acid, silver salt (CAS No. 335-93-3)

Octanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-

pentadecafluoro-, chromium(3+) (CAS No. 68141-02-6)

Ethanaminium, N,N,N-triethyl-, salt with

pentadecafluorooctanoic acid (1:1) (CAS No. 98241-25- 9)

PFOA, its salts and

PFOA-related compounds

are commonly used in the production of fluoroelastomers and fluoropolymers.

PFOA-related compounds

are commonly used as surfactants and surface treatment agents in textiles, papers and paints, firefighting foams. PFOA-related compounds refer to any linear or branched perfluoroheptyl derivative with the formula C7F15-X, other than

PFOA and PFOA salts, and any linear or branched

perfluorooctyl derivative with the formula C8F17-X.

Examples of PFOA-related compounds*:

Fluorotelomer alcohols

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-

Heptadecafluordecan-1-ol (CAS No. 678-39-7)

4

S/N Chemical Name &

Identity

Category Additional Information

(*Please note that the list of CAS numbers is not exhaustive)

Common Uses

Fluorotelomer acrylates, 8:2 Fluorotelomer acrylate (CAS No. 27905-45-9)

Polyfluoroalkyl phosphoric acid diesters, 8:2

Fluorotelomer phosphate diester (CAS No. 678-41-1) Perfluorinated Iodides, Perfluorooctyl iodide (CAS No.

507-63-1)

2 Perfluorohexane sulfonic

acid (PFHxS) (CAS No.

355-46-4), its salts and

PFHxS related

compounds

Industrial Examples of PFHxS salts*:

Perfluorohexanesulfonate ammonium salt

(CAS No. 68259-08-5) Perfluorohexanesulfonate potassium (CAS No. 3871-99- 6)

PFHxS, its salts and

PFHxS related

compounds are commonly used in consumer goods such as carpets, leather, apparel, textiles, firefighting foam, papermaking, printing inks, sealants, non-stick cookware.

Examples of PFHxS-related compounds*:

Perfluorohexane sulfonyl fluoride (CAS No. 423-50-7)

Perfluorohexane sulfonamide (CAS No. 41997-13-1)

Potassium N-ethyl-N-[(tridecafluorohexyl)sulfonyl]- glycinate (CAS No. 67584-53-6)

Review under Rotterdam Convention

3 Benzidine (CAS No. 92-

87-5) and its salts

Industrial Example of Benzidine salts*:

Benzidine dihydrochloride (CAS No. 531-85-1)

manufacture of dyes, pigments, plastic films and as a rubber compounding agent for the manufacture of rubber compounds

4 Bis(chloromethyl) ether

(CAS No. 542-88-1)

Industrial NIL manufacture of polymers,

surface treatment of vulcanized rubber and 5

S/N Chemical Name &

Identity

Category Additional Information

(*Please note that the list of CAS numbers is not exhaustive)

Common Uses

manufacture of flame retardant fabrics

5 Dinoterb

(CAS No. 1420-07-1)

Pesticide NIL used as herbicide and

rodenticide

6 Amitraz

(CAS No. 33089-61-1)

Pesticide NIL used as insecticide and

acaricide

7 Lambda-cyhalothrin

(CAS No. 91465-08-6)

Pesticide NIL used as insecticide

8 Atrazine

(CAS No. 1912-24-9)

Pesticide NIL used as herbicide

9 Paraquat (CAS No.

4685-14-7) and its salts

Pesticide Examples of Paraquat salts*:

Paraquat dichloride (CAS No. 1910-42-5)

Paraquat dichloride hydrate (CAS No. 75365-73-0)

Paraquat methosulfate (CAS No. 2074-50-2)

used as herbicide

10 Acetochlor

(CAS No. 34256-82-1)

Pesticide NIL used as herbicide

11 Hexazinone

(CAS No. 51235-04-2)

Pesticide NIL used as herbicide

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