[PDF] 4.41 TABLE 4.11 Bond Dissociation Energies The bond dissociation





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BC 335-4

01-Feb-2012 Texas A/S - Knullen 22 - DK-5260 Odense S – Denmark. Version 12.2. Tel. +45 6395 5555 - www.texas.dk - post@texas.dk. BC 335-4.



4.41 TABLE 4.11 Bond Dissociation Energies The bond dissociation

335(4). 343(4). 414(4). H9C(CH3)2CH"CH2. 331. H9cyclopentyl. 395(42). H9CH2C(CH3)3. 418(4). H9C6H5. 431. H9CH2C6H5. 356(4). H9C(C6H5)3.



The Law of Epikrates of 354/3 BC

Athenian law inscribed on a marble stele and enacted in 354/3 b.c. during the not in IG II3 part 4



Bioinformatics (BS)

ECOL 335 (4; S). ECOL 320 (SS; F; 4)____. ____. Major electives (22 units) EP or BC GE. 3. Total. 15 – 17. Semester 3. CHEM 241A + CHEM 243A.



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DID ARISTOTLE OWN A SCHOOL IN ATHENS BETWEEN 335/34

339/38 B. C.) he was not elevated to the scholarchate of the sometime between 335/4 and 323 ?. ? This then



The Athenian Calendar

3 335/4 " 24 Euainetos 0 The archons after 294/3 B. C. are dated as ... and 313/2 B. C. we find two successive intercalary years



The Macedonian Expeditionary Corps in Asia Minor (336–335 BC)

the winter of 335/4 was recalled by Alexander to Europe – likely to assist him in the preparation of the forthcoming expedition (Diod. 17.16.2).24.



Bronze Statues on the Athenian Acropolis: The Evidence of a

of the Acropolis proposed by Lycurgus in 335 B.C. and reflects a conscious policy of enhancement further



IG II2 1195 and Agathe Tyche in Attica

inscriptions of the last quarter of the 4th century B.C. Walbank (1989 pp. in 335/4

PROPERTIES OF ATOMS, RADICALS, AND BONDS4.41

TABLE 4.11Bond Dissociation Energies

The bond dissociation energy (enthalpy change) for a bond A9B which is broken through the reaction

AB:A?B

is defined as the standard-state enthalpy change for the reaction at a specified temperature, here at 298 K.

That is,

?Hf??Hf(A)??

Hf(B)??Hf(AB)298 298 298 298

All values refer to the gaseous state and are given at 298 K. Values of 0 K are obtained by subtractingRT

3 2 from the value at 298 K. To convert the tabulated values to kcal/mol, divide by 4.184. hSrg?Hf 298
kJ/molBond?Hf 298
kJ/mol iyAMsrAM iy9Al186(9) iy9As 180 iy9Au 326(6)iy9Br 439(8) iy9C 255 iy9Cl494(13) iyCy9Cl402(8) iyCy j

9Cl372(8)

iyR9Cl515(84) iy9Cu 216(10) iy9D 291 iy9F 664(6) iyt9F 546(42) iyt j

9F 544(46)

iyR9F 761(42) iy9H 285(6)iy9I 368(4) iy9Li 176(15) iy9N 297(96) iy9O 512(4) iyCy9O 540(41) iyt9O 582 iy9P 213(13) iy9Pd 259(12) iy9S 374(8) iy9Se 334(10) iy9Si 251(3) iy9Te 268(10) iy9U 326(29)ir,sMSrp nv9Sb 299(6) nv9Br 314(59) nv9Cl360(50) nv9F 439(96) nv9N 301(50) ir,sMSrp Ucontinued) nv9O 372(84) nv9P 357 nv9S 379 nv9Te 277.4(38) iDmNrsl im9As 382(11) im9Cl448 im9Ga 209.6(12)im9H 272(12) im9N 582(126) im9O 481(8) im9P 534(13) im9S (478) im9Se 96 im9Tl198(15) im,B,srN i,9At (115.9) hBDsAM hB9Br 370(8) hB9Cl444(13) hB9F 487(7)hB9I?431(4) hB9O 563(42) hB9OH 477(42) hB9S 400(19) hNDpyysAM hN9Be 59 hN9Br 381(84) hN9Cl388(9) dTi. >2:j86 Uul=;H4 fo=;c o.cTfiCco0T ,SF S1 DE vBmN S1 DE lBF ENsJE, vBmN S1 ,N?, mESD, m,BrgBDg ySrJ

4.42SECTION 4

TABLE 4.11Bond Dissociation Energies (Continued)

hSrg?Hf 298
kJ/molBond?Hf 298
kJ/mol hNDpyysAM Ucontinued) hNCy9Cl540(63) hN9F 577(42) hN9H 226(21) hN9O 448(21) hN9S 372(59) hsmMA,E hs9Bi 197(4) hs9Br 267(4) hs9Cl305(8) hs9D 284 hs9F 259(29) hs9Ga 159(17) hs9H 279 hs9O 343(6) hs9P 280(13) hs9Pb 142(15) hs9S 316(5) hs9Sb 251(4) hs9Se 280(6) hs9Te 232(11) hs9Tl121(13) hSDSr h9B 297(21) 2 h9BH 3 146

Rh9BO 506(84)

h9Br 435(21) h9C 448(29) h9Cl536(29) hR9Cl460(42) h9D 341(6) h9F 766(13) ht9F 523(63) ht j

9F 557(84)

h9H 330(4) h9I 384(21) h9N 389(21) h9O 806(5) hCy9O 715(41) h9P 347(17) h9S 581(9) h9Se 462(15) h9Si 289(29) h9Te 354(20) hDSMsrN hD9Br 193.870(4) hD9C 280(21) hD9CH 3

284(8)

hD9CH 2

Br 255(13)

hD9CHBr 2

259(17)

hD9CBr 3

209(13)

hD9CCl 3

218(13)

hD9CF 3

285(13)

hD9CF 2 CF 3

287.4(63)

hD9CF 2 CF 2 CF 3

278.2(63)

hD9CHF 2 289
hD9Cl218.84(4) hD9CN 381 hD9CO9C 6 H 5 268
hD9F 233.8(2) hD9N 276(21) hD9NF 2 222
hD9NO 120.1(63) hD9O 235.1(4)

CBgMsAM

Cg9Cd 11.3(8)

Cg9Br 159(96)

Cg9Cl206.7(34)

Cg9F 305(21)

Cg9H 69.0(4)

Cg9I 138(21)

Cg9In 138

Cg9O 142(42)

Cg9S 196

Cg9Se 310

CBylsAM

CB9Ca 14.98(46)

CB9Br 321(23)

CB9Cl398(13)

CB9F 527(21)

CB9H 167.8

CB9I 285(63)

CB9O 464(84)

CB9S 314(19)

CBDvSr

C9C 607(21)

2 C9CH 3 368
dTi. >2:j86 Uul=;H4aTtc o.cTfiCco0T ,SF S1 DE vBmN S1 DE lBF ENsJE, vBmN S1 ,N?, mESD, m,BrgBDg ySrJ

PROPERTIES OF ATOMS, RADICALS, AND BONDS4.43

TABLE 4.11Bond Dissociation Energies (Continued)

hSrg?Hf 298
kJ/molBond?Hf 298
kJ/mol

CBDvSr Ucontinued)

UC; 2 4 j C9CH 3 335
UC; 2 4 j

C9C(CH

3 2 282.4
C; 2 9C 6 H 5 389
C; 2 9CH 2 C 6 H 5 301
UC; 2 4 2 C9C(C 6 H 5 3 63
C; 2

9allyl 301

C; 2

9vinyl121

C; 2

9C#CH 490

C; j "CH9CH"CH 2 418
;C#C9C#CH 628 j C"CH 2 682
;C#CH 962 C; 2

9CN 506(21)

C; 2 9CH 2

CN 305(8)

C; 2

9CH(CH

3 )CN 331(8) C; 2 9C(C 6 H 5 )CN(CH 3 ) 251 C; 2 C; j 9CH 2

CN 321.8(71)

.C9CN 603(21) C 8 9 9C 6 H 5 418
C; 2 9CF 3

423.4(46)

C; j t9CH 2

F 368(8)

Ct 2 9CF 3

406(13)

Ct j "CF 2

318(13)

Ct 2

9CN 501

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