[PDF] 1 Determination of the Exchange Capacity of a Cation Ion





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37 Chapter 3: Ions Ionic Compounds

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1 Determination of the Exchange Capacity of a Cation Ion

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[PDF] Ionspdf - Plus de bonnes notes

18 avr 2021 · Le sérum physiologique Le sérum physiologique est en réalité une solution d'ions sodium et d'ions chlorure de formule chimique  

  • Quelle la formule de l'ion sodium ?

    La formule de l'ion sodium est Na+, sa configuration électronique est : 1s2 2s2 2p6. 3. La matière étant électriquement neutre, pour compenser les charges négatives de l'ion oxyde O2?, il faut dans le solide ionique Na2O deux fois plus d'ions sodium Na+ que d'ions oxyde O2?.
  • Quel est la charge de l'ion sodium ?

    Les ions sodium Na+ portent une charge +1. Les ions chlorure Cl? portent une charge ?1. La matière étant électriquement neutre, il y a autant d'ions sodium que d'ions chlorure dans le chlorure de sodium.
1 Determination of the Exchange Capacity of a Cation Ion

1 DeterminationoftheExchangeCapacityofaCationIon-ExchangeResinIntroductionIonexchangeisaprocessinwhichionsattachedtoahighmolecularweightpolymerareexchangedforotherionsinsolution.Thehighmolecularweightpolymerisnormallyintheformofsmall,roundspherescalledbeads.Ionexchangeresinsareusedtodemineralizewaterandtoseparatemixturesofions.Oneimportantcharacteristicofionexchangeresinisitscapacity,expressedintermsofmilliequivalentsofexchangeableionpergramofresin.Exchangecapacitycanbemeasuredbyexchangingsodiumion(Na+)forhydrogenform(H+initiallyattachedtotheresin).Thehydrogenionisthentitratedwithstandardsodiumhydroxidesolution.Theexchangereactioncanberepresentedas:2R-H++2Na+(aq)+SO4-2(aq)⇔2R-Na++2H+(aq)+SO4-2(aq)Intheequation,Rrepresentstheionexchangeresin.Thereactionisanequilibriumprocess(shownbythedouble-headedarrow,⇔)andcanbeforcedtocompletionbyusing"concentrated"sodiumsulfatesolution.Solutionsneededforthisexperiment:SolutionpreparedbythestudentSolutionsuppliedbytheinstructor0.5MsodiumsulfatePhenolphthaleinindicator0.1000Msodiumhydroxide(standardizedbystudent)Instructionsforpreparingandstandardizingsodiumhydroxidesolutionarefoundattheendofthisexperiment.

2 Specializedequipmentneeded:Youwillbeusingachromatographycolumn(Figure1).Thecolumnisassembledfromthreepieces;arelativelylongglasscolumn,avalveassembly,andadeliverytip.Beforeusingthecolumn,testitforleaksbyfillingitwithwater.Ifitleaks,tellyourinstructorsothattheproblemcanbecorrectedbeforeyoustarttheexperiment.Placeasmallplugofglasswoolatthebottomofthechromatographycolumn.Theglasswoolpreventsbeadsofionexchangeresinfrompluggingthevalveassembly.Figure1.Chromatographycolumnassembledandloadedwithionexchangeresin.

3 ExperimentalProcedureAir-dryingtheresin1. Transfer~1gramofcationexchangeresintoa150or250mLbeaker.Coverthebeakerwithawatchglass,andstoreitinyourequipmentlockerovernight.2. DONOTDRYTHERESININTHEOVEN!Loadingthechromatographycolumn1. Fillthecolumn~2/3fullwithdeionizedwater.Removeanyairbubblesfromthecolumnbygentlytappingthesideswithaglassstirringrod.2. Accuratelyweighasampleoftheairdriedresin(~0.9-1.0grams)ontheanalyticalbalance,andtransfertoa50mLbeaker.3. Addabout25mLofdeionizedwatertotheresin,andtransfertheresinslurrytothecolumn.UseawashbottlecontainingDIwatertocompletelytransferallresintothecolumn.4. Ifnecessary,apieceofrubbertubingcanbeattachedtothedeliverytip,applyingintermittentpressuretothetubingcausingthewaterlevelinthecolumntoriseandfall,expellingairbubbles.(Youwillofcoursehavetoopenthevalveforthistowork).5. Oncethecolumnhasbeenprepared,adjustthewaterlevelsothatitis~1cmabovethetopoftheresinbed.DoNOTallowthewaterleveltofallbelowthetopoftheresinbed.Ionexchange1. Prepare~300mLof0.5Msodiumsulfatesolutionbydissolving21.3gramsofsodiumsulfatein~280mLDIwater.2. Add~5mLofthesodiumsulfatesolutiontothecolumn,andadjustthevalvesothatthesolutionpassesthroughthecolumnatarateof2-3mL/minute.3. Addfreshsodiumsulfatesolutiontothecolumn,in5mLportions,justoftenenoughtokeeptheliquidlevelfromfallingbelowthetopoftheresin.4. Collecttheeffluent(theliquiddrainingfromthebottomofthecolumn)ina500-mLErlenmeyerflask.Whenall300mLofsodiumsulfatehasbeenpassedthroughthecolumn,pass50mLofdeionizedwaterthroughthecolumn,collectingthedeionizedwaterinthesameflaskastheeffluent.

4 Titration1. Usingstandardized0.1000Msodiumhydroxidesolution,titratetheentirecontentsofthe500-mLErlenmeyerflasktothephenolphthaleinendpoint.NOTE:yougettoperformthistitrationONCE,sobeextremelycareful!2. Theexchangecapacity,inmilliequivalents/gramofresin,iscalculatedusingtheformula:Capacity=mLNaOH ! MNaOHmassresinLabreport.Asamplereportisfoundattheendofthisexperiment.WASTEDISPOSAL:Allliquidwastescanbepoureddownthesink.Discardresininthetrashcan.

5 Preparationandstandardizationofsodiumhydroxidesolution.1. Dry~2gramsofpotassiumhydrogenphthalate(KHP)intheovenfor2hoursat110oC.Removefromtheovenandstoreinadesiccator.2. Prepare1literof0.1Nsodiumhydroxidebyadding~500mLofdeionizedwatertoaclean1literplasticbottle.Addeither4.0gramsofsolidsodiumhydroxide,or8.0grams(~5.3mL)of50%sodiumhydroxidesolution(NOTBOTH).Mixthecontentsuntilthesodiumhydroxideiscompletelydissolved,andthenfillthebottlewithdeionizedwater.Capthebottleandmixbyshaking.3. Usingananalyticalbalance,dispensethree0.5gramsamplesofKHPintoseparatebeakersorflasks.MakesureyourecordthemassofKHPusedtofourdecimalpoints.Addabout25mLofwatertoeachsample.TheKHPshouldcompletelydissolve,butifitdoesn'tDON'TWORRYABOUTIT.4. ToeachKHPsample,add2-3dropsofphenolphthaleinsolution.5. TitrateeachKHPsamplewithyoursodiumhydroxidesolutiontothefirst,palepinkendpointthatisstableforatleast10seconds(Figure1).Theentirecontentsofthebeaker/flaskmustbepalepink,andthepalestendpointpossibleisthemostdesirable.Recordthevolumeofsodiumhydroxidesolutionused.6. Sodiumhydroxideconcentrationisfoundfromtheequation:NNaOH=gramsKHPMWKHPmLNaOHwheremLNaOHarethemillilitersofsodiumhydroxideneededtoreachthephenolphthaleinendpoint.ThemolecularweightofKHP(KHC8H4O4)is204.2212g/mole.Labelyoursodiumhydroxidesolutionwiththeaverageconcentrationfromthreetitrations.

6 Figure1.Acorrectpalepinkendpoint,andexamplesofotherpossible(wrong)endpoints.

7 SAMPLEREPORT:ALLVALUESAREFICTIONALANDAREUSEDFORILLUSTRATIONONLY!!ExchangeCapacity,CationResinUnknown#2T.A.LeeStandardizationofNaOHsolutionMass,KHP(grams)0.51210.51200.5122mLNaOH25.0525.0024.95Normality,NaOH0.10010.10030.1005AverageNormality,NaOH0.1003Exchangecapacitydata:Massofresinused(grams,airdried):0.9885mLNaOHusedtotitrate:35.05NormalityNaOH:0.1003Exchangecapacity:3.556meq/gCalculation:Exchangecapacity=(mLNaOHXNNaOH)/massResin=(35.05X0.1003)/0.9885=3.556meq/g

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