25 COMPOUNDS OF CARBON CONTAINING HALOGENS
In this section you will learn the nomenclature of halogen derivatives of both aliphatic and aromatic hydrocarbons i.e. haloalkanes and haloarenes.
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10-Mar-2019 Let us discuss the chemistry of alkyl halides and aryl halides. NOMENCLATURE OF HALOALKANES AND HALOARENES. Naming haloalkanes (or alkyl ...
Haloalkanes
atom are named haloalkanes or in the common system of nomenclature
COMPOUNDS OF CARBON CONTAINING HALOGENS Y
In this section you will learn the nomenclature of halogen derivatives of both aliphatic and aromatic hydrocarbons. i.e. haloalkanes and haloarenes. 27.
Haloalkanes and Haloarenes Haloalkanes and Haloarenes
Haloalkanes and haloarenes may be classified as follows: of nomenclature alkyl halides are named as halosubstituted hydrocarbons.
CHEMISTRY (043) SYLLABUS FOR SESSION 2021-22 CLASS XI
Haloalkanes and Haloarenes: Haloalkanes: Nomenclature nature of C–X bond
Class: XII Subject: CHEMISTRY TERM-1 NO. OF PERIOD TOPIC
nomenclature of. Haloalkanes and. Haloarenes. Work-Sheet-10. Learners will be able to know how to write the trivial and. IUPAC name of Haloalkanes.
CHEMISTRY (Code No. 043) (2022-2023)
Unit X: Haloalkanes and Haloarenes. 15 Periods. Haloalkanes: Nomenclature nature of C–X bond
Haloalkanes and Haloarenes Haloalkanes and Haloarenes
Alkyl halides are named as halosubstituted hydrocarbons in the IUPAC system of nomenclature. Haloarenes are the common as well as IUPAC names of aryl halides.
Assignment Chapter 10: Haloalkanes and Haloarenes 1. Name the
Chapter 10: Haloalkanes and Haloarenes. 1. Name the following halides according to IUPAC system: (a) CH3CH(Br)CH=C(CH3)CH2Cl (b). C(CH3)2Br.
Assignment
Chapter 10: Haloalkanes and Haloarenes
1. Name the following halides according to IUPAC system:
(a) CH 3CH(Br)CH=C(CH
3 )CH 2Cl (b) C(CH
3 2 Br (c) CH 3 CH(CH 3 )CH(Br)CH3 (d) ClCH 2 C=CCH 2 Br (e) Cl----- (f) CH 3CH ŋ CI
2. What happens when bromine attacks CH
2 =CH-CH2-C ŋ CH ?
3. Write the structures of the following organic compounds:
(i) 2-Chloro-3-methylpentane (ii) 1-Chloro-4-ethylcyclohexane (iii) 2-(2-Chlorophenyl)-1-iodo octane (iv) 4-tert-Butyl-3-iodoheptane4. Answer the following questions:
(i) What is meant by chirality of the compound? Give an example. (ii) Which of the following compounds is more easily hydrolysed by KOH and why? CH3CH(Cl)CH
2 CH 3 or CH 3 CH 2 CH 2 Cl (iii) Which one undergoes S N2 faster and why?
I Cl Or5. Which one of the following reacts faster in an S
N1 reaction and why?
ClCl or
6. State one use of DDT and iodoform. Why chloroform is kept in dark coloured bottles
completely filled?7. What are ambident nucleophiles? Explain with the help of an example.
8. Write short notes on:
(a) Fittig reaction (b) Swartz reaction9. Account for the following:
i) tert-Butyl chloride reacts with aqueous NaOH by SN1 mechanism while n-butyl chloride
reacts by S N2 mechanism.
ii) Among HI, HBr and HCl, HI is most reactive. iii) Alkyl halides though polar, are immisible with water. iv) Chlorobenzene is extremely less reactive towards nucleophillic substitution reaction.10 Carry out the following conversions:
i) 1-Chlorobutane to n-octane ii) Toluene to benzyl alcohol iii) Benzyl chloride to benzyl alcohol11. What will be the mechanism for the substitution of -Br by -OH in (CH
3 2C(Br)CH
2 CH 312. Identify the following compounds from A to T:
(a) CH 3 CH 2 CH 2Cl + NaI A A
heat (b) (CH 3 3CBr + KOH Ethanol, heat B
( c) CH 3CH(Br)CH
2 CH 3 + NaOH (aq) C ethanol (d) CH 3 CH 2Br + KCN D
(e) (CH 3 3CBr + H
2 O heat E C 2 H 5ONa, heat
(f) (CH 3 2CHCH(Br)CH
2 CH 3 F (g) CH 3 CH 2Cl + SbF
3 heat G (h) CH 2 =CHCH 2Br + H
2O H
(i) C 6 H 4 CH 2Cl + C
2 H 5ONa I
(j) CH 3 CH 2 CH 2OH + SOCl
2 J peroxide (k) CH 3 CH 2 CH=CH 2 + HBr K (l) CH 3CH=C(CH
3 2 + HBr L (m) Br + CH 3 NH 2 M CH 2 Br Cl 2 , FeCl 3 (n) OH N (o) CH 2 CH 2 OH + HBr O (p) CH(CH 3 2 + Br 2 heat P acetonequotesdbs_dbs17.pdfusesText_23[PDF] nominalisation des verbes
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