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1 1

Periodic Table

The periodic table is the most important chemistry reference there is.It arranges all the known elements in an informative array. Elements are arranged left to right and top to bottom in orderof increasing atomic number.

Periods

Groups

2Molecules

Molecules are compounds in which the elements are

in definite, fixed ratios and those atoms are held together usually by chemical bonds.

For example: water, glucose, and alanine.

Ions Ionis an electrically charged particle produced by either removing electrons from a neutral atom to give a positive ion (Cation) or adding electrons to a neutral atom to give a negative ion (anion). Note: When an ion is formed, the number of protons does not change.

3Example:What is the number of electrons

(e), neutrons (n) and protons (p) in the zinc ion ?

Answer:

number of protons = 30 number of neutrons = 65 - 30 = 35 number of electrons = 30 - 2 = 28)Zn(26530+

4Example: What is the number of electrons

(e), neutrons (n) and protons (p) in the chlorine ion ?

Answer:

number of protons = 17 number of neutrons = 35 - 17 = 18 number of electrons = 17+1 = 18)(-C lC lC lC l3 53
53
53
51
71
71
71
7

5Polyatomic ions

Name Formula Name Formula

Ammonium(NH41+)

Chlorate (ClO

31-)Bicrbonate(HCO31-)

Cyanide (CN

1-)Hydroxide(OH1-)

Nitrate (NO

31-)Nitrite(NO21-)

Permanganate (MnO

41-)Thiocyanate(SCN1--)

Carbonate (CO

32-)Chromate(CrO42-)

Dichromate (CrO

42-)Sulfate(SO42-)

Sulfite (SO

32-)

Phosphate (PO

43-)

6Chemical and structural Formulas

The chemical formulatells you how many of each type of atom are in a molecule. The structural formulatells you how many of each type of atoms are in a molecule and also how they are connected. For example, the chemical formula for ethanol is C

2H6Oand

The structural formula of ethanol is

Be carful,the chemical formula could be the same for different molecules, but the structural formula is unique.

The chemical formula for dimethyl ether is C

2H6Oand

The structural formula of dimethyl ether is:

2

7Empirical Formulas (simplest formula)• It shows the simplest whole number ratio

of atoms in a molecule. • For example, hydrogen peroxide's chemical formulais H

2O2, but its empirical formulais HO

formula Empericalx)formula Emperical of mass (g/mole) unknown ofweight Molecular ( FormulaMolecular ====

Write the different formulas for the glucose molecule The chemical formula for glucose is C6H12O6, but its empirical formula is CH

2O, and its structural formula is

8Naming compounds:The elements inside the periodic table are organized in

groups (column), where each group has common characteristics.

One of these common characteristics is the charge

(oxidation number), as the whole group tends to lose or gain certain number of electrons and form ion.

Group IA IIA IIIA IVA VA VIA VIIA VIII

A # electrons

1 2 3 4 3 2 1 0

Actionlose lose lose Lose/gain gain gain gain no

ExampleNa+Ca2+Al3+C4-or C4+N3-O2-Cl1-Ne

9

Element Name ion Type Name

Li

Lithium Li1+CationLithium ion

NaSodium Na1+CationSodium ion

MgMagnesium Mg2+CationMagnesium ion

CaCalcium Ca2+CationCalcium ion

AlAluminum Al3+CationAluminum ion

KPotassium K1+CationPotassium ion

ClChlorine Cl1-AnionChloride

BrBromine Br1-AnionBromide

SSulfur S2-AnionSulfide

OOxygen O2-AnionOxide

NNitrogen N3-AnionNitride

Pphosphors P3-AnionPhosphide

CCarbon C4-AnionCarbide

SiSilicon Si4-AnionSilicide

Common ions and their names

10Rules for naming compounds:- The cation is named first and the anion is named second- Be sure the net charge is ZERO

-P.S. For Ionic compounds that contain transition metals cations (more than one possible oxidation state), write the oxidation state between two bracket.Ionic compounds (compounds contain cations and anions)

Compound Name Compound Name

AlCl

3Aluminum ChlorideNa2SSodium Sulfide

K

2OPotassium Oxide MgH2Magnesium Hydride

FeOIron (II) Oxide Fe

2O3Iron (III) Oxide

CaCO

3Calcium CarbonateAlPO4Aluminum Phosphate

Zn(OH)

2Zinc HydroxideKMnO4Potassium Permanganate

CuSO

4Copper (II) SulfateAgNO3Silver Nitrate

Example: Write the names for the following molecules:AlCl3, Na2S, K2O, MgH2, FeO, Fe2O3, CaCO3, AlPO4, Zn(OH)2, KMnO4, CuSO4,

AgNO 3.

Answer:

11How to write the formula:1- Identify the symbol for both cation and anion.2- Writethem and the charge underneath them.3- Remove the charge (+ or -), and leave the number.4- Exchange the numbers5- Make the numbers as simple as possible (exact number andno fractions).6- Writethe formula using the final numbers from step 5.

12 Example: Write the chemical formula for Calcium sulfate, Aluminum oxide, Iron(II) nitrate.

Answer:

Calcium sulfate

Using the above mentioned method:

1- Calcium is Ca

2+, and sulfate is (SO42-)

2- Write them and the charge underneath them

Ca (SO

4) 2+2-

3- Remove the charge Ca (SO4)

22

4- Exchange the numbers Ca (SO4)

22

5- Divide both numbers by 2: Ca (SO4)

11

6- Write the formula:

Ca

1(SO4)1orCaSO4

3

13Naming Covalent compoundsCovalent compounds contain no charge and they are formed from non-

metals located at the right hand side of the periodic table.The number of the atoms must be writtenbefore the name of the elementusing the following prefix(Drop a prefix is if themonois to appear at the beginning of the name).

Number of atoms Prefix Number of atoms Prefix

oneMono-TwoDi-

ThreeTri-FourTetra-

FivePenta-SixHexa-

14

Name Formula Name Formula

Carbon dioxideCO

2sulfur trioxideSO3

dihydrogen monoxide H2O dihydrogen monoxide H2O phosphorous trichloridePCl

3nitrogen dioxide NO2

Example:Write the Chemical formula for: Carbon dioxide, sulfur trioxide, dihydrogen monoxide, phosphorous trichloride,nitrogen dioxide.

Answer:

Example: Write the names for the following molecules: CO, N2O4,

NO, SO

2, PCl5Answer:

Compound Name Compound Name

COCarbon monoxideN2O4Dinitrogen tetraoxide

NONitrogen monoxideSO

2Sulfur dioxide

PCl

5Phosphorus pentachlorideHBrHydrogen monochloride

15

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