Nouvelles réactions de contraction de cycle: outils pour la
Sep 22 2014 contrainte 22 obtenue par extrusion d'un résidu acétamide. L'élimination acido-catalysée du ... NaOH 3.0 N aq. ... Br2. DCM
Chapter 6 Amines and Amides
Examples: Basicity of Amines. • Complete the following reactions: CH3NH2 + HCl. NHCH3. + HCl. N. CH3. CH3. H. CH3. + NaOH.
Lab 14: Qualitative Organic Analysis
deprotonated by NaOH to form water-??soluble alkoxides. Recommended Controls: butylamine acetamide
Introduction à la cinétique Chimique
Sur un mélange équimoléculaire d'acétamide et de HCl à 63°C on a mesuré la Br2 k5 v5 = k5 . [Br]2. 1. Montrer que la vitesse de la réaction globale V
Identification of Organic Compound by Organic Qualitative Analysis
Bromine water Test. Substance + 2 ml of water shake well + 2 drops of i) Decolourisation of bromine ... 1 ml of extract + 2-3 drops of NaOH solution.
Untitled
b- Br2 / NaOH c- PCl5 d- LiAlH4. 5- Acetamide on reduction with LiAlH4 gives a- Acetaldehyde b- Ethylamine c- Acetone d- Methylamine.
Chem 11 Lab Manual
Mix 5 drops of 10% NaOH(aq) with 5 drops of dilute 6 M HCl(aq). Dissolve 0.5 g of acetamide in 5 mL of 6 M H2SO4 in a large test tube (150 x 18 mm).
Substitution nucléophile aromatique des acides benzoïques et
Jan 1 2011 NaOH. Me. CO2Et. O. Br2. AcOH
???????? ??????????????????????????
acetamide ethyl acetate + 4NaOH + Br2 ... Tollen's reagent (???????????? 10% NaOH 1 ??? ???? 5% AgNO3 2 mL ????? ???????? 2% NH4OH ??.
The Chemistry of the Perfluoroaliphatic Acids and their Derivatives
2CF3CONH2 + NaOH + Br2-S- CF-CF8. RfCONH2 —> reaction with acetamide. NaOBr. RfCONH2 -->- ... bromine and perfluoropropyl isocyanate (followed.
Chapter Fourteen
Carboxylic Acids
Problem 14.1: Suggest the IUPAC name for each of the following compounds.Solution
(a) 2-Cyclohexenecarboxylic acid (b) 2-Cyclopropylpropanoic acid (c) 1,5-Pentanedioic acid (d) 4-Oxo-pent-2-enoic acid (e) Benzene-1,3-dicarboxylic acid Problem 14.2: Predict the major product for the following reactions. Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic AcidsSolution:
Problem 14.3: How could you separate a mixture containing the following compounds?C6H5CO2H , C6H5OH , C6H5CONHC6H5
Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic AcidsSolution
Problem 14.4: Rank in the order of decreasing acidity. (a) 1 > 2 > 3 > 4 (b) 1 > 3 > 2 > 4 (c) 1 > 4 > 2 > 3 (d) 2 > 1 > 3 > 4 (d) 2 > 3 > 1 > 4 (e) 2 > 4 > 1 > 2 Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic Acids (f) 2 > 4 > 3 > 1 (g) 3 > 4 > 2 > 1Solution: (f)
Problem 14.5: Give the formula for compounds A to F.Solution
A = RCOCl B = RCON(CH3)2
C = RCH2N(CH3)2 D = RCH2N+(CH3)2I
E = Problem 14.6: Select the correct answer of the following:1- The reaction of formic acid with conc. H2SO4 gives.
(a) CO2+H2O (b) HCHO (c) CH3CO2H (d) CO+H2O2- Propanoic acid when treated with aq. NaHCO3, the
CO2 comes from.
(a) CH3 (b) Methylene (c) Bicarbonate (d) Carboxylic acid3- The acid, which has reducing properties, is.
Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic Acids (a) Formic acid (b) Acetic acid (c) Oxalic acid (d) Ethanoic acid4- Carboxylic acid when warmed with hydrazoic acid
(HN3) in the presence of H2SO4, its produces. (a) Acid amide (b) Primary amine (c) Alkyl cyanide (d) Secondary amine5- Which one is the strongest acid?
(a) -Nitrobenzoic acid (b) -Nitrobenzoic acid (c) -Nitrobenzoic acid (d) -NitrophenolSolution
1- (d) 2- (c) 3- (a) 4- (b) 5- (a)
Problem 14.7: Select the correct answer of the following:1- Formic acid and acetic acid may be distinguished by
reaction with (a) Na (b) C2H5ONa (c) dil. KMnO4 (d) 2,4-(NO2)2 C6H3NHNH22- Benzoic acid and phenol may be distinguished by their
reaction with (a) aq. NaOH (b) aq. NaHCO3 Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic Acids (c) FeCl3 (d) aq. NH33- The IUPAC name of CH3CH2CH=CHCO2H is
(a) Pent-3-en-1-oic acid (b) Pent-2-en-1-oic acid (c) Pent-2,3-en-1-oic acid (d) Pent-3,4-en-1-oic acid4- Benzoic acid reacts with conc. HNO3 and conc. H2SO4
to give. (a) -Nitrobenzoic acid (b) -Nitrobenzoic acid (c) -Nitrobenzoic acid (d) -and -Nitrobenzoic acid5- -Methoxybenzoic acid is less acidic than salicylic
acid because of the: (a) Resonance (b) Inductive effect (c) Hydrogen bond (d) None of these6- Pyruvic acid can be obtained by the oxidation of
propanic acid with. (a) KMnO4 (b) Ag2O (c) MnO2 (d) SeO27- The final product for the acid hydrolysis and the
decarboxylation of Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic AcidsSolution
1- (c) 2- (b, c) 3- (b) 4- (b)
5- (c) 6- (d) 7- (c)
Problem 14.8: Give the name for each of the following compounds.1- HCO2H 2- CH3CO2H
3- CH3CH2CO2H 4- CH3CH2CH2CO2H
5- CH3CH2CH2CH2CO2H 6- (CH3)3CCO2H
7- C6H5CH2CO2H
Solution
Common system Derived system IUPAC system
1- Formic acid --- Methanoic acid
2- Acetic acid --- Ethanoic acid
3- Propionic acid Methyl acetic acid Propanoic acid
4- Butyric acid Ethyl acetic acid Butanoic acid
5- Valeric acid Propyl acetic acid Pentanoic acid
6- --- Trimethyl acetic acid 2,3-Dimethylpropanoic acid
7- --- Phenyl acetic acid 2-Phenylethanoic acid
Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic Acids Problem 14.9: Predict the products of the following.Solution:
1- CH3COONa + H2O + CO2
2- CH3COCl + POCl3 + HCl
3- CH3CONH2 + H2O
4- ClCH2COOH + HCl
Problem 14.10: How will you distinguish between
1- Crotonic acid and propionic acid?
2- Formic acid and acetic acid?
Solution
1- Crotonic acid is an unsaturated acid, it decolorizes the
red color of Br2 / CCl4 solution, but propionic acid does not give this test. Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic Acids2- A-By Tollen's reagent: Formic acid produces silver
mirror with ammonical silver nitrate solution, but acetic acid does not give this test. B- By mercuric chloride : Formic acid produces a white precipitate with HgCl2 solution but acetic acid does not give this test. Problem 14.11: How will you convert acetic acid to: (1) Sodium acetate? (2) Acetyl chloride? (3) Acetamide? (4) Acetic anhydride? (5) Ethanol? (6) Chloroacetic acid?Solution:
Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic Acids Problem 14.12 Arrange the following compounds in the order of increasing acidity.1- ClCH2CO2H, Cl2CHCO2H, Cl3CCO2H, CH3CO2H
2- CH3CO2H, (CH3)2CHCO2H, (CH3)3CCO2H
Solution:
1- CH3CO2H < ClCH2CO2H < Cl2CHCO2H < Cl3CCO2H
2- (CH3)3CCO2H < (CH3)2CHCO2H < CH3CO2H
Problem 14.13: Identify A, B and C in the following reaction sequences. Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic AcidsSolution:
1 A: CH3CH2Br B : CH3CH2CN C: CH3CH2CO2H
2 A: (CH3CO)2Cu B : CH3COCH3 C:(CH3)2C=NNH2
3 A:CH3CH(OH)CN B: CH3CH(OH)CO2H C: CH3COCO2H
4 A: CH3CH2Br B : CH3CH2CN C: CH3CH2CO2H
Problem 14.14 How will you synthesize:
(1) Acetic acid from acetylene? (2) Acetic acid from propionic acid? (3) Propionic acid from acetic acid ?Solution:
Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic AcidsProblem 14.15 How will you synthesize.
(1) Isobutyric acid from isopropyl alcohol? (2) Chloroacetic acid from methyl chloride? (3) Pyruvic acid from ethyl bromide? (4) Glycine from ethyl alcohol? (5) Malonic acid from acetic acid?Solution
Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic Acids Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic Acids Problem 14.16 How will you synthesize crotonic acid from acetaldehyde? Solution Crotonic acid could be synthesized from acetaldehyde using two methods . (1) Via aldol condensation. (2) Via Knoevenagel condensation.Problem 14.17How will you synthesize.
(1) Trimethyl acetic acid from -butylalcohol? (2) 2,4,6-Trimethylbenzoic acid from 2,4,6-trimethylbenzene?Solution
Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic AcidsProblem 14.18 A fatty acid contains the group of.
(a) ±OH (b) C=O (c) ±CONH2 (d) ±CO2HSolution: (d)
Problem 14.19 Select the correct answers:
1- A carboxylic acid contains of
(a) HO- (b) C=O (c) HO- & C=O (d) CONH22- Methanoic acid bears functional groups of :
(a) CO2H (b) HO- (c) C=O & OH (d) CO2H & OH and CHO Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic Acids3- Methanoic acid differs from ethanoic acid in the
reaction with. (a) FeCl3 (b) NaHCO3 (c) KMnO4 (d) C2H5OH4- The reaction between a carboxylic acid and alcohol is
known as (a) Condensation (b) Hydrolysis (c) Esterification (d) Carbonation5- Mark the acid which is by decarboxylation does not
give a hydrocarbon. (a) Formic acid (b) Acetic acid (c) Benzoic acid (d) Propionic acid6- Which of the following acids cannot be prepared by
reaction of Grignard's reagent and CO2? (a) Acetic acid (b) Formic acid (c) Propionic acid (d) Benzoic acid7- Ammonium acetate by heating with P2O5 gives.
(a) Acetic anhydride (b) Acetamide (c) Acetonitrile (d) Ethylamine8- Acetic acid can be manufactured by.
(a) Fermentation (b) Distillation (c) Saccharification (d) Ozonolysis Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic AcidsSolution:
1- c 2- d 3- c 4- c
5- a 6- b 7- c 8- a
Problem 14.20: Chose the correct answers:
1- The acid that present in the vinegar is.
(a) Citric acid (b) Acetic acid (c) Formic acid (d) Oxalic acid2- Mark the acid that reduces Tollen's reagent.
(a) Acetic acid (b) Formic acid (c) Propionic acid (d) Carbonic acid3- Formic acid on heating yields.
(a) CO2 + H2O (b) CO + H2O (c) CO + H2 (d) None of these4- The acid used in pickling is:
(a) Formic acid (b) Acetic acid (c) Citric acid (d) Tartaric acid5- When methyl alcohol vapour, mixed with carbon
monoxide, and passed under pressure at 150C° over a catalyst, the product was. (a) Formic acid (b) Acetic acid Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic Acids (c) Propionic acid (d) Oxalic acid6- Mark the strongest acid:
(a) HCO2H (b) CH3CO2H (c) ClCH2CO2H (d) Cl3CCO2H7- Which acids is used in the manufacture of synthetic
fibers? (a) Formic acid (b) Acetic acid (c) Carbonic acid (d) Oxalic acid8- When hydrogen ion is removed from the carboxylic
acid, the fragment left is. (a) An acyl group (b) An acetyl group (c) An acyloxy group (d) None of theseSolution
1- b 2- b 3- d 4- b
5- b 6- d 7- b 8- c
Problem 14.21Give the name of the following compounds. Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic AcidsSolution
a- (E)-2-Methyl-2-butenoic acid (tiglic acid) b- (Z)-2-Methyl-2-butenoic acid (angelic acid) c- 2-Hydroxypropane-1,2,3-tricarboxylic acid (citric acid) d- 3,5-Dihydroxy-3-methylpentanoic acid (mevalonic acid) Problem 14.22: How will you convert the following reaction?Solution:
Chapter Fourteen Fawzi Hameeed Jumaa Al-Obaidy Carboxylic Acids Problem 14.23 Provide an acceptable IUPAC name for each of the following:Solution
(a) 4-Methyl-5-phenylhexanoic acid (b) Cyclohexanecarboxylic acid (c) 3-Methyl-2-ethylbutanoic acidquotesdbs_dbs4.pdfusesText_7[PDF] acetamide with naoh
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