Acidic and Basic Amide Hydrolysis //
The mechanism of basic amide hydrolysis is straightforward and recent hydrolysis of amides in dilute acid solutions involves attack by a water molecule.
catalyzed hydrolysis of amide and peptide bonds in proteins 1
and acidity but also on the acid used. When hydrolyzed at 65° C by certain strong monobasic acids of high molecular weight the amide and the peptide.
Carboxylic acid participation in amide hydrolysis. External general
carboxylic acid promoted amide hydrolysis is presented which involves intermediates of standing of enzyme-catalyzed amide hydrolysis.1'2 Although.
21.7 HYDROLYSIS OF CARBOXYLIC ACID DERIVATIVES
The a-carbon reactions of all carbonyl compounds are grouped together in Chapter 22. The reactivity of amides at nitrogen is discussed in Sec. 23.11D. 21.7.
Dilute acid-catalyzed amide hydrolysis: efficiency of the N
protonated amide to show that hydrolysis via the latter species is not sufficient to support the overall observed acid-hydrolysis rate constant for amides.
Structure medium
http://pubs.acs.org/doi/pdf/10.1021/ja00753a042
Fatty Acid Amide Hydrolase Substrate Specificity
Endogenous oleamide and anandamide are hydrolyzed and inactivated by fatty acid amide hydrolase. (FAAH)17
Kinetics and mechanism of amide acetal hydrolysis. Carbon-oxygen
Hydrolysis. Carbon-Oxygen vs. Carbon-Nitrogen Bond Cleavage in Acid Solutions. Robert A. McClelland.
Carboxylic acid participation in amide hydrolysis. Evidence that
Carboxylic Acid Participation in Amide Hydrolysis. Evidence That Separation of a Nonbonded Complex Can Be. Rate Determining. Ronald Kluger* and Jik Chin.
The Hydrolysis of Vitamin B12. Studies with Model Amides
amide are described and therates of hydrolysis of these and other model amides in aqueous hydrochloric acid-dioxane at 50° are recorded. Aquocobalamin has.
[PDF] amide hydrolysis products
[PDF] amide hydrolysis under acidic conditions
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[PDF] amide hydrolysis with hcl
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[PDF] amine functional group pdf
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