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Chemistry of Polymer - Relationship between average functionality

defined as the fraction of functional groups/monomers that have reacted at time t) and average degree of polymerization (Xn defined as equal to the total 



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Degree of polymerization (DP): - The no of repeating units or monomer Bi-functional monomers containing two functional groups give linear polymers.



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Functionality is used to determine of Dp and Mn. HTPB that was prepared via radical polymerization and found that functionality7 of HTPB.



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0.98) DP = 33. Step-Growth Polymerization Kinetics (3). The assumption that the reactivity of a functional group on the growing end of the polymer chain is 



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Degree of polymerization (DP): - The no of repeating units or monomer Bi-functional monomers containing two functional groups give linear polymers



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Relationship between average functionality extent of reaction and degree of polymerization: W H Carothers derived a general expression relating average 



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  • What is functionality and degree of polymerization?

    The degree of polymerization (DP) is usually defined as the number of monomeric units in a macromolecule or polymer or oligomer molecule. For a homopolymer, there is only one type of monomeric unit and the number-average degree of polymerization is given by. DPn?Xn=MnMo.
  • What is the functionality of polymerization?

    Functionality in polymer chemistry
    According to IUPAC, the functionality of a monomer is defined as the number of bonds that a monomer's repeating unit forms in a polymer with other monomers. Thus in the case of a functionality of f = 2 a linear polymer is formed by polymerizing (a thermoplastic).
  • What are the different types of functionality in polymer?

    Functionality may be separated into two broad categories: intrinsic functional groups and extrinsic functional groups. An example of polymers with intrinsic functionality and intrinsic functionality include rubbery polymers and conducting polymers, respectively.
  • The minimum polymerization is 2. If an a-functional monomer reacts with a b-functional monomer in a non-chain reaction, the functionality of the product molecule is a 1 b 2 2. This is because every new linkage consumes two bonding sites.
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