Organic Chemistry 32-235 Practice Questions for Exam #2 Part 1
The answer here is 1S. 2S. 2. Consider the SN1 reaction of tert-butyl chloride with iodide ion: (CH3)3C Cl + I.
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Organic Chemistry 32-235 Practice Questions for Exam #2 Part 1
The answer here is 1S. 2S. 2. Consider the SN1 reaction of tert-butyl chloride with iodide ion: (CH3)3C Cl + I.
General Organic Chemistry Questions
d. Page 9. 7. When an external magnetic field is applied what happens to the protons in a sample? a. All protons align with the field.
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[PDF] Organic Chemistry 32-235 Practice Questions for Exam Part 1
Organic Chemistry 32-235 Practice Questions for Exam #2 Part 1: (Circle only ONE choice circling more than one will be counted as wrong!) 4 points each
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ACS Examination guide (Selected Questions) Organic Chemistry Nomenclature 1 What is the IUPAC names for this compound? a) 1-tert-butyl-2-butanol
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Work the Problems
Learning Organic Chemistry requires problem practice. You should attempt all NCERT questions, then your reference book exercises and hit the past year papers. Spend all the extra time you save from theory for organic chemistry into solving problems. So, work the problemsHow to pass the introduction to organic chemistry?
Organic chemistry is the area of chemistry that involves the study of carbon and its compounds. Carbon is now known to form a seemingly unlimited number of compounds. The uses of organic compounds impact our lives daily in medicine, agriculture, and general life.
Organic Chemistry Questions
The Covalent Bond
1. The hybridization of the central carbon in CH
3CN and the bond angle CCN are
a. sp 2 , 180°. b. sp, 180°. c. sp 2 , 120°. d. sp 3 , 109°.2. Which of the following statements about an sp hybridized carbon is FALSE?
a. It is divalent. b. It forms bonds that are linear. c. It has two p orbitals. d. It always forms triple bonds to carbon.3. Which molecule has the largest dipole moment?
a. HCl b. CCl 4 c. H 2 S d. CO 24. What are the hybridizations of carbons 1 and 2 respectively in the following structure?
a. sp 3 and sp 2 b. sp 2 and sp 3 c. sp 3 and sp d. sp 2 and sp 25. What are the hybridizations of atoms 1 and 2 respectively in the following structure?
a. sp 3 and sp 2 b. sp 2 and sp 3 c. sp 3 and sp d. sp 2 and sp 26. Identify the orbital hybridization at the two indicated carbons in the molecule below.
a. C 1 : sp; C 2 : sp b. C 1 : sp 2 ; C 2 : sp 2 c. C 1 : sp; C 2 : sp 2 d. C 1 : sp 2 ; C 2 : sp7. How many total resonance structures can be drawn for the following anion (include
those without separation of charge)? a. 1 b. 2 c. 3 d. 48. How many resonance structures can be drawn for the following molecule?
a. 1 b. 4 c. 3 d. 29. The correct geometry around oxygen in CH
3 OCH 3 is a. linear. b. bent. c. tetrahedral. d. trigonal planar10. Determine the relationship between the two molecules shown.
a. constitutional isomers b. enantiomers c. diastereomers d. identical molecules11. What is the correct name for this molecule?
a. (2R,3R)-2-bromo-3-chlorobutane b. (2S,3R)-2-bromo-3-chlorobutane c. (2S,3S)-2-bromo-3-chlorobutane d. (2R,3S)-2-bromo-3-chlorobutane12. What is the specific rotation 20[Į ]
D of the following molecule? a. +4.42 o b. +0.442 o c. +44.2 o d. - 44.2 o13. Which of the following physical properties differ for each of a pair of enantiomers?
a. solubility in ethanol b. direction of rotation of plane-polarized light c. boiling point and melting point d. index of refraction14. Determine the double bond stereochemistry (E or Z) for the following molecules.
a. A: E; B: E b. A: Z; B: Z c. A: E; B: Z d. A: Z; B: E15. Determine the double bond stereochemistry (E or Z) for the following molecules.
a. A: E; B: E b. A: Z; B: Z c. A: E; B: Z d. A: Z; B: EMolecular Structure and Spectra
1. A strong signal at 1700 cm
-1 in an IR spectrum indicates the presence of a(n) a. alcohol b. ether c. carbonyl d. amine2. A strong signal at 3400 cm
-1 in an IR spectrum indicates the presence of a(n) a. alcohol b. ether c. carbonyl d. amine3. Deduce the structure of an unknown compound with molecular formula C
5 H 12O using
information given by its infrared spectrum.Intensity (peak): Frequency (cm
-1 m 3300 m 2900 m 2800 m 1465 m 1450 m 1375 a. b. c. d.4. Deduce the structure of an unknown compound with molecular formula C
9 H 10O using
information given by its infrared spectrum.Intensity (peak): Frequency (cm
-1 s 3100 m 2900 m 2800 s 1710 m-w 1600 m-w 1475 m 1465 m 1450 m 1375 a. b. c. d.5. Deduce the structure of an unknown compound with molecular formula C
5 H 8O using
information given by its infrared spectrum.Intensity (peak): Frequency (cm
-1 m 3100 m 2800 s 1705 m-w 1640 m 1450 m 1375 a. b. c. d.6. Which of the following compounds a-d has an IR absorption at 3300 cm
-1 a. a b. b c. c d. d7. When an external magnetic field is applied, what happens to the protons in a sample?
a. All protons align with the field. b. All protons align opposite to the field. c. Some protons align with the field and some align opposite to it. d. All protons assume a random orientation8. Which of the following compounds has the MOST deshielded protons?
a. CH 3 Cl b. CH 3 I c. CH 3 Br d. CH 49. Arrange the following compounds in order of decreasing chemical shift for the
underlined hydrogens (largest value first, smallest value last). CH 3 CH 2 CH 3 CH 3 OCH 2 CH 3 Cl 2 CHCH 2 CH 3 ClCH 2 CH 2 CH 3 a b c d a. b > c > a > d b. b > c > d > a c. c > b > a > d d. c > b > d > a10. An unknown molecule A has 4 signals in the
1H NMR spectrum. Which of the
following corresponds to molecule A? a. b. c. d.11. Deduce the structure of an unknown compound using the following
1 H NMR spectrum, mass spectroscopy data, and IR spectrum. 1H NMR spectrum:
1.30 (triplet, 6H)
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