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Compilation of Henry"s Law Constants for Inorganic and Organic Species of Potential Importance in Environmental
Chemistry
Rolf Sander
Air Chemistry Department
Max-Planck Institute of Chemistry
PO Box 3060
55020 Mainz
Germany
e-mail: sander@mpch-mainz.mpg.deVersion 3 (April 8, 1999)
c ?Rolf Sander (non-commercial reproduction permitted)Contents
1 Introduction3
2 The physical quantity of solubility3
3 Temperature dependence3
4 Unit conversions3
5 How to use the Tables4
6 Further Sources of Information4
7 Data Table (Inorganic)6
oxygen (O) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
hydrogen (H) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
nitrogen (N) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
fluorine (F) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
chlorine (Cl) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
bromine (Br) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
iodine (I) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
sulfur (S) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
rare gases . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
other elements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
2R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
8 Data Table (Organic)14
alkanes (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
cycloalkanes (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
aliphatic alkenes and cycloalkenes (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28
aliphatic alkynes (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
mononuclear aromatics (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
terpenes and polynuclear aromatics (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
alcohols (ROH) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
polyols (R(OH)n) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
peroxides (ROOH) and peroxy radicals (ROO) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . 43
aldehydes (RCHO) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44
ketones (RCOR) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46
carboxylic acids (RCOOH) and peroxy carboxylic acids (RCOOOH) (C, H, and O only) . . . . . . . . . . . . . . 48
esters (RCOOR) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50
ethers (ROR) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54
miscellaneous, e.g. multiple functional groups (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . 55
compounds with nitrogen: amines (RNH2) (C, H, O, and N only) . . . . . . . . . . . . . . . . . . . . . . . . . . . 58
compounds with nitrogen: amino acids (RCHNH2COOH) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59
compounds with nitrogen: heterocycles (C, H, O, and N only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59
compounds with nitrogen: nitrates (RONO2) (C, H, O, and N only) . . . . . . . . . . . . . . . . . . . . . . . . . 61
compounds with nitrogen: nitriles (RCN) (C, H, O, and N only) . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
compounds with nitrogen: nitro (RNO2) (C, H, O, and N only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 66
compounds with fluorine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68
aliphatic compounds with chlorine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71
aromatic compounds with chlorine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82
compounds with chlorine and fluorine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 84
compounds with bromine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
compounds with iodine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89
compounds with sulfur . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90
polychlorobiphenyls (PCB"s), pesticides, etc. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92
9 Notes96
10 Acknowledgements99
References99
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)31 Introduction
Henry"s law constants (solubilities) of trace gases of potential importance in environmental chemistry (atmospheric chem-
istry, waste water treatment, ...) have been collected and converted into a uniform format.Disclaimer: Although this compilation has been edited with greatest care the possibility of errors cannot be excluded. If
you use data from this table it is recommended that you also check the original literature. If you find an error in this table,
please tell me about it!2 The physical quantity of solubility
There are several ways of describing the solubility of a gas in water. Usually the Henry"s law constantkHis defined as:
kHdef=ca/pg(1)
Here,cais the concentration of a species in the aqueous phase andpgis the partial pressure of that species in the gas phase.
IfkHrefers to standard conditions (T?= 298.15 K) it will be denoted ask? H.Henry"s law constant can also be expressed as the dimensionless ratio between the aqueous-phase concentrationcaof a
species and its gas-phase concentrationcg: k ccHdef=ca/cg=kH×RT(2)whereR= gas constant andT= temperature. To distinguish these different physical quantities, this constant has been
namedkccHhere.Sometimes the reciprocal valuekpx
H,invis used, representing the volatility instead of the solubility. The usual definition is: k pxH,invdef=pg/xa=?H2OMH2O×kH(3)
wherexa= molar mixing ratio in the aqueous phase,?H2O= density of water, andMH2O= molar mass of water.
3 Temperature dependence
A simple way to describe Henry"s law as a function of temperature is: k H=k?H×exp?-ΔsolnHR?
1T-1T???
(4) where Δ solnH= enthalpy of solution. Here, the temperature dependence is: -dlnkHd(1/T)=ΔsolnHR(5)4 Unit conversions
Detailed information about the conversion between different units and definitions of Henry"s law constants is given by
Sander[1999]. Here is a short summary:
The commonly used unit forkHis [M/atm] = [molaq/dm3aqatm]. The official SI unit is [molaq/m3aqPa]. The conversion is:
kH[M/atm]= 101.325×kH[(molaq/m3aq)/Pa](6)
The relation betweenkHandkccHis:
T[K]×kH[M/atm]= 12.2×kccH(7)
4R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
AtT= 298.15 K this leads to:kH[M/atm]= 0.0409×kccH(8)The commonly used unit forkpx
H,invis [atm]. The product ofkHandkpx
H,invis constant:
kH[M/atm]×kpx
H,inv[atm]= 55.3 (9)
5 How to use the Tables
Inorganic substances are sorted according to the elements they contain. The order chosen is: O, H, N, F, Cl, Br, I, S, rare
gases, others. Organic substances (i.e. everything with carbon, including CO and CO2) are sorted somewhat arbitrarily by increasing
chain length and complexity. Hetero atoms (N, F, Cl, Br, I, and S) are sorted in the same way as for inorganic compounds.
The column labeled 'substance" gives the systematic name, the chemical formula, trivial names (if any), and in several cases
the CAS registry number (in square brackets).The column labeled 'k?
H" contains the Henry"s law constants as defined in equation (1), rounded to two significant digits and given in the unit [M/atm].The column labeled '-dlnkH/d(1/T)" contains the temperature dependence of the Henry"s law constants as defined in
equations (4) and (5), rounded to two significant digits and given in the unit [K].For each table entry the column labeled 'type" denotes how the Henry"s law constant was obtained in the given reference.
Literature reviews are usually most reliable, followed by original publications of experimental determinations ofkH. Other
data has to be treated more carefully. The types listed here are roughly ordered by decreasing reliability:'L"The cited paper is a literature review.'M"Original publication of a measured value (e.g. head-space or bub-
ble column technique as explained byBetterton[1992]).'V"Vapor pressure of the pure substance is used to determine the
Henry"s law constant (c/pfor a saturated solution).'R"The cited paper presents a recalculation of previously published
material (e.g. extrapolation to a different temperature or concen- tration range).'T"Thermodynamical calculation (ΔsolnG=-RTlnkH, seeSander [1999] for details).'C"The paper that is cited here refers to another reference which I could not obtain (e.g. personal communication, Ph.D. theses, internal papers etc.).'X"I haven"t seen the paper that I cite here. I found it referenced byanother paper or I know about it through others.'?"The cited paper doesn"t clearly state how the value was obtained.'E"The value is estimated. Estimates are only listed if no reliable
measurements are available for that compound.In some cases there might be good agreement between different authors. However, if the original work they refer to is not
known one has to be careful when evaluating the reliability. It is possible that they were recalculating data from the same
source. The similarity in that case would not be due to independent investigations.6 Further Sources of Information
Further important references:
•monoaromatic hydrocarbons, chlorobenzenes, and PCBs:Mackay et al.[1992a] R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)5•polynuclear aromatic hydrocarbons, polychlorinated dioxins, and dibenzofuranes:Mackay et al.[1992b]
•volatile organic chemicals:Mackay et al.[1993] •oxygen, nitrogen, and sulfur containing compounds:Mackay et al.[1995]•pestizides, PCB"s, etc.:Westcott et al.[1981];Burkhard et al.[1985];Hassett and Milicic[1985];Yin and Hassett
[1986];Murphy et al.[1987];Shiu et al.[1988];Rice et al.[1997];Fendinger and Glotfelty[1988];Fendinger et al.
[1989];De Maagd et al.[1998];Duce et al.[1991]•additional references that are not (yet) included:Lide and Frederikse[1995];Shiu et al.[1994];Watts and Brimble-
combe[1987];Wright et al.[1992a];Tse et al.[1992];Kolb et al.[1992];Ettre et al.[1993];Gan and Yates[1996];
Peng and Wan[1997];Roberts and D¨andliker[1983];Economou et al.[1997];Wong and Wang[1997];Suleimenov
and Krupp[1994];Heron et al.[1998];Becker et al.[1998];Leuenberger et al.[1985]•predictive methods for Henrys law coefficients (QSPRs):Russell et al.[1992];Nirmalakhandan et al.[1997];Brennan
et al.[1998]On the Internet:
•The NIST Chemistry WebBook athttp://webbook.nist.gov/chemistry •The Pesticide Properties Database (PPD) athttp://www.arsusda.gov/rsml/ppdb2.html6R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
7 Data Table (Inorganic)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenoteoxygen (O)oxygen1.3×10-31700Loomis[1928]X1O21.2×10-31800Carpenter[1966]M[7782-44-7]1.3×10-31500Wilhelm et al.[1977]L1.3×10-31700Dean[1992]?21.3×10-31500Lide and Frederikse[1995]L1.2×10-31700Kavanaugh and Trussell[1980]X3ozone1.2×10-22300Loomis[1928]X1O31.3×10-22000Briner and Perrottet[1939]M[10028-15-6]1.3×10-22000Wilhelm et al.[1977]L1.2×10-2Durham et al.[1981]C1.1×10-22300Kosak-Channing and Helz[1983]M1.2×10-22700Chameides[1984]T9.4×10-32500Hoffmann and Jacob[1984]?41.1×10-22400Jacob[1986]C9.4×10-32400Seinfeld[1986]C8.9×10-32900Kavanaugh and Trussell[1980]X3hydrogen (H)hydrogen7.8×10-4Hine and Weimar[1965]RH27.8×10-4490Wilhelm et al.[1977]L[1333-74-0]7.8×10-4640Dean[1992]?27.8×10-4500Lide and Frederikse[1995]Lhydroxyl radical2.9×1013100Berdnikov and Bazhin[1970]T5OH3.2×101Mozurkewich[1986]T[3352-57-6]2.5×1015300Jacob[1986]C62.5×101Lelieveld and Crutzen[1991]C2.0×102Lelieveld and Crutzen[1991]C9.0×103Lelieveld and Crutzen[1991]C3.0×1014500Hanson et al.[1992]Thydroperoxy radical4.6×1034800Berdnikov and Bazhin[1970]T5HO29.0×103Chameides[1984]T[3170-83-0]1.2×103Schwartz[1984]T76600Jacob[1986]E9.0×103Weinstein-Lloyd and Schwartz[1991]T4.0×1035900Hanson et al.[1992]T5.7×103R´egimbal and Mozurkewich[1997]Rhydrogen peroxide7.1×1047000Martin and Damschen[1981]TH2O27.1×1047300Hoffmann and Jacob[1984]?4[7722-84-1]1.4×105Yoshizumi et al.[1984]M89.7×1046600Chameides[1984]T6.9×1047900Hwang and Dasgupta[1985]M1.0×1056300Lind and Kok[1994]M98.3×1047400O"Sullivan et al.[1996]M1.1×1057500Staffelbach and Kok[1993]M108.6×1046500Zhou and Lee[1992]M
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)7substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenotenitrogen (N)ammonia5.9×1014100Sillen and Martell[1964]X1NH35.7×1014100Robinson and Stokes[1970]X1[7664-41-7]1.0×1011500Wilhelm et al.[1977]L6.1×1014200Edwards et al.[1978]L7.6×1013400Hales and Drewes[1979]M5.8×1014100Chameides[1984]T7.8×101Holzwarth et al.[1984]M5.8×1014100Hoffmann and Jacob[1984]?45.6×1014100Dasgupta and Dong[1986]M5.6×1014200Dasgupta and Dong[1986]T6.1×1014200Clegg and Brimblecombe[1989]M2.7×1012100Dean[1992]?26.2×101Van Krevelen et al.[1949]X115.4×101Bone et al.[1983]?126.0×1014400Kavanaugh and Trussell[1980]X3hydrazoic acid9.93100Wilhelm et al.[1977]LHN3[7782-79-8]dinitrogen monoxide2.5×10-2Loomis[1928]X1N2O2.6×10-2Liss and Slater[1974]?(nitrous oxide, laughing gas)2.4×10-22600Wilhelm et al.[1977]L[10024-97-2]2.5×10-2Seinfeld[1986]?132.4×10-22800Dean[1992]?22.5×10-22600Lide and Frederikse[1995]L142.4×10-22700Perry[1963]Xnitrogen6.5×10-41300Wilhelm et al.[1977]LN26.1×10-41300Kavanaugh and Trussell[1980]X3[7727-37-9]nitrogen monoxide7.9×10-73800Wilhelm et al.[1977]LNO1.4×10-3Zafiriou and McFarland[1980]M(nitric oxide)1.9×10-31500Schwartz and White[1981]L[10102-43-9]1.9×10-3Durham et al.[1981]C1.9×10-31700Dean[1992]?21.9×10-31400Lide and Frederikse[1995]Lnitrogen dioxide3.4×10-21800Berdnikov and Bazhin[1970]T5NO27.0×10-3Lee and Schwartz[1981]M15[10102-44-0]4.0×10-2Lee and Schwartz[1981]C2.4×10-2Lee and Schwartz[1981]C1.2×10-2Schwartz and White[1981]L4.1×10-2Durham et al.[1981]C1.2×10-22500Chameides[1984]Tnitrogen trioxide3.4×10-22000Berdnikov and Bazhin[1970]T5NO31.2×1011900Chameides[1986]T(nitrate radical)2.02000Thomas et al.[1993]M[12033-49-7]6.0×10-1Rudich et al.[1996]M16see noteSeinfeld and Pandis[1998]M171.8Thomas et al.[1998]M
8R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenotedinitrogen trioxide6.0×10-1Schwartz and White[1981]LN2O32.6×101Durham et al.[1981]C[10544-73-7]dinitrogen tetroxide1.4Schwartz and White[1981]LN2O41.6Durham et al.[1981]C[10544-72-6]dinitrogen pentoxide∞Jacob[1986]E18N2O52.13400Fried et al.[1994]E19(nitric anhydride)∞Sander and Crutzen[1996]E18[10102-03-1]nitrous acid4.9×1014800Schwartz and White[1981]LHNO23.7×101Durham et al.[1981]C[7782-77-6]4.9×1014800Chameides[1984]T4.8×1014700Martin[1984]T4.9×1014900Park and Lee[1988]M5.0×1014900Becker et al.[1996]Mnitric acid2.1×105Schwartz and White[1981]THNO38.9×104Durham et al.[1981]C[7697-37-2]2.6×1068700Chameides[1984]T3.5×105/KA8700Hoffmann and Jacob[1984]?20, 42.4×106/KA8700Brimblecombe and Clegg[1989]T20, 212.1×1058700Lelieveld and Crutzen[1991]R22pernitric acid2.0×1040Jacob et al.[1989]CHNO41.0×105M¨oller and Mauersberger[1992]E23[26404-66-0]1.2×1046900R´egimbal and Mozurkewich[1997]T4.0×103Amels et al.[1996]Mfluorine (F)fluorine atom2.1×10-2400Berdnikov and Bazhin[1970]T5F[14762-94-8]hydrogen fluoride9.6/KA7400Brimblecombe and Clegg[1989]T20, 21HF[7664-39-3]nitrogen trifluoride7.9×10-41900Wilhelm et al.[1977]LNF3[7783-54-2]dinitrogen tetrafluoride8.5×10-42500Wilhelm et al.[1977]LN2F4(tetrafluorohydrazine)[10036-47-2]
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)9substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenotechlorine (Cl)hydrogen chloride1.9×1019000Loomis[1928]X1HCl1.7×105/KALoomis[1928]X1,20[7647-01-0]1.5×103Chen et al.[1979]X12.0×101Graedel and Goldberg[1983]C1.12000Marsh and McElroy[1985]T2.5×103Seinfeld[1986]?132.0×106/KA9000Brimblecombe and Clegg[1989]T20, 211.9×101600Dean[1992]?22.0×106/KA9000Wagman et al.[1982]Thypochlorous acid7.3×102Holzwarth et al.[1984]MHOCl4.8×102Hanson and Ravishankara[1991]M24[7790-92-3]9.3×102Blatchley et al.[1992]M6.6×1025900Huthwelker et al.[1995]L2.6×1025100Wagman et al.[1982]Tnitrosyl chloride>0.05Scheer et al.[1997]MNOCl[2696-92-6]nitryl chloride2.4×10-2Behnke et al.[1997]E25ClNO24.6×10-2Frenzel et al.[1998]E[13444-90-1]chlorine nitrate∞Sander and Crutzen[1996]E18ClNO3[14545-72-3]molecular chlorinesee noteKruis and May[1962]?26Cl29.1×10-22500Wilhelm et al.[1977]L[7782-50-5]6.2×10-22800Wagman et al.[1982]T9.3×10-22300Dean[1992]?26.3×10-23200Brian et al.[1962]L9.5×10-22100Lide and Frederikse[1995]L8.6×10-22000Kavanaugh and Trussell[1980]X3dichlorine monoxide1.7×1011800Wilhelm et al.[1977]LCl2O1.7×1011700Lide and Frederikse[1995]L[7791-21-1]chlorine dioxide1.03300Wilhelm et al.[1977]LClO21.03300Lide and Frederikse[1995]L14[10049-04-4]8.5×10-13400Kavanaugh and Trussell[1980]X3chlorine atom1.5×10-21500Berdnikov and Bazhin[1970]T5Cl2.0×10-1Mozurkewich[1986]T[22537-15-1]chloramide9.4×1014800Holzwarth et al.[1984]MNH2Cl[10599-90-3]dichloroamine2.9×1014200Holzwarth et al.[1984]MNHCl2(chlorimide)[3400-09-7]nitrogen trichloride1.0×10-14100Holzwarth et al.[1984]MNCl3[10025-85-1]
10R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenotebromine (Br)hydrogen bromide1.3×109/KA10000Brimblecombe and Clegg[1989]T20, 21HBr7.2×10-16100Chameides and Stelson[1992]C27[10035-10-6]2.5×101370Dean[1992]?27.2×108/KA10000Wagman et al.[1982]Thypobromous acid>1.9×103Blatchley et al.[1992]MHOBr1.8Mozurkewich[1995]T28[13517-11-8]9.3×101Vogt et al.[1996]Esee noteFickert[1998]M296.1×103Frenzel et al.[1998]Enitryl bromide3.0×10-1Frenzel et al.[1998]EBrNO2[13536-70-4]bromine nitrate∞Sander and Crutzen[1996]E18BrNO3[40423-14-1]molecular bromine7.9×10-13600Winkler[1899]X30Br27.1×10-14100Kelley and Tartar[1956]M[7726-95-6]9.7×10-1Jenkins and King[1965]M88.0×10-13900Jenkins and King[1965]R6.9×10-1Hill et al.[1968]M7.3×10-14000Wagman et al.[1982]T7.6×10-14100Dean[1992]?21.83300Dubik et al.[1987]M31bromine chloride4.23700Dubik et al.[1987]M31BrCl1.1see noteT32[13863-41-7]7.4×10-1see noteT335.2Disselkamp et al.[1998]M349.4×10-15600Bartlett and Margerum[1998]M5.9×10-1Frenzel et al.[1998]Ebromine atom3.4×10-21800Berdnikov and Bazhin[1970]T5Br1.2Mozurkewich[1986]T[10097-32-2]
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)11substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenoteiodine (I)hydrogen iodide2.5×109/KA9800Brimblecombe and Clegg[1989]T20, 21HI2.2×109/KA9800Wagman et al.[1982]T[10034-85-2]hypoiodous acid>4.5×101Thompson and Zafiriou[1983]EHOI<4.5×104Thompson and Zafiriou[1983]E[14332-21-9]>4.1×102Palmer et al.[1985]Cmolecular iodine3.14600Berdnikov and Bazhin[1970]RI23.34800Wagman et al.[1982]T[7553-56-2]1.1Thompson and Zafiriou[1983]C353.04400Palmer et al.[1985]Riodine atom6.3×10-32300Berdnikov and Bazhin[1970]T5I8.0×10-2Mozurkewich[1986]T[14362-44-8]iodine chloride1.1×102Wagman et al.[1982]TICl[7790-99-0]iodine bromide2.4×101Wagman et al.[1982]TIBr[7789-33-5]
12R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenotesulfur (S)hydrogen sulfide1.0×10-32300Loomis[1928]X1H2S1.0×10-1Hine and Weimar[1965]R[7783-06-4]1.0×10-12100Wilhelm et al.[1977]L1.0×10-12100Edwards et al.[1978]L1.0×10-12200Carroll and Mather[1989]L1.0×10-12300Dean[1992]?21.0×10-12000Lide and Frederikse[1995]L8.7×10-22100De Bruyn et al.[1995]M9.8×10-22200Kavanaugh and Trussell[1980]X3sulfur dioxide1.23200Sillen and Martell[1964]X1SO21.23100Hales and Sutter[1973]c[7446-09-5]1.1Liss and Slater[1974]c1.23100Smith and Martell[1976]X11.42800Wilhelm et al.[1977]L1.23000Edwards et al.[1978]L1.2Durham et al.[1981]C1.23100Chameides[1984]T1.23100Hoffmann and Jacob[1984]?41.23200Jacob[1986]C1.23100Pandis and Seinfeld[1989]C1.52900Dean[1992]?21.2Maahs[1982]X111.23200Maahs[1982]X11.42900Lide and Frederikse[1995]L1.32800Kavanaugh and Trussell[1980]X3sulfur trioxide∞Sander and Crutzen[1996]E18SO3[7446-11-9]sulfuric acidsee noteGmitro and Vermeulen[1964]M36H2SO4[7664-93-9]sulfur hexafluoride2.4×10-42400Wilhelm et al.[1977]LSF6[2551-62-4]
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)13substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenoterare gaseshelium3.7×10-4360Morrison and Johnstone[1954]M37He3.8×10-492Wilhelm et al.[1977]L[7440-59-7]neon4.5×10-4530Morrison and Johnstone[1954]M37Ne4.5×10-4450Wilhelm et al.[1977]L[7440-01-9]argon1.4×10-31100Morrison and Johnstone[1954]MAr1.4×10-31500Wilhelm et al.[1977]L[7440-37-1]krypton2.4×10-31500Morrison and Johnstone[1954]MKr2.5×10-31900Wilhelm et al.[1977]L[7439-90-9]xenon4.3×10-31900Morrison and Johnstone[1954]MXe4.3×10-32200Wilhelm et al.[1977]L[7440-63-3]radon9.3×10-32600Wilhelm et al.[1977]LRn[10043-92-2]other elementsselenium hydride8.4×10-21900Wilhelm et al.[1977]LH2Se[7783-07-5]phosphorus trihydride8.1×10-32000Wilhelm et al.[1977]LPH3(phosphine)[7803-51-2]arsenic hydride8.9×10-32100Wilhelm et al.[1977]LAsH3(arsine)[7784-42-1]mercury9.3×10-2Brimblecombe[1986]?38Hg[7439-97-6]
14R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
8 Data Table (Organic)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenotealkanes (CandHonly)methane9.2×10-3Butler and Ramchandani[1935]VCH41.4×10-3Hine and Weimar[1965]R9.7×10-4Liss and Slater[1974]C1.5×10-3Hine and Mookerjee[1975]V1.4×10-31700Wilhelm et al.[1977]L1.3×10-3Mackay and Shiu[1981]L1.3×10-31900Dean[1992]?21.4×10-31600Lide and Frederikse[1995]L141.5×10-3Yaws and Yang[1992]?391.3×10-31800Kavanaugh and Trussell[1980]X3ethane1.1×10-2Butler and Ramchandani[1935]VC2H62.0×10-3Hine and Mookerjee[1975]V1.8×10-32400Wilhelm et al.[1977]L2.0×10-3Mackay and Shiu[1981]L1.9×10-32300Lide and Frederikse[1995]L2.0×10-3Yaws and Yang[1992]?39propane1.4×10-3Hine and Mookerjee[1975]VC3H81.5×10-32700Wilhelm et al.[1977]L1.4×10-3Mackay and Shiu[1981]L1.5×10-32700Lide and Frederikse[1995]L1.4×10-3Yaws and Yang[1992]?39butane4.9×10-3Butler and Ramchandani[1935]VC4H101.1×10-3Hine and Mookerjee[1975]V1.2×10-33100Wilhelm et al.[1977]L1.1×10-3Mackay and Shiu[1981]L1.1×10-3Yaws and Yang[1992]?392-methylpropane8.5×10-4Hine and Mookerjee[1975]VHC(CH3)38.1×10-42700Wilhelm et al.[1977]L(isobutane)8.4×10-4Mackay and Shiu[1981]L8.7×10-4Yaws and Yang[1992]?39dimethylpropane4.6×10-4Hine and Mookerjee[1975]VC(CH3)45.9×10-43400Wilhelm et al.[1977]L(neopentane)2.7×10-4Mackay and Shiu[1981]Lpentane8.0×10-4Hine and Mookerjee[1975]VC5H128.1×10-4Mackay and Shiu[1981]L7.9×10-4Yaws and Yang[1992]?392-methylbutane7.3×10-4Mackay and Shiu[1981]LC5H127.3×10-4Yaws and Yang[1992]?39(isopentane)2,2-dimethylpropane4.7×10-4Yaws and Yang[1992]?39C5H12
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)15substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenotehexane5.5×10-4Hine and Mookerjee[1975]VC6H146.0×10-4Mackay and Shiu[1981]L7.7×10-4Yaws and Yang[1992]?391.0×10-37500Ashworth et al.[1988]X32-methylpentane5.8×10-4Hine and Mookerjee[1975]VC6H146.0×10-4Mackay and Shiu[1981]L(isohexane)5.8×10-4Yaws and Yang[1992]?39[107-83-5]1.3×10-1960Ashworth et al.[1988]X33-methylpentane5.9×10-4Hine and Mookerjee[1975]VC6H145.9×10-4Mackay and Shiu[1981]L8.9×10-4Yaws and Yang[1992]?392,2-dimethylbutane5.1×10-4Hine and Mookerjee[1975]VC6H145.9×10-4Mackay and Shiu[1981]L6.6×10-4Yaws and Yang[1992]?392,3-dimethylbutane7.8×10-4Mackay and Shiu[1981]LC6H147.7×10-4Yaws and Yang[1992]?39heptane4.9×10-4Hine and Mookerjee[1975]VC7H164.4×10-4Mackay and Shiu[1981]L1.2×10-33700Hansen et al.[1995]L3.7×10-4Yaws and Yang[1992]?391.2×10-33700Hansen et al.[1993]X32-methylhexane2.9×10-4Mackay and Shiu[1981]LC7H161.9×10-3-3600Hansen et al.[1995]M402.9×10-4Yaws and Yang[1992]?391.9×10-3-3500Hansen et al.[1993]X33-methylhexane4.2×10-4Mackay and Shiu[1981]LC7H163.2×10-4Yaws and Yang[1992]?392,2-dimethylpentane3.2×10-4Mackay and Shiu[1981]LC7H163.1×10-4Yaws and Yang[1992]?392,3-dimethylpentane5.8×10-4Mackay and Shiu[1981]LC7H165.8×10-4Yaws and Yang[1992]?392,4-dimethylpentane3.2×10-4Hine and Mookerjee[1975]VC7H163.4×10-4Mackay and Shiu[1981]L3.4×10-4Yaws and Yang[1992]?393,3-dimethylpentane5.4×10-4Mackay and Shiu[1981]LC7H165.5×10-4Yaws and Yang[1992]?393-ethylpentane3.9×10-4Yaws and Yang[1992]?39C7H162,2,3-trimethylbutane4.1×10-4Yaws and Yang[1992]?39C7H16
16R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenoteoctane3.1×10-4Hine and Mookerjee[1975]VC8H183.4×10-4Mackay and Shiu[1981]L2.0×10-4Yaws and Yang[1992]?392.9×10-37800Hansen et al.[1993]X32-methylheptane2.7×10-4Hoff et al.[1993]?13C8H182.7×10-4Yaws and Yang[1992]?393-methylheptane2.7×10-4Mackay and Shiu[1981]LC8H182.7×10-4Yaws and Yang[1992]?394-methylheptane2.7×10-4Yaws and Yang[1992]?39C8H182,2-dimethylhexane2.9×10-4Yaws and Yang[1992]?39C8H182,3-dimethylhexane2.6×10-4Yaws and Yang[1992]?39C8H182,4-dimethylhexane2.8×10-4Yaws and Yang[1992]?39C8H182,5-dimethylhexane3.0×10-4Yaws and Yang[1992]?39C8H183,3-dimethylhexane2.6×10-4Yaws and Yang[1992]?39C8H183,4-dimethylhexane2.4×10-4Yaws and Yang[1992]?39C8H18
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)17substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenote3-ethylhexane2.6×10-4Yaws and Yang[1992]?39C8H182,2,3-trimethylpentane2.6×10-4Yaws and Yang[1992]?39C8H182,2,4-trimethylpentane3.3×10-4Hine and Mookerjee[1975]VC8H183.1×10-4Mackay and Shiu[1981]L3.0×10-4Yaws and Yang[1992]?392,3,3-trimethylpentane2.4×10-4Yaws and Yang[1992]?39C8H182,3,4-trimethylpentane5.3×10-4Mackay and Shiu[1981]LC8H185.7×10-4Yaws and Yang[1992]?393-ethyl-2-methylpentane2.6×10-4Yaws and Yang[1992]?39C8H183-ethyl-3-methylpentane2.3×10-4Yaws and Yang[1992]?39C8H182,2,3,3-tetramethylbutane2.6×10-4Yaws and Yang[1992]?39C8H18
18R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenotenonane2.0×10-4Mackay and Shiu[1981]LC9H201.7×10-4Yaws and Yang[1992]?392.4×10-3210Ashworth et al.[1988]X32-methyloctane2.1×10-4Yaws and Yang[1992]?39C9H203-methyloctane2.0×10-4Yaws and Yang[1992]?39C9H204-methyloctane1.0×10-4Mackay and Shiu[1981]LC9H201.0×10-4Yaws and Yang[1992]?392,3-dimethylheptane1.9×10-4Yaws and Yang[1992]?39C9H202,2-dimethylheptane2.1×10-4Yaws and Yang[1992]?39C9H202,4-dimethylheptane2.1×10-4Yaws and Yang[1992]?39C9H202,5-dimethylheptane2.0×10-4Yaws and Yang[1992]?39C9H202,6-dimethylheptane2.1×10-4Yaws and Yang[1992]?39C9H203,3-dimethylheptane1.9×10-4Yaws and Yang[1992]?39C9H203,4-dimethylheptane1.8×10-4Yaws and Yang[1992]?39C9H203,5-dimethylheptane2.0×10-4Yaws and Yang[1992]?39C9H204,4-dimethylheptane1.9×10-4Yaws and Yang[1992]?39C9H203-ethylheptane1.9×10-4Yaws and Yang[1992]?39C9H204-ethylheptane1.9×10-4Yaws and Yang[1992]?39C9H20
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)19substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenote2,2,3-trimethylhexane1.9×10-4Yaws and Yang[1992]?39C9H202,2,4-trimethylhexane2.1×10-4Yaws and Yang[1992]?39C9H202,2,5-trimethylhexane2.9×10-4Mackay and Shiu[1981]LC9H201.9×10-4Yaws and Yang[1992]?392,3,3-trimethylhexane1.7×10-4Yaws and Yang[1992]?39C9H202,3,4-trimethylhexane1.8×10-4Yaws and Yang[1992]?39C9H202,3,5-trimethylhexane2.0×10-4Yaws and Yang[1992]?39C9H202,4,4-trimethylhexane1.9×10-4Yaws and Yang[1992]?39C9H203,3,4-trimethylhexane1.7×10-4Yaws and Yang[1992]?39C9H203-ethyl-2-methylhexane1.9×10-4Yaws and Yang[1992]?39C9H204-ethyl-2-methylhexane2.1×10-4Yaws and Yang[1992]?39C9H203-ethyl-3-methylhexane1.7×10-4Yaws and Yang[1992]?39C9H203-ethyl-4-methylhexane1.8×10-4Yaws and Yang[1992]?39C9H202,2,3,3-tetramethylpentane1.6×10-4Yaws and Yang[1992]?39C9H202,2,3,4-tetramethylpentane1.7×10-4Yaws and Yang[1992]?39C9H202,2,4,4-tetramethylpentane1.9×10-4Yaws and Yang[1992]?39C9H202,3,3,4-tetramethylpentane1.6×10-4Yaws and Yang[1992]?39C9H20
20R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenote3-ethyl-2,2-dimethylpentane1.8×10-4Yaws and Yang[1992]?39C9H203-ethyl-2,3-dimethylpentane1.5×10-4Yaws and Yang[1992]?39C9H203-ethyl-2,4-dimethylpentane1.8×10-4Yaws and Yang[1992]?39C9H203,3-diethylpentane1.5×10-4Yaws and Yang[1992]?39C9H20decane1.4×10-4Mackay and Shiu[1981]LC10H222.1×10-4Yaws and Yang[1992]?392-methylnonane1.8×10-4Yaws and Yang[1992]?39C10H223-methylnonane1.7×10-4Yaws and Yang[1992]?39C10H224-methylnonane1.7×10-4Yaws and Yang[1992]?39C10H225-methylnonane1.7×10-4Yaws and Yang[1992]?39C10H222,2-dimethyloctane1.7×10-4Yaws and Yang[1992]?39C10H222,3-dimethyloctane1.5×10-4Yaws and Yang[1992]?39C10H222,4-dimethyloctane1.7×10-4Yaws and Yang[1992]?39C10H222,5-dimethyloctane1.6×10-4Yaws and Yang[1992]?39C10H222,6-dimethyloctane1.6×10-4Yaws and Yang[1992]?39C10H22
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)21substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenote2,7-dimethyloctane1.7×10-4Yaws and Yang[1992]?39C10H223,3-dimethyloctane1.5×10-4Yaws and Yang[1992]?39C10H223,4-dimethyloctane1.5×10-4Yaws and Yang[1992]?39C10H223,5-dimethyloctane1.6×10-4Yaws and Yang[1992]?39C10H223,6-dimethyloctane1.6×10-4Yaws and Yang[1992]?39C10H224,4-dimethyloctane1.5×10-4Yaws and Yang[1992]?39C10H224,5-dimethyloctane1.5×10-4Yaws and Yang[1992]?39C10H223-ethyloctane1.6×10-4Yaws and Yang[1992]?39C10H224-ethyloctane1.6×10-4Yaws and Yang[1992]?39C10H222,2,3-trimethylheptane1.5×10-4Yaws and Yang[1992]?39C10H222,2,4-trimethylheptane1.6×10-4Yaws and Yang[1992]?39C10H22
22R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenote2,2,5-trimethylheptane1.6×10-4Yaws and Yang[1992]?39C10H222,2,6-trimethylheptane1.7×10-4Yaws and Yang[1992]?39C10H222,3,3-trimethylheptane1.4×10-4Yaws and Yang[1992]?39C10H222,3,4-trimethylheptane1.4×10-4Yaws and Yang[1992]?39C10H222,3,5-trimethylheptane1.4×10-4Yaws and Yang[1992]?39C10H222,3,6-trimethylheptane1.6×10-4Yaws and Yang[1992]?39C10H222,4,4-trimethylheptane1.5×10-4Yaws and Yang[1992]?39C10H222,4,5-trimethylheptane1.5×10-4Yaws and Yang[1992]?39C10H222,4,6-trimethylheptane1.8×10-4Yaws and Yang[1992]?39C10H222,5,5-trimethylheptane1.5×10-4Yaws and Yang[1992]?39C10H223,3,4-trimethylheptane1.3×10-4Yaws and Yang[1992]?39C10H223,3,5-trimethylheptane1.4×10-4Yaws and Yang[1992]?39C10H223,4,4-trimethylheptane1.3×10-4Yaws and Yang[1992]?39C10H223,4,5-trimethylheptane1.4×10-4Yaws and Yang[1992]?39C10H22
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)23substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenote3-ethyl-2-methylheptane1.5×10-4Yaws and Yang[1992]?39C10H224-ethyl-2-methylheptane1.6×10-4Yaws and Yang[1992]?39C10H225-ethyl-2-methylheptane1.6×10-4Yaws and Yang[1992]?39C10H223-ethyl-3-methylheptane1.4×10-4Yaws and Yang[1992]?39C10H224-ethyl-3-methylheptane1.4×10-4Yaws and Yang[1992]?39C10H223-ethyl-5-methylheptane1.6×10-4Yaws and Yang[1992]?39C10H223-ethyl-4-methylheptane1.4×10-4Yaws and Yang[1992]?39C10H224-ethyl-4-methylheptane1.4×10-4Yaws and Yang[1992]?39C10H224-propylheptane1.7×10-4Yaws and Yang[1992]?39C10H224-isopropylheptane1.5×10-4Yaws and Yang[1992]?39C10H222,2,3,3-tetramethylhexane1.2×10-4Yaws and Yang[1992]?39C10H222,2,3,4-tetramethylhexane1.2×10-4Yaws and Yang[1992]?39C10H22
24R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenote2,2,3,5-tetramethylhexane1.6×10-4Yaws and Yang[1992]?39C10H222,2,4,4-tetramethylhexane1.2×10-4Yaws and Yang[1992]?39C10H222,2,4,5-tetramethylhexane1.5×10-4Yaws and Yang[1992]?39C10H222,2,5,5-tetramethylhexane1.8×10-4Yaws and Yang[1992]?39C10H222,3,3,4-tetramethylhexane1.2×10-4Yaws and Yang[1992]?39C10H222,3,3,5-tetramethylhexane1.4×10-4Yaws and Yang[1992]?39C10H222,3,4,4-tetramethylhexane1.2×10-4Yaws and Yang[1992]?39C10H222,3,4,5-tetramethylhexane1.4×10-4Yaws and Yang[1992]?39C10H223,3,4,4-tetramethylhexane1.0×10-4Yaws and Yang[1992]?39C10H223-ethyl-2,2-dimethylhexane1.4×10-4Yaws and Yang[1992]?39C10H224-ethyl-2,2-dimethylhexane1.6×10-4Yaws and Yang[1992]?39C10H223-ethyl-2,3-dimethylhexane1.3×10-4Yaws and Yang[1992]?39C10H224-ethyl-2,3-dimethylhexane1.4×10-4Yaws and Yang[1992]?39C10H223-ethyl-2,4-dimethylhexane1.4×10-4Yaws and Yang[1992]?39C10H224-ethyl-2,4-dimethylhexane1.3×10-4Yaws and Yang[1992]?39C10H223-ethyl-2,5-dimethylhexane1.5×10-4Yaws and Yang[1992]?39C10H22
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)25substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenote4-ethyl-3,3-dimethylhexane1.3×10-4Yaws and Yang[1992]?39C10H223-ethyl-3,4-dimethylhexane1.3×10-4Yaws and Yang[1992]?39C10H223,3-diethylhexane1.3×10-4Yaws and Yang[1992]?39C10H223,4-diethylhexane1.4×10-4Yaws and Yang[1992]?39C10H223-isopropyl-2-methylhexane1.1×10-4Yaws and Yang[1992]?39C10H222,2,3,3,4-pentamethylpentane1.0×10-4Yaws and Yang[1992]?39C10H222,2,3,4,4-pentamethylpentane1.0×10-4Yaws and Yang[1992]?39C10H223-ethyl-2,2,3-trimethylpentane1.0×10-4Yaws and Yang[1992]?39C10H223-ethyl-2,2,4-trimethylpentane1.3×10-4Yaws and Yang[1992]?39C10H223-ethyl-2,3,4-trimethylpentane1.1×10-4Yaws and Yang[1992]?39C10H223,3-diethyl-2-methylpentane1.1×10-4Yaws and Yang[1992]?39C10H222,4-dimethyl-3-isopropylpentane1.3×10-4Yaws and Yang[1992]?39C10H22
26R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenoteundecane5.5×10-5Mackay and Shiu[1981]LC11H245.5×10-4Yaws and Yang[1992]?39dodecane1.4×10-4Mackay and Shiu[1981]LC12H261.4×10-4Yaws and Yang[1992]?39tridecane4.3×10-4Yaws and Yang[1992]?39C13H28tetradecane8.8×10-4Yaws and Yang[1992]?39C14H30pentadecane2.1×10-3Yaws and Yang[1992]?39C15H32hexadecane4.3×10-3Yaws and Yang[1992]?39C16H34heptadecane1.8×10-2Yaws and Yang[1992]?39C17H36octadecane1.1×10-1Yaws and Yang[1992]?39C18H38nonadecane3.4×10-1Yaws and Yang[1992]?39C19H40eicosane3.1Yaws and Yang[1992]?39C20H42
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)27substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenotecycloalkanes (CandHonly)cyclopropane1.1×10-21700Wilhelm et al.[1977]LC3H61.3×10-2Yaws and Yang[1992]?39, 41cyclopentane5.4×10-3Hine and Mookerjee[1975]VC5H105.5×10-3Mackay and Shiu[1981]L6.6×10-33400Hansen et al.[1995]M5.4×10-3Yaws and Yang[1992]?396.6×10-33300Hansen et al.[1993]X3cyclohexane5.1×10-3Hine and Mookerjee[1975]VC6H125.6×10-3Mackay and Shiu[1981]L5.2×10-3Yaws and Yang[1992]?395.6×10-33200Ashworth et al.[1988]X36.3×10-3710USEPA[1982]X3cycloheptane1.6×10-1Hoff et al.[1993]?13C7H141.1×10-2Yaws and Yang[1992]?39cyclooctane9.9×10-3Hoff et al.[1993]?13C8H169.6×10-3Yaws and Yang[1992]?39methylcyclopentane2.8×10-3Hine and Mookerjee[1975]VC5H9CH32.8×10-3Mackay and Shiu[1981]L2.8×10-3Yaws and Yang[1992]?39methylcyclohexane2.3×10-3Hine and Mookerjee[1975]VC6H11CH32.5×10-3Mackay and Shiu[1981]L9.7×10-39400Hansen et al.[1995]M2.3×10-3Yaws and Yang[1992]?399.4×10-39100Hansen et al.[1993]X3cis-1,2-dimethylcyclohexane2.8×10-3Hine and Mookerjee[1975]VC6H10(CH3)22.8×10-3Mackay and Shiu[1981]L2.8×10-3Yaws and Yang[1992]?39trans-1,2-dimethylcyclohexane2.1×10-3Yaws and Yang[1992]?39C6H10(CH3)2trans-1,4-dimethylcyclohexane1.1×10-3Mackay and Shiu[1981]LC6H10(CH3)21.1×10-3Yaws and Yang[1992]?391,1,3-trimethylcyclopentane6.4×10-4Mackay and Shiu[1981]LC5H7(CH3)3propylcyclopentane1.1×10-3Mackay and Shiu[1981]LC5H9C3H71.1×10-3Yaws and Yang[1992]?39pentylcyclopentane5.5×10-4Mackay and Shiu[1981]LC5H9C5H115.5×10-4Yaws and Yang[1992]?39decahydronaphthalene7.3×10-34100Ashworth et al.[1988]X3C10H18(decalin)[91-17-8]
28R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenotealiphatic alkenes and cycloalkenes (CandHonly)ethene4.9×10-3Loomis[1928]X1C2H44.7×10-3Hine and Mookerjee[1975]V(ethylene)4.7×10-31800Wilhelm et al.[1977]L4.7×10-3Mackay and Shiu[1981]L4.9×10-3Seinfeld[1986]?134.8×10-3Yaws and Yang[1992]?39propene4.8×10-3Hine and Mookerjee[1975]VC3H67.4×10-33400Wilhelm et al.[1977]L(propylene)4.8×10-3Mackay and Shiu[1981]L4.8×10-3Yaws and Yang[1992]?391-butene4.0×10-3Hine and Mookerjee[1975]VC4H81.3×10-26400Wilhelm et al.[1977]L1.4×10-3Mackay and Shiu[1981]L4.0×10-3Yaws and Yang[1992]?39cis-2-butene4.3×10-3Irrmann[1965]X42C4H8trans-2-butene4.4×10-3Irrmann[1965]X42C4H82-methylpropene4.7×10-3Hine and Mookerjee[1975]VC4H85.7×10-33000Wilhelm et al.[1977]L(isobutene)1.6×10-3Mackay and Shiu[1981]L4.8×10-3Yaws and Yang[1992]?391-pentene2.5×10-3Hine and Mookerjee[1975]VC5H102.5×10-3Mackay and Shiu[1981]L2.5×10-3Yaws and Yang[1992]?39cis-2-pentene4.4×10-3Mackay and Shiu[1981]LC5H104.4×10-3Yaws and Yang[1992]?39trans-2-pentene4.3×10-3Hine and Mookerjee[1975]VC5H104.3×10-3Yaws and Yang[1992]?392-methyl-2-butene4.5×10-3Hine and Mookerjee[1975]VC5H103-methyl-1-butene1.9×10-3Hine and Mookerjee[1975]VC5H101.9×10-3Mackay and Shiu[1981]L1.9×10-3Yaws and Yang[1992]?39
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)29substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenote1-hexene2.4×10-3Hine and Mookerjee[1975]VC6H122.4×10-3Mackay and Shiu[1981]L3.3×10-3Yaws and Yang[1992]?392-methyl-1-pentene3.6×10-3Mackay and Shiu[1981]LC6H123.6×10-3Yaws and Yang[1992]?394-methyl-1-pentene1.6×10-3Hine and Mookerjee[1975]VC6H121.6×10-3Mackay and Shiu[1981]L1.6×10-3Yaws and Yang[1992]?391-heptene2.5×10-3Yaws and Yang[1992]?39C7H14trans-2-heptene2.5×10-3Hine and Mookerjee[1975]VC7H142.4×10-3Mackay and Shiu[1981]L1-octene1.1×10-3Hine and Mookerjee[1975]VC8H161.1×10-3Mackay and Shiu[1981]L1.6×10-3Yaws and Yang[1992]?391-nonene1.2×10-3Yaws and Yang[1992]?39C9H181,3-butadiene1.6×10-2Hine and Mookerjee[1975]VC4H61.4×10-24500Wilhelm et al.[1977]L1.4×10-2Mackay and Shiu[1981]L1.4×10-2Yaws and Yang[1992]?39methylbutadiene1.3×10-2Hine and Mookerjee[1975]VC5H81.3×10-2Mackay and Shiu[1981]L(isoprene)2.8×10-2Karl and Lindinger[1997]M431.3×10-2Yaws and Yang[1992]?391,4-pentadiene8.3×10-3Hine and Mookerjee[1975]VC5H88.4×10-3Mackay and Shiu[1981]L8.5×10-3Yaws and Yang[1992]?391,5-hexadiene7.4×10-3Hine and Mookerjee[1975]VC6H102,3-dimethyl-1,3-butadiene2.1×10-2Hine and Mookerjee[1975]VC6H10cyclopentene1.6×10-2Hine and Mookerjee[1975]VC5H81.5×10-2Yaws and Yang[1992]?39cyclohexene2.2×10-2Hine and Mookerjee[1975]VC6H102.6×10-2Nielsen et al.[1994]M2.2×10-2Yaws and Yang[1992]?391-methylcyclohexene1.3×10-2Hine and Mookerjee[1975]VC6H9CH31,3,5-cycloheptatriene2.1×10-1Yaws and Yang[1992]?39C7H8
30R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenotealiphatic alkynes (CandHonly)ethyne4.2×10-2Hine and Mookerjee[1975]VC2H24.1×10-21800Wilhelm et al.[1977]L(acetylene)3.9×10-2Yaws and Yang[1992]?39propyne9.2×10-2Hine and Mookerjee[1975]VCH3CCH9.1×10-2Mackay and Shiu[1981]L(methylacetylene)9.4×10-2Yaws and Yang[1992]?39see noteWilhelm et al.[1977]?441-butyne5.4×10-2Hine and Mookerjee[1975]VC2H5CCH7.6×10-21900Wilhelm et al.[1977]L(ethylacetylene)5.3×10-2Mackay and Shiu[1981]L5.5×10-2Yaws and Yang[1992]?391-pentyne4.0×10-2Hine and Mookerjee[1975]VC3H7CCH4.1×10-2Mackay and Shiu[1981]L2.0×10-2Yaws and Yang[1992]?391-hexyne2.5×10-2Hine and Mookerjee[1975]VC4H9CCH4.6×10-2Yaws and Yang[1992]?391-heptyne1.5×10-2Hine and Mookerjee[1975]VC5H11CCH1.4×10-2Yaws and Yang[1992]?391-octyne1.2×10-2Hine and Mookerjee[1975]VC6H13CCH1.2×10-2Yaws and Yang[1992]?391-nonyne6.9×10-3Hine and Mookerjee[1975]VC7H15CCH7.0×10-3Yaws and Yang[1992]?393-buten-1-yne3.8×10-21700Wilhelm et al.[1977]LCH2CHCCH(vinylacetylene)butadiyne1.9×10-1Yaws and Yang[1992]?39C4H2(biacetylene)
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)31substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenotemononuclear aromatics (CandHonly)benzene1.8×10-1Hine and Mookerjee[1975]VC6H61.8×10-1Mackay et al.[1979]M[71-43-2]1.8×10-1Mackay et al.[1979]T1.8×10-1Mackay and Shiu[1981]L1.8×10-1Ettre et al.[1993]X451.9×10-13800Robbins et al.[1993]M2.1×10-1Nielsen et al.[1994]M2.1×10-13600Dewulf et al.[1995]M1.8×10-1Vitenberg et al.[1975]M1.6×10-14500Wasik and Tsang[1970]M1.8×10-1Bohon and Claussen[1951]V1.7×10-1Hoff et al.[1993]M2.2×10-14200Hartkopf and Karger[1973]M1.8×10-1Karl and Lindinger[1997]M431.8×10-1Yaws and Yang[1992]?391.7×10-13900Cooling et al.[1992]X31.8×10-12200USEPA[1982]X31.9×10-14300Kavanaugh and Trussell[1980]X31.2×10-15300Ervin et al.[1980]X31.6×10-14100Staudinger and Roberts[1996]L1.6×10-14300Bissonette et al.[1990]X31.8×10-13200Ashworth et al.[1988]X31.8×10-14000Leighton and Calo[1981]X31.8×10-1Allen et al.[1998]Emethylbenzene1.5×10-1McAuliffe[1971]X45C6H5CH31.5×10-1Hine and Mookerjee[1975]V(toluene)1.5×10-1Mackay et al.[1979]M[108-88-3]1.5×10-1Mackay et al.[1979]T1.5×10-1Mackay and Shiu[1981]L1.6×10-1Kolb et al.[1992]X451.6×10-1Ettre et al.[1993]X451.5×10-13400Robbins et al.[1993]M1.6×10-1Nielsen et al.[1994]M1.8×10-14100Dewulf et al.[1995]M1.9×10-1Vitenberg et al.[1975]M1.7×10-15900Wasik and Tsang[1970]M1.8×10-1Bohon and Claussen[1951]V1.3×10-1Hoff et al.[1993]M2.1×10-14600Hartkopf and Karger[1973]M1.6×10-1Yaws and Yang[1992]?391.5×10-11900USEPA[1982]X31.5×10-14000Staudinger and Roberts[1996]L1.4×10-15000Bissonette et al.[1990]X31.5×10-13000Ashworth et al.[1988]X31.5×10-13700Leighton and Calo[1981]X31.5×10-14900Ervin et al.[1980]X31.7×10-18400Lamarche and Droste[1989]X31.6×10-1Allen et al.[1998]E
32R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenote1,2-dimethylbenzene1.9×10-1Hine and Mookerjee[1975]VC6H4(CH3)22.0×10-1Mackay and Shiu[1981]L(o-xylene)1.9×10-13400Robbins et al.[1993]M[95-47-6]2.5×10-14200Dewulf et al.[1995]M2.9×10-15400Wasik and Tsang[1970]M2.4×10-1Yaws and Yang[1992]?391.9×10-13200Ashworth et al.[1988]X31.9×10-14000Staudinger and Roberts[1996]L2.1×10-15600Bissonette et al.[1990]X31,3-dimethylbenzene1.6×10-1Hine and Mookerjee[1975]VC6H4(CH3)21.4×10-1Mackay and Shiu[1981]L(m-xylene)1.6×10-14000Dewulf et al.[1995]M[108-38-3]1.7×10-1Bohon and Claussen[1951]V1.5×10-1Yaws and Yang[1992]?391.3×10-13300Ashworth et al.[1988]X31.3×10-14200Staudinger and Roberts[1996]L1.4×10-16000Bissonette et al.[1990]X31,4-dimethylbenzene1.6×10-1Hine and Mookerjee[1975]VC6H4(CH3)21.4×10-1Mackay and Shiu[1981]L(p-xylene)1.7×10-14500Dewulf et al.[1995]M[106-42-3]1.6×10-1Bohon and Claussen[1951]V2.3×10-15400Wasik and Tsang[1970]M1.6×10-1Yaws and Yang[1992]?391.2×10-13000Hansen et al.[1993]X31.2×10-15300Bissonette et al.[1990]X31.3×10-13500Ashworth et al.[1988]X31.3×10-13800Staudinger and Roberts[1996]L1,2,3-trimethylbenzene3.1×10-1Mackay and Shiu[1981]LC6H3(CH3)32.7×10-1Yaws and Yang[1992]?39[526-73-8]1,2,4-trimethylbenzene1.7×10-1Hine and Mookerjee[1975]VC6H3(CH3)31.7×10-1Mackay and Shiu[1981]L[95-63-6]1.5×10-14300Hansen et al.[1995]M1.8×10-1Yaws and Yang[1992]?391.5×10-14200Hansen et al.[1993]X31,3,5-trimethylbenzene1.7×10-1Mackay and Shiu[1981]LC6H3(CH3)31.2×10-1Yaws and Yang[1992]?39(mesitylene)1.4×10-13600Ashworth et al.[1988]X3[108-67-8]1,2,4,5-tetramethylbenzene4.0×10-2Mackay and Shiu[1981]LC6H2(CH3)43.9×10-2Yaws and Yang[1992]?39
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)33substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenoteethylbenzene1.2×10-1Hine and Mookerjee[1975]VC6H5C2H51.2×10-1Mackay et al.[1979]M[100-41-4]1.1×10-1Mackay et al.[1979]T1.3×10-1Mackay and Shiu[1981]L1.3×10-14600Robbins et al.[1993]M1.5×10-14600Dewulf et al.[1995]M1.5×10-1Bohon and Claussen[1951]V1.1×10-1Hoff et al.[1993]?131.7×10-16100Hartkopf and Karger[1973]M1.2×10-1Yaws and Yang[1992]?391.2×10-15100Staudinger and Roberts[1996]L1.6×10-11700USEPA[1982]X31.1×10-15500Bissonette et al.[1990]X31.2×10-15000Ashworth et al.[1988]X31.4×10-15500Ervin et al.[1980]X31.3×10-1Allen et al.[1998]Epropylbenzene1.0×10-1Hine and Mookerjee[1975]VC6H5C3H71.4×10-1Mackay and Shiu[1981]L[103-65-1]9.8×10-2Yaws and Yang[1992]?399.1×10-23700Ashworth et al.[1988]X3(2-propyl)-benzene6.8×10-2Hine and Mookerjee[1975]VC6H5C3H77.8×10-1Mackay and Shiu[1981]L(isopropylbenzene, cumene)6.9×10-2Hoff et al.[1993]?13[98-82-8]6.9×10-2Yaws and Yang[1992]?398.8×10-23200Hansen et al.[1993]X31-ethyl-2-methylbenzene2.4×10-1Mackay and Shiu[1981]LC6H4CH3C2H52.3×10-1Yaws and Yang[1992]?39(o-ethyltoluene)[611-14-3]1-ethyl-4-methylbenzene2.0×10-1Mackay and Shiu[1981]LC6H4CH3C2H52.0×10-1Yaws and Yang[1992]?39(p-ethyltoluene)[622-96-8]butylbenzene8.0×10-2Hine and Mookerjee[1975]VC6H5C4H97.8×10-2Mackay and Shiu[1981]L[104-51-8]7.6×10-2Yaws and Yang[1992]?392-methylpropylbenzene3.1×10-2Mackay and Shiu[1981]LC6H5C4H9[538-93-2]sec-butylbenzene8.7×10-2Hine and Mookerjee[1975]VC6H5C4H97.2×10-2Mackay and Shiu[1981]L[135-98-8]tert-butylbenzene8.5×10-2Hine and Mookerjee[1975]VC6H5C4H98.4×10-2Mackay and Shiu[1981]L[98-06-6]1-isopropyl-4-methylbenzene1.3×10-1Mackay and Shiu[1981]LC6H4CH3C3H7
34R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenotepentylbenzene1.7×10-1Mackay and Shiu[1981]LC6H5C5H116.0×10-2Yaws and Yang[1992]?39hexylbenzene4.6×10-2Yaws and Yang[1992]?39C6H5C6H13C6H5C5H115.5×10-2Hine and Mookerjee[1975]V(tert-amylbenzene)ethenylbenzene3.7×10-1Yaws and Yang[1992]?39C8H82.9×10-14800Bissonette et al.[1990]X3(styrene)3.8×10-14200USEPA[1982]X31-ethenyl-3-methylbenzene2.6×10-1Yaws and Yang[1992]?39C9H10(m-methylstyrene)1-ethenyl-4-methylbenzene3.5×10-1Yaws and Yang[1992]?39C9H10(p-methylstyrene)
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)35substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenoteterpenes and polynuclear aromatics (CandHonly)pinene4.9×10-2Karl and Lindinger[1997]M43C10H16[127-91-3]naphthalene2.4Hine and Mookerjee[1975]VC10H82.1Mackay et al.[1979]M2.1Mackay et al.[1979]T2.4Mackay and Shiu[1981]L1.9Bohon and Claussen[1951]V8.1×10-1Yaws and Yang[1992]?392.0Meylan and Howard[1991]X32.13600USEPA[1982]X31-methylnaphthalene2.3Mackay and Shiu[1981]LC10H7CH33.9Mackay and Shiu[1981]M2.7Yaws and Yang[1992]?392-methylnaphthalene2.5Mackay and Shiu[1981]LC10H7CH35.1×10-31200Hansen et al.[1995]M2.0Yaws and Yang[1992]?395.1×10-31200Hansen et al.[1993]X31-ethylnaphthalene2.7Mackay and Shiu[1981]LC10H7C2H52.7Yaws and Yang[1992]?392-ethylnaphthalene1.2Mackay and Shiu[1981]LC10H7C2H51.6Yaws and Yang[1992]?391,3-dimethylnaphthalene1.4Yaws and Yang[1992]?39C12H121,4-dimethylnaphthalene2.0Yaws and Yang[1992]?39C12H121,5-dimethylnaphthalene1.6Yaws and Yang[1992]?39C12H122,3-dimethylnaphthalene1.7Yaws and Yang[1992]?39C12H122,6-dimethylnaphthalene8.3×10-1Yaws and Yang[1992]?39C12H12biphenyl2.5Mackay et al.[1979]M(C6H5)23.6Mackay and Shiu[1981]L3.3Mackay and Shiu[1981]M1.2Bohon and Claussen[1951]V1.2Yaws and Yang[1992]?39
36R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenoteacenaphthene1.3×101Hine and Mookerjee[1975]VC12H106.8Mackay et al.[1979]M[83-32-9]4.2Mackay and Shiu[1981]L6.5×10-1Mackay and Shiu[1981]M4.12800USEPA[1982]X36.5Meylan and Howard[1991]X3phenanthrene3.9×101Hine and Mookerjee[1975]VC14H102.5×101Mackay et al.[1979]M2.5×101Mackay and Shiu[1981]L2.8×101Mackay and Shiu[1981]M2.8×101Meylan and Howard[1991]X39.54700USEPA[1982]X32,3-benzindene1.2×101Mackay and Shiu[1981]LC13H101.0×101Mackay and Shiu[1981]M(fluorene)8.53000USEPA[1982]X3[86-73-7]1.0×101Meylan and Howard[1991]X3anthracene5.6×101Hine and Mookerjee[1975]VC14H101.7×101Mackay and Shiu[1981]L[120-12-7]1.4Mackay and Shiu[1981]M1.5×101Meylan and Howard[1991]X33.5×1014000USEPA[1982]X3pyrene8.4×101Mackay and Shiu[1981]LC16H109.2×101Mackay and Shiu[1981]M[129-00-0]fluoranthene4.6×10-1Mackay and Shiu[1981]LC16H101.1×1026900tenHulscher et al.[1992]X3[206-44-0]benzo[a]fluoranthene1.7×1035900tenHulscher et al.[1992]X39.7×10-11900USEPA[1982]X3benzo[b]fluoranthene1.5×1035500tenHulscher et al.[1992]X3benzo[k]fluoranthene1.7×1035900tenHulscher et al.[1992]X3indeno[1,2,3-cd]pyrene2.9×1033600tenHulscher et al.[1992]X3benzo[a]pyrene1.6×10-1110USEPA[1982]X3C20H122.2×1034700tenHulscher et al.[1992]X3[50-32-8]benzo[ghi]perylene3.0×1033200tenHulscher et al.[1992]X3C22H12[191-24-2]1,2,3,4-tetrahydronaphthalene5.3×10-15400Ashworth et al.[1988]X3C10H12(tetralin)[119-64-2]
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)37substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenotealcohols (ROH) (C,H, andOonly)methanol2.3×102Butler et al.[1935]M46CH3OH2.3×102Burnett[1963]M2.1×102Timmermans[1960]M,X472.2×102Gaffney and Senum[1984]X482.2×1025200Snider and Dawson[1985]M1.4×102Yaws and Yang[1992]?391.6×1025600Schaffer and Daubert[1969]X32.2×102Meylan and Howard[1991]X3ethanol1.9×102Butler et al.[1935]MC2H5OH2.2×102Burnett[1963]M1.6×102Timmermans[1960]M,X472.0×102Gaffney and Senum[1984]X481.9×1026600Snider and Dawson[1985]M2.3×102Rohrschneider[1973]M1.2×102Yaws and Yang[1992]?391.5×1026400Schaffer and Daubert[1969]X32.0×102Meylan and Howard[1991]X31-propanol1.4×102Butler et al.[1935]M46C3H7OH1.6×102Burnett[1963]M[71-23-8]1.3×1027500Snider and Dawson[1985]M1.5×102Snider and Dawson[1985]C1.1×102Yaws and Yang[1992]?392-propanol1.2×102Butler et al.[1935]MC3H7OH1.7×102Hine and Weimar[1965]R(isopropanol)1.3×1027500Snider and Dawson[1985]M[67-63-0]8.9×101Yaws and Yang[1992]?391-butanol1.2×102Butler et al.[1935]M46C4H9OH1.1×102Buttery et al.[1969]M[71-36-3]1.4×102Burnett[1963]M1.3×1027200Snider and Dawson[1985]M1.2×102Snider and Dawson[1985]C5.4×101Friant and Suffet[1979]M492-butanol9.8×101Butler et al.[1935]MC4H10O9.8×101Butler et al.[1935]V(sec-butanol)1.1×1027300Snider and Dawson[1985]M[78-92-2]2-methyl-1-propanol8.4×101Butler et al.[1935]MC4H10O1.0×102Snider and Dawson[1985]M(isobutanol)[78-83-1]2-methyl-2-propanol8.4×101Butler et al.[1935]MC4H10O7.0×1018300Snider and Dawson[1985]M(tert-butanol)see noteKoga[1995]M50[75-65-0]
38R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenote1-pentanol7.7×101Butler et al.[1935]MC5H11OH7.9×101Butler et al.[1935]V(amylalcohol)8.2×101Yaws and Yang[1992]?39[71-41-0]2-pentanol6.8×101Butler et al.[1935]MC5H12O(sec-pentanol)[6032-29-7]2-methyl-1-butanol7.1×101Butler et al.[1935]MC5H12O(isopentanol)[137-32-6]2-methyl-2-butanol7.3×101Butler et al.[1935]MC5H12O(tert-pentanol)[75-85-4]2,2-dimethyl-1-propanol5.0×101Saxena and Hildemann[1996]E51C5H12O[75-84-3]1-hexanol6.5×101Butler et al.[1935]VC6H13OH5.9×101Buttery et al.[1969]M[111-27-3]6.5×101Hine and Mookerjee[1975]V5.4×101Yaws and Yang[1992]?393-hexanol2.0×101Hine and Mookerjee[1975]VC6H14O[623-37-0]2-methyl-2-pentanol3.1×101Hine and Mookerjee[1975]VC6H14O[590-36-3]4-methyl-2-pentanol2.2×101Hine and Mookerjee[1975]VC6H14O[108-11-2]2-methyl-3-pentanol2.9×101Hine and Mookerjee[1975]VC6H14O[565-67-3]2,3-dimethyl-2-butanol3.0×101Hine and Mookerjee[1975]VC6H14O[594-60-5]1-heptanol5.3×101Butler et al.[1935]VC7H15OH5.4×101Hine and Mookerjee[1975]V[110-70-6]8.6×101Yaws and Yang[1992]?391-octanol4.1×101Butler et al.[1935]VC8H17OH4.2×101Hine and Mookerjee[1975]V[111-87-5]4.0×101Buttery et al.[1969]M6.3×101Yaws and Yang[1992]?39
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)39substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenote1-nonanol6.1×101Yaws and Yang[1992]?39C9H19OH1-decanol3.7×101Yaws and Yang[1992]?39C10H21OH1-dodecanol1.1×101Yaws and Yang[1992]?39C12H25OH1-tetradecanol3.9×105Yaws and Yang[1992]?39C14H29OH1-pentadecanol3.0×105Yaws and Yang[1992]?39C15H31OH1-hexadecanol6.0×101Yaws and Yang[1992]?39C16H33OH1-heptadecanol1.2×103Yaws and Yang[1992]?39C17H35OH1-octadecanol9.2×101Yaws and Yang[1992]?39, 52C18H37OHcyclohexanol1.7×102Hine and Mookerjee[1975]VC6H11OH[108-93-0]2-propen-1-ol2.0×102Pierotti et al.[1957]X53C3H5OH1.8×102Yaws and Yang[1992]?39(allyl alcohol)2.0×102Meylan and Howard[1991]X3[107-18-6]4.4×1027200USEPA[1982]X32-buten-1-ol3.0×102Saxena and Hildemann[1996]E51CH3CHCHCH2OH2-methyl-3-buten-2-ol6.5×101Iraci et al.[1998]M49[115-18-4]
40R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenotehydroxybenzene4.9×102Hine and Weimar[1965]RC6H5OH3.0×103Gaffney and Senum[1984]X48(phenol)2.9×1036800Parsons et al.[1971]M547.8×10-2Howe et al.[1987]X111.9×1023600Janini and Quaddora[1986]X33.0×103Meylan and Howard[1991]X31.9×1037300USEPA[1982]X31.6×103Tremp et al.[1993]X55,8(hydroxymethyl)benzene9.0×103Saxena and Hildemann[1996]E51C6H5CH2OH(benzyl alcohol)[100-51-6]4-tert-butylphenol9.0×1027700Parsons et al.[1972]M56(CH3)3CC6H4OH1-hydroxy-2-methylbenzene8.3×102Gaffney and Senum[1984]X48HOC6H4CH38.3×1027300Parsons et al.[1972]M56(2-cresol,o-cresol)1.2×103Yaws and Yang[1992]?39, 8[95-48-7]2.6×1024600Janini and Quaddora[1986]X38.3×102Meylan and Howard[1991]X31-hydroxy-3-methylbenzene1.4×103Yaws and Yang[1992]?39, 8HOC6H4CH36.3×1027700Janini and Quaddora[1986]X3(3-cresol,m-cresol)[108-39-4]1-hydroxy-4-methylbenzene1.0×103Gaffney and Senum[1984]X48HOC6H4CH31.3×1037200Parsons et al.[1972]M56(4-cresol,p-cresol)2.5×103Yaws and Yang[1992]?39, 8[106-44-5]1.1×103Meylan and Howard[1991]X35.3×1024600Janini and Quaddora[1986]X31,3-dimethyl-4-hydroxybenzene1.9×10-1-3300Ashworth et al.[1988]X3C8H10O4.1×1026600USEPA[1982]X3(2,4-dimethylphenol)[105-67-9]
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)41substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenotepolyols (R(OH)n) (C,H, andOonly)1,2-ethanediol1.7×104Butler and Ramchandani[1935]M57HO(CH2)2OH4.0×106Bone et al.[1983]M8(ethylene glycol)[107-21-1]1,2-propanediol>1.0×105Saxena and Hildemann[1996]E51C3H8O2<6.0×106Saxena and Hildemann[1996]E511,3-propanediol9.2×105Bone et al.[1983]M8C3H8O21,2,3-propanetriol6.0×104Butler and Ramchandani[1935]M57C3H8O3>6.0×108Saxena and Hildemann[1996]E51(glycerol)<4.0×1011Saxena and Hildemann[1996]E511,3-butanediol5.0×106Saxena and Hildemann[1996]E51C4H10O21,4-butanediol>1.0×105Saxena and Hildemann[1996]E51C4H10O2<5.0×106Saxena and Hildemann[1996]E512,3-butanediol>4.0×104Saxena and Hildemann[1996]E51C4H10O2<4.0×106Saxena and Hildemann[1996]E511,2,3-butanetriol3.0×1011Saxena and Hildemann[1996]E51C4H10O31,2,4-butanetriol3.0×1011Saxena and Hildemann[1996]E51C4H10O31,2,3,4-tetrahydroxy butane2.0×1016Saxena and Hildemann[1996]E51C4H10O41,5-pentanediol4.0×106Saxena and Hildemann[1996]E51C5H12O22,3-pentanediol3.0×106Saxena and Hildemann[1996]E51C5H12O22,4-pentanediol3.0×106Saxena and Hildemann[1996]E51C5H12O21,2,3,4,5-pentahydroxy pentane9.0×1020Saxena and Hildemann[1996]E51C5H12O51,6-hexanediol3.0×106Saxena and Hildemann[1996]E51C6H14O2
42R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenote2,5-hexanediol2.0×106Saxena and Hildemann[1996]E51C6H14O22-methyl-1,3-pentanediol3.0×106Saxena and Hildemann[1996]E51C6H14O22-methyl-2,4-pentanediol2.0×106Saxena and Hildemann[1996]E51C6H14O21,2,6-hexanetriol2.0×1011Saxena and Hildemann[1996]E51C6H14O31,2,3,4,5,6-hexahydroxy hexane4.0×1025Saxena and Hildemann[1996]E51C6H14O61,2,4,5-tetrahydroxy cyclohexane4.0×1016Saxena and Hildemann[1996]E51C6H12O41,2,3,4,5,6-hexahydroxy cyclohexane1.0×1026Saxena and Hildemann[1996]E51C6H12O61,7-heptanediol2.0×106Saxena and Hildemann[1996]E51C7H16O22,4-heptanediol2.0×106Saxena and Hildemann[1996]E51C7H16O22,3-diethyl-1,3-propanediol2.0×106Saxena and Hildemann[1996]E51C7H16O22-ethyl-1,3-hexanediol2.0×106Saxena and Hildemann[1996]E51C8H18O21,2,3,4,5-pentahydroxy heptane5.0×1020Saxena and Hildemann[1996]E51C7H16O51,2,3,4,6-pentahydroxy heptane4.0×1020Saxena and Hildemann[1996]E51C7H16O51,2,3,5,7-pentahydroxy heptane5.0×1020Saxena and Hildemann[1996]E51C7H16O51,2,3,4,5,6-hexahydroxy heptane3.0×1025Saxena and Hildemann[1996]E51C7H16O6
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)43substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenote1,2-dihydroxybenzene4.6×103Mackay et al.[1995]VC6H4(OH)2(pyrocatechol)[120-80-9]1,3-dihydroxybenzene8.3×1066300USEPA[1982]X3C6H4(OH)2(resorcinol)[108-46-3]1,4-dihydroxybenzene2.6×107Meylan and Howard[1991]X58C6H4(OH)21.7×107Meylan and Howard[1991]X58(hydroquinone)2.5×107Mackay et al.[1995]V[123-31-9]peroxides (ROOH) and peroxy radicals (ROO) (C,H, andOonly)methyl hydroperoxide3.0×1025300Lind and Kok[1994]M9CH3OOH3.1×1025200O"Sullivan et al.[1996]M(methylperoxide)[3031-73-0]ethyl hydroperoxide3.4×1026000O"Sullivan et al.[1996]MC2H5OOH(ethylperoxide)hydroxymethyl hydroperoxide1.7×1069700O"Sullivan et al.[1996]MHOCH2OOH1.6×10610000Staffelbach and Kok[1993]M(HMHP,HMP)4.8×1051500Zhou and Lee[1992]M[15932-89-5]bis(hydroxymethyl)peroxide>1.0×107Staffelbach and Kok[1993]MHOCH2OOCH2OH4.5×1058400Zhou and Lee[1992]M(BHMP)[17088-73-2]methylperoxy radical6.05600Jacob[1986]E59CH3OO2.0×1036600Lelieveld and Crutzen[1991]E60peroxyacetyl radical<0.1Villalta et al.[1996]MCH3C(O)O2[36709-10-1]
44R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenotealdehydes (RCHO) (C,H, andOonly)methanalsee noteLedbury and Blair[1925]M61HCHO6.0×103Gaffney and Senum[1984]X48(formaldehyde)7.0×1036400Chameides[1984]T[50-50-0]see noteDong and Dasgupta[1986]M626.3×103Seinfeld[1986]?133.0×1037200Betterton and Hoffmann[1988]M631.4×104Warneck[1988]C3.1×1036500Zhou and Mopper[1990]M643.0×1037200M¨oller and Mauersberger[1992]c3.2×1036800Staudinger and Roberts[1996]Lethanal1.5×101Buttery et al.[1969]MCH3CHO1.5×101Gaffney and Senum[1984]X48(acetaldehyde)1.3×1015800Snider and Dawson[1985]M[75-07-0]1.1×1016300Betterton and Hoffmann[1988]M631.7×1015000Zhou and Mopper[1990]M641.3×1015700Benkelberg et al.[1995]M1.5×101Pierotti et al.[1957]X659.9Yaws and Yang[1992]?391.7×1014700USEPA[1982]X31.74500Janini and Quaddora[1986]X31.4×1015600Staudinger and Roberts[1996]Lpropanal1.3×101Buttery et al.[1969]MC2H5CHO1.3×101Snider and Dawson[1985]C(propionaldehyde)1.3×1015700Zhou and Mopper[1990]M64[123-38-6]2.82400Janini and Quaddora[1986]X35.35600Schaffer and Daubert[1969]X3butanal9.66200Zhou and Mopper[1990]M64C3H7CHO8.7Buttery et al.[1969]M(butyraldehyde)5.54000Janini and Quaddora[1986]X3[123-72-8]pentanal6.46300Zhou and Mopper[1990]M64C4H9CHO6.8Buttery et al.[1969]M(valeraldehyde)4.4Yaws and Yang[1992]?39, 49[110-62-3]hexanal4.96500Zhou and Mopper[1990]M64C5H11CHO4.7Buttery et al.[1969]M1.9Yaws and Yang[1992]?39, 49heptanal3.37500Zhou and Mopper[1990]M64C6H13CHO3.7Buttery et al.[1969]M2.3Yaws and Yang[1992]?39, 49octanal2.17400Zhou and Mopper[1990]M64C7H15CHO1.9Buttery et al.[1969]M2.1×102Yaws and Yang[1992]?39, 49nonanal1.06700Zhou and Mopper[1990]M64C8H17CHO1.3Buttery et al.[1969]M7.0×10-1Yaws and Yang[1992]?39, 49decanal6.1×10-18700Zhou and Mopper[1990]M64C9H19CHO
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)45substancek?H[M/atm]-dlnkHd(1/T)[K]referencetypenotepropenal8.2Gaffney and Senum[1984]X48CH2CHCHO7.45100Snider and Dawson[1985]M(acrolein)1.0×1013800USEPA[1982]X3[107-02-8]8.2Meylan and Howard[1991]X32-methylpropenal4.35300Allen et al.[1998]EC4H6O6.5Iraci et al.[1998]M(methacrolein)[78-85-3]trans-2-butenal5.2×101Buttery et al.[1971]MCH3CHCHCHO5.1×101Gaffney and Senum[1984]X48(crotonaldehyde)5.1×101Meylan and Howard[1991]X36.0×1013600USEPA[1982]X3trans-2-hexenal2.0×101Buttery et al.[1971]MC3H7CHCHCHOtrans-trans-2,4-hexadienal1.0×102Buttery et al.[1971]MCH3CHCHCHCHCHOtrans-2-octenal1.3×101Buttery et al.[1971]MC5H11CHCHCHOsee notesee note?66benzaldehyde3.6×101Hine and Mookerjee[1975]VC6H5CHO3.6×101Gaffney and Senum[1984]X48[100-52-7]3.7×1015100Betterton and Hoffmann[1988]M634.2×1014600Zhou and Mopper[1990]M643.9×1014800Staudinger and Roberts[1996]L3.5×1017000Allen et al.[1998]E3-hydroxybenzaldehyde4.0×105Gaffney and Senum[1984]X48C6H4(OH)CHO(3-formylphenol)4-hydroxybenzaldehyde1.9×1068600Parsons et al.[1971]M54C6H4(OH)CHO(4-formylphenol)generic aldehyde4.2×103Graedel and Goldberg[1983]CRCHOethanedial>3.0×105Betterton and Hoffmann[1988]M63OHCCHO3.6×105Zhou and Mopper[1990]M(glyoxal)
46R. Sander: Henry"s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)substancek?
H[M/atm]-dlnkHd(1/T)[K]referencetypenoteketones (RCOR) (C,H, andOonly)propanone3.0×101Butler and Ramchandani[1935]RCH3COCH32.8×101Burnett[1963]M(acetone)3.1Hine and Weimar[1965]R[67-64-1]2.5×101Buttery et al.[1969]M3.0×101Gaffney and Senum[1984]X482.6×1014800Snider and Dawson[1985]M3.5×1013800Zhou and Mopper[1990]M643.2×1015800Betterton[1991]M2.7×1015300Benkelberg et al.[1995]M2.5×101Vitenberg et al.[1975]M2.5×101Vitenberg et al.[1974]X672.7×101Hoff et al.[1993]M2.3×101Yaws and Yang[1992]?392.2×1015000Schaffer and Daubert[1969]X33.03300Janini and Quaddora[1986]X33.0×1014600Staudinger and Roberts[1996]L2-butanone7.1Hine and Weimar[1965]RC2H5COCH31.8×1015700Snider and Dawson[1985]M(methyl ethyl ketone, MEK)2.1×101Buttery et al.[1969]M[78-93-3]7.7Ashworth et al.[1988]X682.0×1015000Zhou and Mopper[1990]M644.1...7.7Howe et al.[1987]X111.8×101Vitenberg et al.[1975]M1.9×101Rohrschneider[1973]M1.7×101Vitenberg et al.[1974]X671.0×101Friant and Suffet[1979]M492.0×1015000Staudinger and Roberts[1996]L6.9-5200Ashworth et al.[1988]X37.25800Janini and Quaddora[1986]X32-pentanone1.6×101Buttery et al.[1969]MC3H7COCH31.2×101Meylan and Howard[1991]X3[107-87-9]9.24600Janini and Quaddora[1986]X33-pentanone2.0×1019200Janini and Quaddora[1986]X3C2H5COC2H52-heptanone7.0Buttery et al.[1969]MC5H11COCH33.5×1014500Janini and Quaddora[1986]X3[110-43-0]6.3Meylan and Howard[1991]X3
R. Sander: Henry"s law constants (http://www.mpch-mainz.mpquotesdbs_dbs19.pdfusesText_25