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[PDF] Herbal shampoo

FORMULATION &

EVALUATION OF SHAMPOO

V.MANIMARAN

LECTURER

DEPARTMENT OF PHARMACEUTICS

SRM COLLEGE OF PHARMACY

UNIT V

CONTENTS

1.Introduction

2.TypesofShampoos

3.ProductIngredients

4.Formulation

5.EvaluationofShampoos

6.References

Introduction

•Definition:A shampoo is a preparation of a surfactant (i.e.surface active material) in a suitable form - liquid, solid orpowder - which when used under the specified conditionswill remove surface grease, dirt, and skin debris from the hairshaft and scalp without adversely affecting the user.

•Requirements of a Shampoo:

1.It should effectively and completely remove dust or soil,excessive sebum or other fatty substances and loose cornealcells from the hair.

2.It should produce a good amount of foam to satisfy thepsychological requirements of the user.

3.It should be easily removed on rinsing with water.

4.It should leave the hair nonͲdry, soft, lustrous with goodmanageability and minimum fly away.

5.It should impart a pleasant fragnance to the hair.

6.It should not cause any sideͲeffects / irritation to skin or eye.

7.It should not make the hand rough and chapped.

Types of

Shampoo

Shampoos are of the following types:

Powder Shampoo

Liquid Shampoo

Lotion Shampoo

Cream Shampoo

Jelly Shampoo

Aerosol Shampoo

Specialized Shampoo

•Conditioning Shampoo •AntiͲdandruff Shampoo •Baby Shampoo •Two Layer Shampoo

PRODUCT INGREDIENTS

•Surfactants are the main component of shampoo. Mainly anionic surfactants are used. •The raw materials used in the manufacture of shampoos are:

1.Principal surfactants: Provide detergency and foam.

2.Secondary surfactants: Improve detergency, foam and hair

condition.

3.Other additives.

CLEANSING ACTION OF SHAMPOO

AsurfactantconsistsoftwopartͲonehydrophilic(waterloving) while theotherishydrophobicinnature.

Surfactants

Anionic surfactantsare mostly used (good foaming

properties). The hydrophilic portion carries a negative charge which results in superior foaming, cleaning and end result attributes. NonͲionicsurfactantshavegoodcleansingproperties butdonothavesufficientfoamingpower.

Cationicsurfactantsaretoxicandarehencenotused.

However,theymaybeusedinlowconcentrationin

hairconditioners.

Ampholytics,beingexpensive,aregenerallynotused.

However,theyaremainlyusedassecondary

surfactantsandgoodhairconditioners.

ANIONICSURFACTANTS

CLASSEXAMPLECOMMENT

Alkylbenzene

sulfonatesSodiumdodecyl benzene sulfonateTendtoyieldan"airy"orlowdensityfoam and oftenaredryingtothehair

PrimaryalkylsulfatesLauric acid, stearic acid and

their saltsGoodlatheringeffectinhard water,freefrom rancidity,easytowash.

Secondaryalcohol

sulfatesSodiumsecͲlauryl sulfateLow cost,dispersingandemulsifyingaction, dissapointingasdetergets andshampoo components

Alkylbenzene

polyoxyethylene sulfonatesTriton

X200Stableinacid oralkalinesolution,excellent

emulsifier,detergentandwettingagent; extremelystableatpHofskin

Sulfated

monoglyceridesLauric monoglyceride ammoniumsulfateStableinhardwater

AlkylethersulfatesDerivativesoflauryl alcohol

etherwithPEGGoodcleansers, actassolventsfornonpolar additives

SarcosinesLauroyl andcocoyl

sarcosinesExcellentfoaming andconditioningaction SulfosuccinatesAerosolOTLessirritatingtoskinandeye(babyshampoo)

MayponProtalbinic andlysalbinic

acidderivatives(maypon 4C)Hydrolysation productofproteinswithfatty acidchloridesinpresenceofalkali

NONͲIONICSURFACTANTS

CLASSEXAMPLECOMMENTS

Fattyacid

alkanolamides (should notbeused>15%)Lauric monoethanolamideImproves solubilityofSLS

Stearic ethanolamidePearlescentthickener

OleicethanolamidesHairconditioning agents

Polyalkoxylated

derivativesEthoxylated fattyalcoholsStableinwiderangeofpH;stabilizing emulsifying andopacifying properties Blockpolymers(pluronics)Good rinsability,canbeusedinhigh% Sorbitol esters(TWEENS)Solubilizersandemulsifiers,usedinbaby shampoos

AmineoxidesCoconutanddodecyl

dimethyl amineoxidesFoamboosterandantiͲstaticagents

AMPHOTERICSURFACTANTS

NͲalkylaminoacidsɴ- aminoacid derivativesFoamingagents Aspargine derivativesCompatiblewithbothanionic and cationicsurfactants

BetainsAmido betainsHighfoamingproperties,mild.

Alkyl imidazolineMIRANOL TM

Babyshampoos

ADDITIVES

Conditioningagents:Lanolin,mineraloil,herbalextracts,eggderivatives. Foam builders:Lauroyl monoethanolamide, sarcosinates

Viscositymodifiers:

Electrolytes-NH

4

Cl,NaCl

Naturalgums-GumKaraya,tragacanth,alginates

Cellulosederivatives-Hydroxyethylcellulose,methylcellulose

Carboxy vinylpolymers- Carbopol 934

Others-PVP,phosphateesters.

Sequesteringagents:EDTA

Opacifying agents:Alkanolamides ofhigherfattyacids,propyleneglycol,Mg,CaandZnsaltsofstearic acid,spermaceti,etc.

Clarifyingagents:

Solubilizing alcohols-ethanol,isopropanol

Phosphates-

NonͲionicsolubilizers - polyethoxyated alcoholsandesters.

ADDITIVES

Perfumes:Herbal,fruityorfloralfragnances.

Preservatives:Methylandpropyl paraben,

formaldehyde(mosteffective).

AntiͲdandruff agents:Theshampooscontainsmall

amount of these actives, which are in contact with the scalp for only a short time. In order to be effective the active ingredient must work in the oilͲ waterenvironmentofthescalpandmustbereadily substantive to the scalp for continuing activity.

Ex:Seleniumsulfide,zincpyrithone,salicylicacid.

FORMULATIONS

POWDER

SHAMPOO

Henna powder5%

Soappowder50%

Sodiumcarbonate22.5%

Potassiumcarbonate7.5%

Borax15%

Perfumeq.S

LIQUIDSHAMPOO

SLS40%

NaCl(todesiredviscosity)2Ͳ4%

WaterUpto 100%

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