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EQUILIBRIUM AND LE CHÂTELIER'S PRINCIPLE Reversible chemical reactions reach equilibrium in closed systems (no substances added or lost)



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CONCENTRATION

EQUILIBRIUM AND LE CH

EQUILIBRIUM

BY © Andy Brunning/Compound Interest 2017 - www.compoundchem.com This graphic is shared under a Creative Commons Attribution-NonCommercial-NoDerivatives licence.

A + B C + D

In reversible reactions products of the

2

1 removes dirt at the same

LE CH

Le Châtelier's principle states that when

A + 2B

EXOTHERMIC

(increases temperature)

TEMPERATURE INCREASED

The equilibrium position shifts

THE ENDOTHERMIC REACTION

In the example below the new

TEMPERATURE DECREASED

The equilibrium position shifts

THE EXOTHERMIC REACTION

In the example above the new

The equilibrium position shifts

SIDE OF REACTION WITH FEWER

In the example below the new

PRESSURE DECREASED

The equilibrium position shifts

SIDE OF REACTION WITH MORE

In the example above the new

REACTANT CONCENTRATION INCREASED

The equilibrium position shifts to

REACTION FORMING

In the example below the new

PRODUCT CONCENTRATION INCREASED

The equilibrium position shifts to

REACTION FORMING

In the example above the new

A + 2B

REDUCES REACTANT CONCENTRATION

A + 2B

DECREASES PRESSURE

(more gas molecules on left) Increasing concentration of one side favours the other.

Note: using a catalyst increases the rate of both the forwards and backwards reactions but doesn't change the equilibrium position.

An analogy for changing equilibrium conditions

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