[PDF] Formulae For ELECTROCHEMISTRY - WordPresscom PDF electrochemisty1.pdf

3 Ecell = Eө cell - 2 303RT [Anode ion] log nF [Cathode ion] 4 Eө cell = c 0 059 logK 12 κ Λ m x1000 = C Remember: Unit of Λm in above formula is Scm2mol-1 13 α c m 0 m ∧ = ∧ 14 2 a cα K = 1-α XII Chemistry CHAPTER 3 -

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0.0591

log n [M] & өc '

2.303RT[Anode ion]

log nF[ Cathodeion] c 0.059 logK n (At 298 K) l A 1 l A 1

Conductance:G=

R # Conductivity = Conductance × Cell constant 1 1 ρR l A = = G l A / Cell constant and is denoted by the symbol G* Λ0 12 3/// 2 -45 6 748
0' 2 ac K =

1-α

XII Chemistry

CHAPTER 3 - ELECTROCHEMISTRY

Mir Mohammed Abbas II PCMB 'A'

ELECTROCHEMISTRYFORMULAS- ELECTROCHEMISTY

15. Kohlrausch"s Law of independent migration of ions:

If the limiting molar conductivity of the cations is denoted by o and that of the anions by o then the limiting molar conductivity of electrolyte is: 0 00 m

ν λv λ

Where v+ and v- are the number of cations and anions per formula of electrolyte.

16. Faraday constant: It is equal to 96487 C mol-1 or approximately equal to

96500 C mol-1.

quotesdbs_dbs21.pdfusesText_27

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