[PDF] [PDF] Haloalkanes and Haloarenes - NCERT

Haloalkanes and haloarenes may be classified as follows: These may by passing dry hydrogen chloride gas through a solution of alcohol or by heating The carbocation thus formed gets stabilised through resonance (Unit 12, Class XI ) as



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[PDF] Chemistry Notes for class 12 Chapter 10 Haloalkanes - Ncert Help

www ncerthelp com (Visit for all ncert solutions in text and videos, CBSE syllabus, in the formation of alkyl halide (haloalkane) and aryl halide (haloarene),



[PDF] Haloalkanes and Haloarenes - NCERT

Haloalkanes and haloarenes may be classified as follows: These may by passing dry hydrogen chloride gas through a solution of alcohol or by heating The carbocation thus formed gets stabilised through resonance (Unit 12, Class XI ) as



[PDF] Chemistry Class 12 Chapter 10 NCERT Solution - Mywayteaching

www mywayteaching com Class XII Chapter 10 – Haloalkanes and Haloarenes Chemistry Page 1 of 40 Question 10 1: Name the following halides according 



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[PDF] CBSE NCERT Solutions for Class 12 Chemistry - cloudfrontnet

− CH2 − CH3 (Secondary butyl) Primary suffix = ane Page 3 Class- XII-CBSE- Chemistry Haloalkanes and Haloarenes Practice more on Haloalkanes and 



Chapter 10 Haloalkanes And Haloarenes

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The replacement of hydrogen atom(s) in a

hydrocarbon, aliphatic or aromatic, by halogen atom(s) results in the formation of alkyl halide (haloalkane) and aryl halide (haloarene), respectively. Haloalkanes contain halogen atom(s) attached to the sp

3 hybridised carbon atom of an alkyl group whereas

haloarenes contain halogen atom(s) attached to sp2 hybridised carbon atom(s) of an aryl group. Many halogen containing organic compounds occur in nature and some of these are clinically useful. These classes of compounds find wide applications in industry as well as in day-to-day life. They are used as solvents for relatively non-polar compounds and as starting materials for the synthesis of wide range of organic compounds. Chlorine containing antibiotic, chloramphenicol, produced by soil microorganisms is very effective for the treatment of typhoid fever.

Our body produces iodine containing hormone,

thyroxine, the deficiency of which causes a disease called goiter. Synthetic halogen compounds, viz. chloroquine is used for the treatment of malaria; halothane is used as an anaesthetic during surgery.

Certain fully fluorinated compounds are being

considered as potential blood substitutes in surgery. In this Unit, you will study the important methods of preparation, physical and chemical properties and uses of organohalogen compounds.After studying this Unit, you will be able to

•name haloalkanes and haloarenes

according to the IUPAC system of nomenclature from their given structures;

•describe the reactions involved in

the preparation of haloalkanes and haloarenes and understand various reactions that they undergo;

•correlate the structures of

haloalkanes and haloarenes with various types of reactions;

•use stereochemistry as a tool for

understanding the reaction mechanism;

•appreciate the applications of

organo-metallic compounds; •highlight the environmental effectsof polyhalogen compounds.Objectives10

UnitUnit

UnitUnitUnit10

Haloalkanes andHaloalkanes andHaloalkanes andHaloalkanes andHaloalkanes and

HaloarHaloarHaloarHaloar

Haloar

enesenes enesenes enesHaloalkanes andHaloalkanes andHaloalkanes andHaloalkanes and

Haloalkanes and

HaloarHaloar

HaloarHaloar

Haloar

enesenes enesenes enes Halogenated compounds persist in the environment due to their resistance to breakdown by soil bacteria.2015-16

282ChemistryHaloalkanes and haloarenes may be classified as follows:

These may be classified as mono, di, or polyhalogen (tri-,tetra-, etc.) compounds depending on whether they contain one, two or more halogen atoms in their structures. For example, Monohalocompounds may further be classified according to the hybridisation of the carbon atom to which the halogen is bonded, as discussed below.

This class includes

(a)Alkyl halides or haloalkanes (R - X) In alkyl halides, the halogen atom is bonded to an alkyl group (R).

They form a homologous series represented by C

nH2n+1X. They are further classified as primary, secondary or tertiary according to the nature of carbon to which halogen is attached. (b)Allylic halides These are the compounds in which the halogen atom is bonded to an sp

3-hybridised carbon atom next to carbon-carbon double bond (C=C)

i.e. to an allylic carbon. (c)Benzylic halides These are the compounds in which the halogen atom is bonded to an sp

3-hybridised carbon atom next to an aromatic ring.10.110.1

10.1.1On the

Basis of

Number of

Halogen

Atoms

10.1.2 Compounds

Containing

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