Carbonyl carbon of both aldehyde and ketones is sp2 – hybridised, One of the GENERAL METHODS OF PREPARATION OF ALDEHYDES AND KETONES 1
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The acid-catalyzed preparation of esters from carboxylic acids is known as Fischer esterification – Esters are carboxylic acid derivatives with the carboxylate -OH
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Carbonyl carbon of both aldehyde and ketones is sp2 – hybridised, One of the GENERAL METHODS OF PREPARATION OF ALDEHYDES AND KETONES 1
[PDF] Module 6 Carbonyl Compounds Lecture 14 Aldehydes and Ketones I
Ketones may be prepared by the oxidation of secondary alcohols in the presence of acid dichromate (Scheme 1) The reaction probably proceeds via the rate
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write the structures of the compounds containing functional groups namely carbonyl and carboxyl groups; • describe the important methods of preparation and
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Alcohol synthesis by reduction can be reversed: chromium reagents Alcohols can be oxidized back to aldehydes and ketones using chromium (VI) compounds
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2° alcohol gives a ketone on oxidation by Na2Cr2O7 [O] 2 Thus this method is not useful in preparation of aldehydes and ketones Illustration 2: Aldehyde gives positive test with Benedict solution 2 2 (Blue) (Red ppt ) RCH O 2Cu 3OH
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Aldehydes and ketones are simple compounds which contain a The major methods for preparing aldehydes an ketones are: 2 ✓+ve, gives yellow ppt
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1 Aldehydes , Ketones and carboxylic acids Methyl ethyl etone is prepared by the oxidation of Which compound does not gives yellow ppt with iodine
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Describe the nucleophilic substitution reactions that can be used to prepare alcohols, ethers, thiols, and sulfides 4 Predict the major product of the addition
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The most common method for preparing aldehydes and ketones involves oxidation of alcohols The oxidation of a primary alcohol gives either an aldehyde or a
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