[PDF] [PDF] Aldehyde and Ketone Identification

[PDF] Identification of an Unknown – Alcohols, Aldehydes, and Ketones

2,4-Dinitrophenylhydrazine: Aldehydes and ketones react with 2,4-dinitrophenylhydrazine reagent to form yellow, orange, or reddish-orange precipitates, whereas alcohols do not react Formation of a precipitate therefore indicates the presence of an aldehyde or ketone

[PDF] Lab 14: Qualitative Organic Analysis - California State University

one major functional group (alcohol, ketone, aldehyde, amide, amine, carboxylic C-14 Tests for the presence of esters Ketones 2,4-Dinitrophenylhydrazine

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You should recall how to name aldehydes and ketones: A few drops of the carbonyl compound are put in a test tube with about 5cm3 of Brady's reagent Recall that alcohols can be oxidized to form aldehydes, ketones and carboxylic acids

[PDF] Identification of Aldehydes and Ketones

Aldehydes and ketones differ from alcohols in having two less ketone b) Reduction of Fehling's reagent This test, like Tollen's test, is used to distinguish 

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Both the above reactions are used as tests for unsaturation 24-04-2018 Alcohols are soluble in Lucas reagent but the formed alkyl halides are not soluble These two carbonyl compounds (aldehydes and ketones) are distinguished on the 

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the 'unknown' is dry and neutral before you can confirm it is an alcohol Positive tests for aldehydes (i e to distinguish them from ketones) depend on this fact

[PDF] Properties of Alcohols, Aldehydes and Ketones Introduction

Laboratory 22: Properties of Alcohols, Aldehydes and Ketones Procedure A Solubility Tests - Water 1 Test the solubility of each of the listed substances with  

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23 mar 2016 · Test Functional groups Observations Bromine water Alkene C=C acid Ketone Alkene Halogenoalkane Aldehyde 1o Alcohol 3o Alcohol 

[PDF] Alcohols, Aldehydes, and Ketones - University Science Books

Alcohols, Aldehydes, and Ketones When an aldehyde is present, the Tollen's test produces a silver mirror on the inside of a test tube or flask, as shown here

[PDF] Aldehyde and Ketone Identification

Aldehyde Methyl Ketone Compounds w/ enol content Chromic Acid Iodoform Test occasionally strongly acidic, strongly basic compounds, and some allylic alcohols Chromic Acid Test (Handle with care, dispose of in appropriate waste )

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Aldehyde and Ketone Identification

Series of classification tests

Aldehydes and Ketones

2,4-dinitrophenylhydrazine (we did not do this)

AldehydeMethyl KetoneCompounds w/ enol content

Chromic AcidIodoform TestFerric Chloride Test

Tollens Reagent(we did not do this)

2,4-dinitrophenylhydrazine (Handle with care, dispose of in appropriate waste)

Reacts with ketones and aldehydes. (we did not do this test)

Form precipitate with aldehydes and ketones

Color of precipitate may provide info about compound: •unconjugated = yellow •conjugated = orange to red •occasionally strongly acidic, strongly basic compounds, and some allylic alcohols.

Procedure

•Place 1 drop of unknown in a tube. •Add 1ml of phenylhydrazine solution • Shake vigorously •If unknown is a solid, dissolve 10mg in 95% ethanol •Most aldehydes/ketones give yellow to red precipitate. It may take 15 minutes or gentle heating to achieve color change Chromic Acid Test (Handle with care, dispose of in appropriate waste)

Reacts with aldehydes.

Works because of ready oxidation of aldehydes

R R O O 2 N H NNO 2 H 2 N H R R O 2 N H NNO 2 N H 2 O 2CrO 3 + 2H 2 O2H 2 Cr 2 O 7 + H 2 O H

3RCHO + H

2 Cr 2 O 7 + 3H 2 SO 4

3RCOOH + Cr

2 (SO 4 3 + 4H 2 O orangegreen Primary and secondary alcohols may also be oxidized as well giving false positive. •Dissolve 1 drop or 10mg of unknown in 1ml reagent grade acetone •Add several drops of chromic acid, w/ shaking •Green precipitate and loss of orange color indicates presence of an aldehyde •w/ aliphatic aldehydes - turns cloudy in 5 sec. and forms precipitate w/in 30 sec. •If solution remains orange bur precipitate forms = negative result. Tollens Test (Handle with care, rinse glassware and acidify waste with 5% HCL, dispose of in appropriate waste)

Reacts with aldehydes.

Should only be used if the compound has been determined to either be a ketone or an aldehyde. •Combine 1ml Tollens A and 1ml Tollens B •Add dilute ammonia dropwise to dissolve prcpt. •Divide solution evenly between three test tubes. •Add 1 drop of aldehyde or solid aldehyde in bis(2ethoxyethyl)ether to tollens reagent. •Precipitation of silver (mirror formed) indicates presence of aldehyde (it may be necessary to warm the reaction •Reagents cannot be stored - dispose of them after they are used

Iodoform Test

Methyl ketone

Iodoform is a yellow precipitate

•Use a water bath between 60-70°C •6 drops of unknown or 0.06g in 2ml 1,2 dimethoxyethane •Add 2ml of 10% NaOH •Place in water bath •Add 4ml of iodine-potassium iodide solution (in 1ml portions) •Cork test tube and shake •Heat in water bath ~5min. •Dark color should be discharged •If not, add more 10% NaOH R

CHO + 2Ag(NH

3 2 OH

2Ag + RCO

2 NH 4 +H 2

O + NH

3 RCH 3 O I 2 NaOH RCI 3 O OH RO O + HCI 3 •Once color has disappeared, add water to within 2cm of lip •cork and shake vigorously •Let stand 15 minutes. •Pale yellow precipitate (iodoform) indicates presence of methyl ketone •Other ketones will discharge color, but will not form iodoform precipitate

Ferric Chloride Test

(we did not do this)

Phenols and compounds with high enolate content

Color is the result of enolate complexation with Fe(III) ion •Add several drops of 2.5% aqueous soln of ferric chloride to 1ml of dilute ketone in aqueous solution. •If solid not soluble in water, 20mg dissolved in CHCl3 can be used. •Add 1 drop of pyridine and 3-5 drops of 1% ferric chloride •Formation of color (red, blue, purple, or green) indicates the presence of a compound with high enol content. Colors are short lived.quotesdbs_dbs17.pdfusesText_23