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Gütlich · Bill

Trautwein

ISBN 978-3-540-88427-9

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - Philipp Gütlich

Eckhard Bill

Alfred X. Trautwein

- - - - - - - - - - - - - - - Philipp Gütlich

Eckhard Bill

Alfred X. Trautwein

Spectroscopy and

Transition Metal

Chemistry

Fundamentals and Application

Transition Metal Chemistry

continued to develop. The authors now present a state-of-the art book which consists of is based on a book published in 1978 in the Springer series 'Inorganic Chemistry Concepts' by P. Gütlich, R. Link and A.X. Trautwein. The second part covers useful practical aspects of measurements, and the application of the techniques to many problems of materials cha racterization. The update includes the use of synchroton radiation and many instructive and illustrative examples in fields such as solid state chemistry, biology and physics, materials and the geosciences, as well as industrial applications. Special chapters on magnetic relaxation phenomena (S. Morup) and computation of hyperfine interaction parameters (F. Neese) are also included. An attached CD-ROM with more than 400 full-color PowerPoint images provides self-explanatory examples. After an initial period this supplementary material will be available at extra.springer.com The book concentrates on teaching the technique using theory as much as needed and as little as possible. The reader will learn the fundamentals of the technique and how to apply it to many problems of materials characterization. Transition metal chemistry, studied on C

Coonntteennttss

and Applications" (Philipp Gütlich)

2. Chemistry

3. Biology

4. Geosciences

5. Archeology

6. Industrial application

WIEN2k calculations for extended systems (Peter Blaha) Parameters of Fe-bearing Compounds (Michael Grodzicki and Stefan Lebernegg) Spectroscopy (John G. Stevens, Airat M. Khasanov, Nina F. Hall, and Irina A. Khasanova) V - "Mossbauer Spectroscopy and Transition Metal Chemistry", 1st edition Springer-Verlag, Berlin Heidelberg New York, 1978 P. Gütlich, R. Link, A. Trautwein 3. Appendix to Chapter 5: (Frank Neese and Taras Petrenko) of Nuclear Inelastic Scattering TheoryLinear Response Theory and Mathematical Development

Contents

Part I

Philipp Gütlich

Lecture series

Acknowledgement

Introduction

Experimental Resonance Conditions

Sharpness of resonance

Recoil Effect

Cross-section for Resonant Absorption

Comparison Between Electronic and Nuclear Transitions

Lattice dynamics

Isomer Shift

Electric Quadrupole Splitting

Magnetic Dipole Splitting

Applications:

Transition Metal Compounds

Bioinorganic Compounds

Spin Crossover

Molecular magnetism

Industrial Applications

Phase Transitions

MIMOS on Mars

MIMOS on Earth

Contents

Part II

Contributions from different laboratories

1. Physics

Title of contribution Authors File name

Determination of the size of Fe nano-

grains in Ag

J. Balogh,

D. Kaptás,

L. F. Kiss, I. Vincze,

A. Kovács,

M. Csontos,

G. Mihály Balogh_Fe nano-grains.ppt

Independent magnetic ordering of the Er

and Fe sublattices in ErFe 6 Sn 6

J.M. Cadogan and

D.H. Ryan

Cadogan_Magnetism of

ErFe6Sn6.ppt

Comparing erbium moments derived from

166
neutron diffraction

D.H. Ryan,

J.M. Cadogan

Cadogan_166Er MS of Er3Ge4.ppt

The first-order magnetostructural

transition in Gd 5 Sn 4

D.H. Ryan

Cadogan_119Sn MS in Gd5Sn4.ppt

Quantitative analysis of iron ore

processing J.M. Cadogan

Cadogan_Iron ore processing.ppt

169

Cadogan_169Tm MS of Tm

alloys.ppt

Yb valence in YbMn

2 (Si,Ge) 2

J.M. Cadogan,

D.H. Ryan

Cadogan_170Yb MS of

YbMn2(SiGe)2.ppt

Spectroscopy (ILEEMS):

a useful variant for true surface studies E. De Grave,

R. E. Vandenberghe

DeGrave_ILEEMS.ppt

-Phase in Fe-Cr and Fe-V Systems

S. M. Dubiel

Dubiel _sigma Phase in Fe-Cr and

Fe-V.ppt

Harmonically modulated structures

S. M. Dubiel

Dubiel_Harmonically modulated

structures.ppt

Ferric fluorides: crystalline, amorphous

and nanostructured states

J. M. Greneche

Greneche_Ferric Fluorides.ppt

properties of nanocrystalline FeNiZrB and

FeNiCoZrB alloys

M. Kopcewicz,

T. Kulik

Kopcewicz_Rf MS in FeNiZrB and

FeNiCoZrB alloys.ppt

Crystallization of amorphous alloys

induced by the rf magnetic field

M. Kopcewicz Kopcewicz_Amorphous alloys.ppt

Nanocrystalline alloys:

I. Hyperfine Interactions M. Miglierini et al.

Miglierini_Nanocrystalline

alloys.part1.ppt

Nanocrystalline alloys:

II. Hyperfine Interactions M. Miglierini et al.

Miglierini_Nanocrystalline

alloys.part2.ppt

Imaging the Magnetic Spin Structure of

Roehlsberger_Spin Structure in Thin

Films .ppt

T.Shinjo Shinjo_Multilayers.ppt

Ditellurides of 3d transition metals

studied by 57

Fe and

125
spectroscopy

P. Fornal, J. Stanek

Stanek_57Fe and 125Te of

ditellurides.ppt

Relativistic Effects in Gold

Chemistry. Part 1

J. Stanek

Stanek_Relativistic Effects in

Au.part1.ppt

Relativistic Effects in Gold

Chemistry. Part 2

J. Stanek

Stanek_Relativistic Effects in

Au.part2.ppt

Nanosized magnetic clusters and their

relation to magnetoresistance in FeCr 2 S 4 spinel

Z. Klencsár,

E. Kuzmann,

Z. Homonnay,

A. Vértes,

A. Simopoulos,

E. Devlin, G. Kallias Klencsar_Magnetoresistance in

FeCr2S4 spinel.ppt

Contents

2. Chemistry

field to explore the low temperature spin structure in a molecular layered ferrimagnet A. Bhattacharjee,

P. Gütlich et al.

Bhattacharjee_Layered

Ferrimagnet.ppt

Metal-to-metal electron transfer and

magnetic interactions in a mixed-valence

Prussian blue analogue

A. Bhattacharjee,

P. Gütlich et al.

Bhattacharjee_Prussian Blue

Analogue.ppt

Fe(II) High Spin ļ Low Spin Transition in

[FeII(isoxazole) 6 ](X) 2 , X = BF 4 , ClO 4

A. Bhattacharjee,

P. Gütlich et al.

Bhattacharjee_Spin crossover.ppt

Thermal and light-induced spin transition

in iron compounds P. Gütlich et al. Guetlich_Spin crossover.ppt oxygen with solid ȕ-Fe II phthalocyanine E. Kuzmann,

Z. Homonnay,

A. Vértes,

S. Li, H. Yin,

Y. Wei,

A. Nath, X. Chen,

J. Li

Kuzmann_Fe_phthalocyanine.ppt

157 T internal magnetic field in

Fe[C(SiMe

3 3 2 compound at 20K

E. Kuzmann,

R. Szalay,

A. Vértes,

Z. Homonnay,

I. Pápai, P. de

Châtel, L. Szepes

Kuzmann_Field in

Fe[C(SiMe3)3]2.ppt

Nuclear inelastic scattering on spin

crossover complexes

H. Paulsen and

A.X. Trautwein

Luebeck_NIS_Spin crossover.ppt

Pressure-induced changes of the

vibrational modes of spin-crossover complexes studied by nuclear resonance scattering of synchrotron radiation

A.X. Trautwein,

H. Paulsen,

H. Winkler

H. Giefers,

G. Wortmann

H. Toftlund

J.A. Wolny

A.I. Chumakov,

O. Leupold

Luebeck_NIS_Spin

crossover_Pressure.ppt

Photoswitching of nitroprussides V. Rusanov,

Sv. Stankov,

H. Paulsen,

A. X. Trautwein

Luebeck_Nitroprussides.ppt

Trinuclear mixed-valent oxo-centered iron

complexes: fully localised, partially and fully delocalised valencies

R.W. Saalfrank,

A. Scheurer,

V. Schünemann,

A.X. Trautwein

Luebeck_Trinuclear mixed

valent.ppt

Unconventional valence transition in

biferrocenium charge-transfer complexes

T. Mochida

Mochida_Biferrocenium.ppt

Exotic dimers part one: the case of the

vanishing hyperfine field

W. M. Reiff,

J.S. Miller,

J. H. Zhang and

D. O'Hare

Reiff_Donor Acceptor.ppt

Exotic dimers part two: a high-spin

ferrous dimer that exhibits genuine spontaneous long range 3-magnetic order in zero field and metamagnetism

W. M. Reiff,

M. Feist, and

E. Kemnitz

Reiff_HS Ferrous Dimer.ppt

Direct spectroscopic evidence of orbital

magnetism of essentially free ion magnitude in a rigorously linear two- coordinate high-spin Fe (II) compound

W. M. Reiff,

A. M. LaPointe, and

C. E. Schulz Reiff_Largest magnetic field.ppt

spectroscopy investigations of magnetic frustration in certain classic Werner complexes above and below 1K

W. M. Reiff,

L. Tákács,

M. J. Kwiecien

Reiff_Magnetic frustration.ppt

Reversible, reductive, topotactic metal ion

insertion chemistry of ferric networks à

La Chimie Douce

W. M. Reiff,

L. Tákács,

J. Tákács,

K. Lázár,

C. C. Torardi Reiff_Metal Ion Insertion.ppt

Spin states of highly deformed iron(III)

porphyrin complexes studied by 57
Fe

M. Nakamura,

M. Takahashi

Takahashi_Porphyrins.ppt

Electronic phase separation in cobaltate

perovskites

Z. Németh,

Z. Klencsár,

Z. Homonnay,

E. Kuzmann,

A. Vértes

Vertes_Cobaltate perovskites.ppt

of the structure of an iron(III) complex with indole-3-acetic acid in acidic aqueous solutions

K. Kovács,

A. A. Kamnev,

E. Kuzmann,

A. Vértes

Vertes_Indole complexes.ppt

Contents

3. Biology

Title of contribution Authors File name

Time-dependent analysis of magnetite

nanoparticles in magnetospirillum

D. Faivre,

D. Schüler,

B. F. Matzanke

Luebeck_Nanoparticles in

Magnetospirillum.ppt

Siderophore reductase FhuF - a case

study

B. F. Matzanke Matzanke_Siderophore

Reductase.ppt

iron metabolization

B. F. Matzanke,

M. Brandenburger,

Matzanke_Microbial Iron

Metabolization.ppt

spectroscopy in energy and time

K. Achterhold,

F.G. Parak

Parak_Dynamics of proteins.ppt

Intermediates in the reaction cycle of

cytochrome P450cam

V. Schünemann,

C. Jung,

A.X. Trautwein

Schuenemann_Cytochrome

P450.ppt

iron uptake strategies in plants

K. Kovács,

E. Kuzmann,

F. Fodor , A. Vértes

Kovacs_Iron Uptake in Plants.ppt

Contents

4. Geoscience

Title of contribution Authors File name

Green rusts and the corrosion of iron

based materials J.-M. R. Génin et al.quotesdbs_dbs14.pdfusesText_20