[PDF] [PDF] Short Summary of IUPAC Nomenclature of Organic Compounds

[PDF] Short Summary of IUPAC Nomenclature of Organic Compounds

IUPAC nomenclature is based on naming a molecule's longest chain of carbons atoms other than carbon and hydrogen, are indicated by prefixes or suffixes according to a specific set of priorities II of steps, as indicated on the examples below: of chain) (Notes: 1 An “e” is dropped if the letter following it is a vowel:  

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various functional classes organic compounds, as well as the relationship between compounds that have The next page contains examples of compounds containing the thirteen common compounds for the same formula C6H11BrO

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IUPAC system of nomenclature and also derive their structures from the given ( ii) Various ways of representing 2-bromo examples of various types of aromatic Table 12 4 Some Functional Groups and Classes of Organic Compounds 

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(ii) Naming Various Classes of Organic Compounds 14 A Ethers and The following example gives the name of an alkane having a branched side chain:

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11 Nomenclature of Spiro compounds 42 12 Exercise - 1 46 Exercise - 2 53 Exercise - 3 58 Mainly three systems are adopted for naming an organic compound : – (i) Common Names or Acrylic anhydride SOLVED EXAMPLE Q 1

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h d h i ffi hil attached to the primary suffix while writing the IUPAC name Page 12 Class of functional secondary compounds group suffix

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Sequence of citation of symbols, 11 Functional class nomenclature, 96 5 Examples 9 C(CH3) 10 CH3-[CH2]5-CH3 11 CaCl 12 [{Fe(CO)3}3(CO)2]2

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What is IUPAC nomenclature? • A systematic method of naming organic chemical compounds as recommended by the International Union of Pure and Applied 

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Examples: polychlorinated biphenyls, caffeine, steroids, organic solvents ( toluene, xylene) C11-5- Include: up to 6-C alcohols and 6-C organic acids, IUPAC nomenclature C11-5- GRADE 11 CHEMISTRY • Topic 5: Organic Chemistry Microscale Chemistry Laboratory Manual (Slater and Rayner- Canham 82—ester

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In this chapter, we consolidate the nomenclature of a number of classes Examples are given below CW:,-CH2 CH3 I I 4-ethyl-3-methyl heptane

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Short Summary of IUPAC Nomenclature of Organic Compounds

IntroductionThe purpose of the IUPAC system of nomenclature is to establish an international standard ofnaming compounds to facilitate communication. The goal of the system is to give each structurea unique and unambiguous name, and to correlate each name with a unique and unambiguousstructure.

I. Fundamental Principle IUPAC nomenclature is based on naming a molecule's longest chain of carbons connected bysingle bonds, whether in a continuous chain or in a ring. All deviations, either multiple bonds oratoms other than carbon and hydrogen, are indicated by prefixes or suffixes according to aspecific set of priorities.

II. Alkanes and CycloalkanesAlkanes are the family of saturated hydrocarbons, that is, molecules containing carbon andhydrogen connected by single bonds only. These molecules can be in continuous chains (calledlinear or acyclic), or in rings (called cyclic or alicyclic). The names of alkanes and cycloalkanesare the root names of organic compounds. Beginning with the five-carbon alkane, the number ofcarbons in the chain is indicated by the Greek or Latin prefix. Rings are designated by the prefix"cyclo". (In the geometrical symbols for rings, each apex represents a carbon with the number ofhydrogens required to fill its valence.)

4methaneCH3[CH2]10CH3dodecaneCH

3CH3ethaneCH3[CH2]11CH3tridecaneCH

3CH2CH3propaneCH3[CH2]12CH3tetradecaneCH

3[CH2]2CH3butaneCH3[CH2]18CH3icosaneCH

3[CH2]3CH3 pentaneCH3[CH2]19CH3henicosaneCH

3[CH2]4CH3hexaneCH3[CH2]20CH3docosaneCH

CHH HHH

Short Summary of IUPAC Nomenclature, p. 2

III. Nomenclature of Molecules Containing Substituents and Functional Groups

A. Priorities of Substituents and Functional GroupsLISTED HERE FROM HIGHEST TO LOWEST PRIORITY, except that the substituents withinGroup C have equivalent priority.

Family of Compound

Alkene

AlkyneStructurePrefix

----Suffix -ene -yneSuffix -oic acid (-carboxylic acid) -al(carbaldehyde) -one -ol -aminePrefix carboxy- oxo- (formyl) oxo- hydroxy- amino-StructureFamily of Compound

Carboxylic Acid

Aldehyde

Ketone

Alcohol

AmineRCO

CHO RCO CCGroup A - Functional Groups Indicated By Prefix Or Suffix Group B - Functional Groups Indicated By Suffix Only Group C - Substituents Indicated by Prefix Only Substituent Structure Prefix Suffix

Alkyl (see list below)R - alkyl-------AlkoxyR - O - alkoxy-------HalogenF - fluoro---------Cl - chloro---------Br - bromo---------I - iodo---------Group C continued on next page

Short Summary of IUPAC Nomenclature, p. 3

Group C - Substituents, continued

Miscellaneous substituents and their prefixes 2CHCH 2CHCH 2CH

2nitrovinylallylphenyl

Common alkyl groups - replace "ane" ending of alkane name with "yl". Alternate names forcomplex substituents are given in brackets.

methyl ethyl propyl (n-propyl)butyl (n-butyl)isopropyl [1-methylethyl]isobutyl [2-methylpropyl]sec-butyl[1-methylpropyl]tert-butyl or t-butyl[1,1-dimethylethyl]CH 3CH

2CH3CH

2CH2CH3CH

2CH2CH2CH3CH

3CH 3CHCH 3CH 3CH 2CH

2CH3CH

3CCH 3CH 3CH

3B. Naming Substituted Alkanes and Cycloalkanes - Group C Substituents Only

1. Organic compounds containing substituents from Group C are named following this sequenceof steps, as indicated on the examples below:•Step 1. Find the longest continuous carbon chain. Determine the root name for thisparent chain. In cyclic compounds, the ring is usually considered the parent chain, unless it isattached to a longer chain of carbons; indicate a ring with the prefix "cyclo" before the rootname. (When there are two longest chains of equal length, use the chain with the greater numberof substituents.)•Step 2. Number the chain in the direction such that the position number of the firstsubstituent is the smaller number. If the first substituents from either end have the same number,then number so that the second substituent has the smaller number, etc.•Step 3. Determine the name and position number of each substituent. (A substituent ona nitrogen is designated with an "N" instead of a number; see Section III.D.1. below.)•Step 4. Indicate the number of identical groups by the prefixes di, tri, tetra, etc.•Step 5. Place the position numbers and names of the substituent groups, in alphabeticalorder, before the root name. In alphabetizing, ignore prefixes like sec-, tert-, di, tri, etc., butinclude iso and cyclo. Always include a position number for each substituent, regardless ofredundancies.

Short Summary of IUPAC Nomenclature, p. 4

Examples

1-sec-butyl-3-nitrocyclohexane(numbering determined by the alphabetical order of substituents)3-fluoro-4-isopropyl-2-methylheptane3-bromo-2-chloro-5-ethyl-4,4-dimethyloctane766

2187
4321
CHCH 2CH3H 3CNO

2CHCHCH

3CHCH

2CH2CH3CH

3CH

3CHCHC

BrCH 3CHCH

2CH2CH3CH

3CH 3ClCH

2CH3CH

C. Naming Molecules Containing Functional Groups from Group B - Suffix Only

1. Alkenes - Follow the same steps as for alkanes, except:

a. Number the chain of carbons that includes the C=C so that the C =C has the lowerposition number, since it has a higher priority than any substituents;

b. Change "ane" to "ene" and assign a position number to the first carbon of the C =C;c. Designate geometrical isomers with a cis,trans or E,Z prefix. 1

2345
buta-1,3-diene5-methylcyclopenta-

1,3-dieneCHCH

2CHCHF

FCH CHCH 2CH

3Special case: When the chain cannot include the C=C, a substituent name is used. 3-vinylcyclohex-1-eneCHCH

22. Alkynes - Follow the same steps as for alkanes, except:

a. Number the chain of carbons that includes the CtC so that the functional group has thelower position number;

b. Change "ane" to "yne" and assign a position number to the first carbon of the CtC.Note: The Group B functional groups (alkene and alkyne) are considered to have equal priority:in a molecule with both a double and a triple bond, whichever is closer to the end of the chaindetermines the direction of numbering. In the case where each would have the same positionnumber, the double bond takes the lower number. In the name, "ene" comes before "yne"because of alphabetization. See examples on next page.

Short Summary of IUPAC Nomenclature, p. 5

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