[PDF] Copper(I)-mediated anti-SN2 Allylic Substitution Reactions with PDF Perrone

Anti-SN2´ substitutions with organocopper reagents on allylic substrates The simultaneous control of the regio- and stereochemistry is a difficult problem to

The most common nucleophiles used in copper-catalyzed allylic substitutions are diorganoz- inc reagents, Grignard reagents, organolithium reagents, and

[PDF] Organometallic Chemistry

Organocopper Reagents (Gilman Reagent) organocopper reagents react with alkyl-, alkenyl-, and aryl Substitution with complete allylic rearrangement (S

[PDF] Asymmetric Synthesis and Mechanistic Studies on Copper(I) - DiVA

copper(I)-Catalyzed Allylic Substitution with Grignard Reagents Cotton prate, is more reactive than organocopper in the reactions described in Scheme 1

[PDF] Stoichiometric versus catalytic action of organocopper compounds

3 juil 2018 · organocopper reagents, substitution/conjugate addition reaction, photoinduced Scheme 13 Allylic substitution with organocopper reagents

[PDF] Synthesis of New Functionalized Organocopper Reagents via a

numerous successive synthesis steps need to be carried out selectively 37 Allylic substitution reactions of organocopper reagents allow a highly selective