[PDF] Example – Peroxide Forming Chemicals



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PEROXIDES AND PEROXIDE FORMING COMPOUNDS

Peroxides, in contact with inorganic obalt and copper compounds, iron or iron compounds, acetone, metalc oxide salt, and acids or bases can react with rapid, uncontrolled decomposition of peroxides leading to fires and explosions (3) Peroxides may form on the surface of finely divided alkali metals and their amides and readily form



Example – Peroxide Forming Chemicals

The peroxides formed in these reactions are extremely shock and heat sensitive The liquid chemicals in this group should be tested for peroxides and discarded within 6 months of opening Acrylic acid Chlorotrifluoroethylene Vinyl acetate Acrylonitrile Methyl methacrylate Vinylacetylene (gas)



Chemicals That Form Peroxides: Handling and Storage

Chemicals That Form Peroxides: Handling and Storage Peroxy compounds are examples of chemicals which present special problems In the laboratory because they can be violently reactive or explosive Their handling deserves careful attention Inorganic Peroxides Inorganic peroxy compounds are generally stable as such, but in contact with



List of Organic peroxides

List of Organic peroxides Purity (Theoretical AOC) Package Volume Storage Temp Half-life(℃) ( ) Act'O( ) of Content (℃) 1min 1Hr 10Hr Chemical Name Physical Form UN Number Cas No Trade Name 1,1,3,3-tetramethylbutyl peroxy 2-ethylhexanoate (5 87) CHEMEX TMPO Liquid(Hydrocarbon solution) 70 4 11 10 ㎏ (10×1) Below -15 3115 22288-43-3



Peroxide-Forming Chemicals (PFCs)

isopropyl alcohol, can also form peroxides if best practices are not followed Identifying Peroxide Formers According to Prudent Practices (Chapter 4 D 3 2 Azos, Peroxides, and Peroxidizables), any organic compound with a weak C–H bond is at risk for forming peroxides depending on the conditions or contaminants the chemical is exposed to



ORGANIC PEROXIDES CHEMICAL HAZARDS & RISK MINIMIZATION

the solution Do not store organic peroxides which are diluted with water at temperatures below 0°C (32°F) to avoid separating out the pure organic peroxide Organic peroxides can also be strong oxidizing agents Combustible materials contaminated with most organic peroxides can catch firevery easily , even spontaneously, and burn very intensely



Safety of organic peroxides - Nouryon

put peroxides in closed metal contain-ers or glass bottles without having installed appropriate venting devices Contamination Contamination constitutes a hazard, because many chemicals seriously reduce the decomposition temperature (SADT) of organic peroxides Notorious examples are metal salts, amines, acids, bases and construction materials such



Peroxide Formers and Other Potential Explosives SOP

Peroxides are also often shock sensitive compounds that can explode if subjected to mechanical shock, intense light, rapid changes in temperature, heat, friction, or in some cases, by spontaneous reaction Chemicals that can potentially form peroxides (peroxidizables) are categorized into three classes (A-C) defined below

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