[PDF] POTENTIOMETRIC TITRATION OF SULPHATE, SULPHITE AND DITHIONATE



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the sulfite ion, SO - DePauw University

the sulfite ion, SO 3 2–, one that minimizes formal charges and one that satisfies the octet rule Anno-tate both structures by specifying the formal charge on each element, by circling any element that does not satisfy the octet rule, and by reporting the bond order between sulfur and oxygen



Free-Radical Chemistry of Sulfite

Sulfite cleaves DNAin the presence of 02 and Mn2+ (30), this reaction is inhibited byhydroquin-one The autoxidation of sulfite can destroy indole-3-acetic acid (31) or tryptophan (32) and several nucleo-tides and nucleic acids have been shownto react with sulfite in the presence ofoxygen(33) Lipid peroxidation has been induced by sulfite (34)



POTENTIOMETRIC TITRATION OF SULPHATE, SULPHITE AND DITHIONATE

ion-selective electrode ’ They used 50 aqueous dioxan medium to suppress the solubility of lead sulphate The detection limit is 5 x 10m5M sulphate Major interference is caused by cations which give an electrode response (Cu’+, Hg’+, Ag+), anions which form insoluble lead salts (PO:-) and high concen-



Elements whose names and symbols you should memorize (you do

2-sulfite PO 3 3-phosphite Remove O (charge SAME) Also learn the other common monatomic “–ides” as well (use periodic table to determine charge for all monatomic –ides): oxide (O2-) , the first four halides (F-, Cl-, Br-, I-), and hydride (H-) “Core Ions”* HSO 3-hydrogen sulfite HPO 3 2-hydrogen phosphite H 2PO 3-dihydrogen



Improved Analysis of Sulfur-Containing Anions from

• It can also react with sulfite to form thiosulfate S n 2– + SO 3 – 2→ (n-1) S 2 O 3 – + S2– Table 2 lists the possible inorganic sulfur-containing anions present in lime sulfur-based aqueous streams or solutions Table 2 Possible Inorganic Sulfur Anions Anion Formula Sulfide S2– Sulfite SO 3 2 – Sulfate SO 4 2 – Polysulfide



Worksheet &# 9 Ion Concentration

Worksheet # 9 Ion Concentration 1 What is the concentration of each ion in a 10 5 M sodium sulfite solution? 2 What is the concentration of each ion in a 5 55 M zinc phosphate solution? 3 What is the concentration of each ion in the solution formed when 94 78 g of iron (III) sulfate is dissolved into 550 0 mL of water? 4



Sulfur Dioxide & Wine Additives

The different forms of sulfite exist in equilibrium in wine in the same manner as tartaric acid H 2 O + SO 2 ↔H+ + HSO 3-↔2H+ + SO 3 = water + molecular sulfur dioxide hydrogen ion + bisulfite hydrogen ion + sulfite 11 Sulfites Like tartaric acid the forms that are present are dependent on pH 12



Basic Disinfection Study Guide - Wisconsin DNR

The dosage rate of sodium bisulfite (NaSO2) to chlorine residual is 1 mg/L active sulfite ion to 1 mg/L of chlorine residual The lower the chlorine residual, the less sodium bisulfite is needed for dechlorination 1 3 4 1 3 5 Describe conditions affecting chlorine demand Basic Disinfection Study Guide - Subclass D



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