1 the 'root' name, indicative of the number of carbon atoms in the Identify the "parent" chain by counting the longest number of carbon atoms which are
The number of chlorine atoms in the compound can be found by subtracting the number of non-carbon atoms (hydrogen + fluorine) from 2n + 2, where n = the number
Aliphatic hydrocarbons can be divided into three types, based on the number of bonds between neighbouring carbon atoms These different types
IUPAC nomenclature is based on naming a molecule's longest chain of carbons connected by single bonds, whether in a continuous chain or in a ring All
a carbon atom with 6 protons, 6 neutrons and 6 electrons An element is a substance made up of atoms with the same number of protons Elements are the
The value of the mole is equal to the number of atoms in exactly 12 grams of pure carbon-12 • 12 00 g C-12 = 1 mol C-12 atoms = 6 022 × 1023 atoms
When a carbon atom has four single bonds, the Each Carbon Atom in an Alkane Forms a Number the carbon atoms in the principal chain starting from
The situation become slightly more complicated when the number of carbon atoms is increased to 5 There are 3 different structural isomers having the
functional group: an atom, or group of atoms (with specific connectivity), contain an oxygen atom bonded to two carbon atom groups by single bonds
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137680_7How_to_name_hydrocarbons.pdf
ast0271 | Hydrocarbon chemistry 3: How to name hydrocarbons (fact sheet) developed for the Department of Education WA
© The University of Western Australia 2011 for conditions of use see spice.wa.edu.au/usage version 1.2 revised February 2015 page 1 Licensed for NEALS fi
Hydrocarbons are compounds that contain only
carbon and hydrogen. Carbon atoms have four valence electrons, allowing them to bond in many different ways. A carbon atom can bond to two, three or four other atoms, which means that hydrocarbons can form a wide variety of structures. Aliphatic hydrocarbons form straight chains, alicyclic hydrocarbons form rings of carbon atoms and aromatic hydrocarbons contain a special structure called a benzene ring (C 6 H 6).
Aliphatic hydrocarbons can be divided into three
types, based on the number of bonds between neighbouring carbon atoms. These different types have different properties due to their bonding. • Alkanes have only single bonds between carbon atoms. • Alkenes contain at least one double bond between a pair of carbon atoms. • Alkynes have at least one triple bond between carbon atoms. There are so many different hydrocarbon molecules possible that a special naming system called IUPAC (International Union of Pure and Applied Chemistry) is used to identify them. This naming system has specific rules so that each molecule has a unique name.
1. The first part of the name is based on the length of the longest carbon chain in the molecule.2. The end of the name is given by the number of bonds between carbon atoms. If there are only single bonds the name ends with '-ane', if there is at least one double bond (and no triple bonds) the name ends in '-ene', and if there is at least one triple bond the name ends in '-yne'.
3. Functional groups (branches coming off the longest carbon chain) are named according to their length and how many there are.
4. Functional groups are numbered to show where they are attached to the main chain. Carbon atoms in the main chain are numbered from the end closest to the functional groups (or the end closest to a multiple bond if there is one).Number of
carbon atomsPrefix for main chainFunctional group
1meth-methyl
2eth-ethyl
3prop-propyl
4but-butyl
5pent-pentyl
6hex-hexyl
7hept-heptyl
8oct-octyl
9non-nonyl
10dec-decylHydrocarbon
classhighest order bondSuffix / prefix alkane CC -ane alkene CC -ene alkyne
CC-yne
cycloalkane CC cyclo ... ane cycloalkene CC cyclo ... ene cycloalkyne CC cyclo ... yne
REPEATING UNITSPREFIX
1 2di- 3tri-
4tetra-
Where there's more than one double or triple bond in a molecule it's conventional to add an 'a' to the prefix. For example, but-1-ene and buta-1,2-diene.How to name hydrocarbons This molecule has only single bonds, so it is an alkane and its name ends in -ane. The longest chain has three carbons, so the prefix is prop-. The molecule has two (di-) single carbon (methyl-) branches, so it is a dimethylpropane. Both branches come off the second carbon atom in the chain, so it starts
2,2-dimethyl-.
The full name is
2,2-dimethylpropane.
CH 3 C CH 3 CH 3 CH 3
ast0271 | Hydrocarbon chemistry 3: How to name hydrocarbons (fact sheet) developed for the Department of Education WA
© The University of Western Australia 2011 for conditions of use see spice.wa.edu.au/usage version 1.2 revised February 2015 page 2
Examples
C CH 3 H H C C C C C C H H H C 2 H 5 H H H H H CH 3 H H H Although this looks at first glance to be a heptane, the methyl group at the left of the chain can be viewed as part of the backbone. • The longest chain has eight carbon atoms, so it is an octane. • The molecule has two branches, one with a single carbon (methyl-) and one with two carbons (ethyl-). • Both branches are attached to the fourth carbon atom. • Full name is 4-ethyl-4-methyloctane. C H H H C C C CH 3 H H CH 3 H • This molecule has a double bond, so it is an alkene with a name ending in -ene. • The double bond is between the first and second carbon atoms, so it is a but-1-ene. • Full name is 3,3-dimethylbut-1-ene. CH 3 C C CH 3 • This molecule is but-2-yne. C C C Cl CH 3 H H H H H When a halogen (group 7 or 17 element) is substituted into a hydrocarbon, the halogen is treated as a functional group (prefixes are fluoro-, chloro-, bromo- and iodo-). • This molecule is 1-chlorobut-1-ene. C C C H Br H H H CH 3 C H H C H H
• If the chain is numbered from the left this molecule would be called 1-bromo-4-methylpent-3-ene.
• If the chain is numbered from the right it would be 5-bromo-2-methylpent-2-ene.
• The chain is numbered in the direction that gives any multiple bonds the lowest possible number, so the correct
name is
5-bromo-2-methylpent-2-ene.