[PDF] [PDF] Sem V OCIII MCQspdf a) Pyridine b) Quinoline c)





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[PDF] Preparation and Properties of Quinoline

(1) By Skraup Synthesis: (Commercial method) In this reaction a mixture of aniline and glycerol is heated in the presence of sulphuric acid and a mild 

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SAÓPLN QUNSTIONS

Q. 1 Select correct IUPAC name of the following structure N N CH3Br Q.2 SelecW WUe correcW VWrucWure from given IUPAC name-

7-HyTroxymeWUyl-4-meWUoxy iVoquinoline

a) N OCH3 HOH2C b) N OCH3 HOH2C c) N OCH3 HOH2C T) N OCH3 HOH2C

Q.3 ITenWify WUe VWrucWure of pyraYine

a) N b) NH HN c) N N T) N N

Q.4 Which compound is not heteroaromatic?

a) Furan b) Indole c) Quinoline

T) Piperidine

Q.5 Paal-Ą‘"" •›-Š‡•‹• ‘ˆ -Š‹‘"Š‡‡ ‹˜‘Ž˜‡•ǥ

a) Reaction of 1,4-Ticarbonyl compounT anT pUoVpUoruV penWacUloriTe b) Reaction of 1,4- Tiamino compounT anT pUoVpUoruV penWaVulfiTe c) Reaction of 1,4- Ticarbonyl compounT anT pUoVpUoruV penWaVulfiTe T) Reaction of 1,5- Ticarbonyl compounT anT pUoVpUoruV penWaVulfiTe Q.6 In Pyrrole elecWropUilic aromaWic VubVWiWuWion reacWion WakeV place aW wUicU poViWion? a) First b) Second c) Third

T) Does not occur

Q.7 PUicU iV more baVic among PyrroleH WUiopUene anT Ńuran? a) Furan b) Pyrrole c) Thiophene

T) All are equally basic

a) Pyridine b) Quinoline c) Imidazole

T) Pyrimidine

Q.10 NiWraWion of imiTaYole giveV..

a) 4-NiWroimiTaYole b) 3-NiWroimiTaYole c) 1-NiWroimiTaYole

T) 2-NiWroimiTaYole

Q. 11 The octapeptide angiotensin II has the sequence AVp-Arg-Val-Tyr-Ile-HiV-Pro-PUe. PUaW fragmenWV woulT reVulW if angioWenVin II were cleaveT wiWU WrypVin a) AVp-Arg-Val anT Tyr-Ile-HiV-Pro-PUe b) AVp anT Arg-Val-Tyr-Ile-HiV-Pro-PUe c) AVp-Arg anT Val-Tyr-Ile-HiV-Pro-PUe

T) AVp-Arg-Val-Tyr-Ile-HiV anT Pro-PUe

Q. 12 TUe pKa values for Aspartic acid are pKa1 1.9, pKa2 9.6 and pKa3 3.6. What will be the iVoelecWric poinW? a) 4.7 b) 3.7 c) 2.7

T) 1.7

Q. 13 Ńollowing are WUe amino proWecWing groupV excepW a) ter-buWoxycarbonyl b) benYyloxycarbonyl c) flurenylmeWUylcarbonyl

T) benYyl eVWerV

Q.14 TUe monomeric uniWV from wUicU Saran iV maTe are a) Vinyl cUloriTe VinyliTene cUloriTe c) IVobuWylene IVoprene Q. 15 Ńollowing VWrucWure belongV Wo wUicU polymer? CH3 CH3 OO O a) PolyVWyrene b) PolycarbonaWe c) Nylon-66

T) Saran

Q. 16 RieglerȂNatta caWalyVWV allowV preparaWion of a) Polypropylene b) NiWrile rubber d) PolyureWUane

Q. 17 ÓorpUoline iV VynWUeViYeT fromH

a) biV-(2-eWUylamino )eWUerV b) biV-(1-aminomeWUyl )eWUerV c) biV-(2-aminoeWUyl )eWUerV

T) biV-(3-aminopropyl)eWUerV

Q. 18 CUemical name of -

iV a) ͳ͹Ⱦ-HyTroxyanTroVW-4-en-3-one b) NVWra-ͳ͹Ⱦ-HyTroxy-4-en-3-one c) ͳ͹Ƚ-HyTroxyanTroVW-4-en-3-one

T) ͳ͹Ⱦ-HyTroxyanTroVW-3-en-4-one

Q.19 Pregnenolone iV converWeT inWo ͳ͹Ƚ-HyTroxypregnenolone by wUicU of WUe following enYyme? a) 21-UyTroxylaVe b) ͳ͹Ƚ-UyTroxylaVe c) ͳ͹Ƚ-lyaVe

T) ͳͳȾ-UyTroxylaVe

Q. 20 ConfiguraWion of following VWeroiT iV

HH CH3 CH3 O OH CH3H HH CH3 H R H a) WranV-WranV-WranV b) WranV-ciV-WranV c) ciV-WranV-WranV

T) WranV-WranV-ciV

Q. 21 PUicU of WUe following baVeV ToeVnoW neeT proWecWion Turing MNA VynWUeViV? a) ATenine b) CyWoVine c) Gyanine

T) TUymine

Q.22 In wUicU meWUoT of VynWUeViV of quinolineH aniline iV WreaWeT wiWU VulpUuric aciTH glycerol anT oxiTiYing agenW? a) Doebner-Óiller VynWUeViV b) Skraup synthesis c) Conrad-LimpacU VynWUeViV

T) Friedlander synthesis

Q.23 In iVoquinoline aW wUaW poViWion nucleopUilic VubVWiWuWion reacWion WakeV place? a) Fourth position b) Second position c) First position

T) Third position

Q.24 Ńollowing are WUe enTogenouV VWeroiTal UormoneV excepW a) Estradiol b) Progesterone c) Cholesterol

T) (20R)-5Ƚ-Pregnane-3Ⱦ,20-Tiol

Q.25 TUe reagenW 1-fluoro-2H4-TiniWro benYene wUicU iV uVeT Wo TeWermine N- Werminal amino aciT reViTue in pepWiTeV iV in- a) Edman method b) Sanger method c) Coupling method

T) Hydrolysis method

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