[PDF] Practice Tests Answer Keys Organic Chemistry I





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Practice Tests Answer Keys Organic Chemistry I

Online Organic Chemistry I Chem 350



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f. 15. Answers Test 1 Version 3. 1. Resonance: No atoms can move!



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Practice Tests Answer Keys Organic Chemistry 2

Online Organic Chemistry 2 Chem 360



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Practice Tests Answer Keys, Organic Chemistry I

Online Organic Chemistry I, Chem 350, Dr. Craig P. Jasperse, Minnesota State University Moorhead

For full class website, see

Test Page

Test 1 Version 1 3

Test 1 Version 2 9

Test 1 Version 3 15

Test 1 Version 4 21

Test 2 Version 1 27

Test 2 Version 2 33

Test 2 Version 3 39

Test 2 Version 4 43

Test 3 Version 1 49

Test 3 Version 2 55

Test 3 Version 3 61

Test 3 Version 4 67

Test 4 Version 1 73

Test 4 Version 2 79

Test 4 Version 3 85

Final Exam Version 1 93

Final Exam Version 2 101

1 2

1 1 JASPERSE CHEM 350 TEST 1 VERSION 1 Organic Chemistry I - Jasperse Intro and Review Structure and Properties of Organic Molecules Structure, Nomenclature, and Conformation/Stereochemistry of Alkanes 1. Draw the correct Lewis structure of CH3CN. (Needn't show 3-D geometry) (3pt) 2. Draw the correct Lewis structure for HOCH2CHO. (Needn't show 3-D geometry). (3pt) 3. Draw a 3-dimensional picture for the atoms in CH3CO2CH2NHCH3, using the hash-wedge convention. (You needn't specify lone pairs, and orbitals need not be shown). (5pt) 4. For the structure shown, what is the hybridization, electron-pair geometry, and approximate bond angle (90, 109, 120, or 180) relative to: (6pt) electron-pair bond electron-pair bond hybridization geometry angle hybridization geometry angle O-1 C-5 C-2 N-7 C-3 O-9 5. Assign any formal charges to any apropriate atoms for proline, given the structure shown (one of the body's 20 monomers from which protein and enzyme biopolymers are constructred). (3pt) HON

OH 1 2 3 4 5 6 7 8 9 NH 2 O O3Answers, Test 1 Version 11. Want normal bonding for all

2. C=O (or C=C in other cases) may help

3. If you have any formal charges (not here), they must sum

to net charge of molecule (zero, in this case)

4. Organization must match condensed formula sequence1. The Nitrogen is tetrahedral, so the N-H hydrogen must

either be wedged or hashed. (The lone pair doesn't need to be drawn in, but it impacts the shape of the nitrogen)

2. Drawing the correct Lewis structure is essential! Do fifirst!Fine if N-H is hashed

instead of wedgedTTT

2 2 6. Rank the acidity of the following, from 1 (most) to 4 (least). (4pt) 7. Which of the following represent pairs of resonance structures? (4pt) d. Both a and c e. a, b, and c are all resonance structures. 8. Draw arrows to show electron-movement in the following two steps (draw arrows for each step). Draw a circle around the atom that functions as nucleophile in step 1, and a square around the atom that functions as nucleophile in step 2. (5pt) 9. Rank the series on the basis of boiling point, 1 having highest boiling point, 3 having lowest. (3pt) 10. Rank the series on the basis of water solubility, 1 having highest solubility, 3 having lowest. (3pt) OHOH

N H O a.b. OCH3OCH3BrBrc.OOOBrBrOHOHBr+ OHStep 1(anion)Step 2+OOHOHOH43 Acidity Factors:

1. charge (not relevant here)

2. Eneg

3. ResonanceNo atoms can move!Explain change in:

1. Bonds

2. Charge

3. Lone Pairs3 factors:

1. H-bonding

2. London force (# of carbons)

-both RAISE BP

3. Polar vs nonpolar2 factors:

1. H-bonding (raises solubility)

2. London force (# of carbons)

-more C's reduces water solubilityH-bonding No H-bonding No

Non-polar H-bonding YesH-bonding YesH-bonding No

Polar YesH-bonding Yes

3 3 11. For each of the following pairs of resonance structures, circle the one that would make a greater contribution to the actual resonance hybrid. (4pt) 12. Cyclopropane is much more "strained" than cyclopentane. Why? (Short!) (3pt) 13. For the following acid-base reaction, a. put a box around the weakest base in the reaction b. put a circle around the weakest acid c. draw an arrow to show whether the equilbrium goes to the right or left. (4pt) 14. Classify the relationship between the pairs of molecules as either: (8pt) same compound structural isomers resonance structures geometric isomers not isomers (different molecular formulas) OCH3OCH3OO(anions)ONaO+ H2OOHO+ NaOHOH

OH CH 3 H H CH 3 H H CH 3 H H H H CH 3 Br H OH H Br H H

OH52 Factors:

1. More bonds

(priority)

2. Electronegativity

(if bonds are equal)Angle strain. Bonds are forced to be 60º, far from the ideal ~109º angle. Note: angle strain only appears in certain rings; For acyclics, steric and torsional are the only strains available. Base Stability factors:

1. charge

2. eneg

3. resonance

1. Equilibrium favors the more stable base

2. More stable base is "weaker" base

3. "Weaker" acid + base on same side

4 4 15. Give the name for the following. (7pt) 16. Identify all the funtional groups in the following molecules. (Do not include "alkane", since that isn't "functional".) (6pt) 17. Which of the following pair will have the larger rotation barrier, relative to the bonds indicated? (3pt) 18. For the following Newman projections, rank them in stability from 1 to 4, 1 being most stable. Identify the "anti" conformation, the "gauche" conformation, and the "totally eclipsed" conformation. (6pt) 19. Draw the Newman projection for the most stable conformation of 1,2-dichloroethane. (3pt) H

CH 3 H ON O OH OOCH 3 H H CH 3H H CH 3 H H H H CH 3 H 3 C H H H H CH 3 H 3 C H H H 3 C H

H6TTT1. cis/trans for di-subbed rings

2. Alphabetize substituents

3. Numbering

4. Know isopropyl and t-butyl1. Longest chain

2. Alphabetize substituents

3. Number from end near

substituentcis-1-isopropyl-3-methylcyclohexane4-ethyl-3-methylheptaneBest: staggered and "anti"Worst: Totally eclipsed

5 5 20. Draw the two chair conformations of cis-1-ethyl-4-methylcyclohexane. (You don't have to draw all the hydrogens). (5pt) 21. W hich is more stable, cis- or tra ns-1-t-butyl-2-methylcyclohexane? Draw the best conformation of the more stable isomer. (4pt) 22. Draw as many structural isomers as you can for C6H14. Be careful not to draw the same isomer twice! I will take off points for duplicating! (6pt) 7TTT1. Make sure you've really

drawn "flflipped" chairs

2. What's "ax" in one chair flflip is

"eq" in the other.

3. Process cis-trans

4. Draw in H's on substituted

carbons (easier to see ax/eq).1. More stable chair has both substituents equatorial

2. Process cis-transAlkane Acyclic: C

n H 2n+2

Alkane Cyclic: C

n H 2n

Beware of drawing same

thing twice! 8

1 JASPERSE CHEM 350 TEST 1 VERSION 2 Organic Chemistry I - Jasperse Intro and Review Structure and Properties of Organic Molecules Structure, Nomenclature, and Conformation/Stereochemistry of Alkanes 1. Draw the correct Lewis structure of CH3CO2CH2COCH3. (Needn't show 3-D geometry) (3pt) 2. Draw a 3-dimensional picture for the atoms in CH3CH2CHCHCH2NHCH2CHO, using the hash-wedge convention. (You needn't specify lone pairs, and orbitals need not be shown). (5pt) 3. For the structure shown, what is the hybridization, electron-pair geometry, and approximate bond angle (90, 109, 120, or 180) relative to: (7pt, 2 points off for each error) electron-pair bond electron-pair bond hybridization geometry angle hybridization geometry angle C-1 C-4 O-2 N-5 C-3 C-6 4. Assign any formal charges to any appropriate atoms for the structure shown below. (4pt) 123456ONOHOONCH3CH3HO9TTT1. Want normal bonding for all

2. C=O (or C=C in other cases) may help

3. If you have any formal charges (not here), they must sum

to net charge of molecule (zero, in this case)

4. Organization must match condensed formula sequence1. The Nitrogen is tetrahedral, so the N-H hydrogen must either be wedged or hashed.

(The lone pair doesn't need to be drawn in, but it impacts the shape of the nitrogen)

2. Drawing the correct Lewis structure is essential! Do fifirst!Fine if N-H is hashed

instead of wedgedAnswers, Test 1 Version 2

2 5. Rank the acidity of the following, from 1 (most) to 4 (least). (4pt) 6. For the following pairs, identify as "isomers" ("I") or "resonance structures" ("R"). (6pt) 7. Draw arrows to show electron-movement in the following reactions. (These are reactions, not resonance.) (5pt) a. b. 8. Rank the series on the basis of boiling point, 1 having highest boiling point, 3 having lowest. (3pt) 9. Rank the series on the basis of water solubility, 1 having highest solubility, 3 having lowest. (3pt) NH2OHHOOOHOHOOOBrO+Br+O+HHOOHOHNH2NH2OHOH10TTT3 Acidity Factors:

1. charge (not relevant here)

2. Eneg

3. ResonanceNo atoms can move!Explain change in:

1. Bonds

2. Charge

3. Lone Pairs2 factors:

1. H-bonding

2. London force (# of carbons)

-both RAISE BP2 factors:

1. H-bonding (raises solubility)

2. London force (# of carbons)

-more C's reduces water solubility2 factors:

1. H-bonding

2. London force (# of carbons)

-both RAISE BPH-bonding No H-bonding YesExtra C's reduce solubility

3 10. Circle whichever of the following could fit the formula C5H10? (3pt) 11. For the following acid-base reaction, a. put a box around the weakest base in the reaction b. put a circle around the weakest acid c. draw an arrow to show whether the equilibrium goes to the right or left. (4pt) 12. Classify the relationship between each pair of molecules as either: (10 pt) same compound structural isomers resonance structures stereoisomers OHNHNa+OONaNH2+OH3COH3COiPrCH3HCH3HHiPrHHCH2CH3HHBrHBrHBrHBrHHNHN11TTTBase Stability factors:

1. charge

2. eneg

3. resonance

1. Equilibrium favors the more stable base

2. More stable base is "weaker" base

3. "Weaker" acid + base on same sideAlkane Acyclic: C

n H 2n+2

Alkane Cyclic: C

n H 2n

Alkene: C

n H 2n (not expected to remember, but evident if you count)

Counting H's can always double-check on this!

4 14. Give the name for the following. (7pt) 15. 16. Identify and write down the names for each of the functional groups in each of the following molecules. (Do not include "alkane", since that isn't "functional".) For each molecule, try to write the names in order, as they appear from left-to-right in the molecules. (8pt) 17. Circle which of the following pair will have the larger rotation barrier, relative to the bonds indicated? (2pt) Identify which reason explains why: steric strain, torsional strain, or angle strain? 18. For the following Newman projections: (6pt total) a. rank them in stability from 1 to 4, 1 being most stable b. identify the "anti", "gauche", and the "totally eclipsed" conformations. c. Is the energy difference between the gauche and the anti conformation based on steric strain, torsional strain, or angle strain? d. In the case of ethane (not shown), staggered conformations are better than eclipsed conformations. Is the difference based on steric strain, torsional strain, or angle strain? 19. Draw both the most stable and the least stable Newman projections for 1-bromopropane, BrCH2CH2CH3, relative to C1-C2 bond. - (3pt) HHHNH2OONHOOOOHCH2CH3HHHHH3CCH2CH3HHCH3HHHH3CH2CHCH3HHHH3CH2CHHHH3C12TTT5-ethyl-3-methyloctanetrans-1-butyl-3-isopropylcyclopentane1. Longest chain

2. Alphabetize substituents

3. Number from end near

substituent1. cis/trans for di-subbed rings

2. Alphabetize substituents

3. Numbering

4. Know isopropyl and t-butylGreater steric strain when totally eclipsed.

(Both will have equal torsional strain when totally eclipsed.)Best: staggered and "anti"Worst: Totally eclipsed

5 20. Which of the following are correct Lewis structures, including formal charges, for nitric acid, HNO3. (3 pts) 21. a. A only b. B only c. C only d. Both A and C e. All of the above 22. Draw the two chair conformations of cis-1-isopropyl-4-methylcyclohexane. (You don't have to draw all the hydrogens). (5pt) (Use "iPr" as abbreviation). 23. Draw the best chair conformation of the more stable isomer. Which is more stable, cis- or trans-1-butyl-2-methylcyclohexane? (4pt) 24. Draw any 6 of the 9 possible structural isomers for alkanes with formula C7H16. When deciding whether to draw cyclic or acyclic alkanes, make sure that you fit the formula! Be careful not to draw the same isomer twice! I will take off points for duplicating! (You can try to show off by getting more than 6, but if you do still be sure you don't duplicate!) (6pt) NOOOHNOOONOOOHHABC13TTT1. Do not exceed octet

2. If formal charges, must sum to net charge

3. As much "normal bonding" as possible, given

the above constraints.1. Make sure you've really drawn "flflipped" chairs

2. What's "ax" in one chair flflip is "eq" in

the other.

3. Process cis-trans

4. Draw in H's on substituted carbons

(easier to see ax/eq).1. More stable chair has both substituents equatorial

2. Process cis-transAlkane Acyclic: C

n H 2n+2

Alkane Cyclic: C

n H 2n

Beware of drawing same

thing twice! 14

1 1 JASPERSE CHEM 350 TEST 1 VERSION 3 Organic Chemistry I - Jasperse Intro and Review Structure and Properties of Organic Molecules Structure, Nomenclature, and Conformation/Stereochemistry of Alkanes 1. (12 points) Give the relationship between the following pairs of structures. The possible relationships are the following: same compound structural isomers resonance structures stereo isomers not isomers (different molecular formula) 2. (8 points) Draw line-angle structures and names for 4 of the 5 structural isomers of C6H14. Br

Br H Br H Br H H a. CC BrH BrH HHCC HH BrBr HH b. Br

Brc. d.

e. f.15Answers, Test 1 Version 31. Resonance: No atoms can move!

2. Stereo: same

condensed formula

3. Structural: different

condensed formulaAlkane Acyclic: C n H 2n+2

Alkane Cyclic: C

n H 2n

Beware of drawing same

thing twice!TTTStructural.

1,2-dibromo vs

1,3-dibromo.Same.

Bond rotation around

quotesdbs_dbs12.pdfusesText_18
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