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UNIVERSITÉ DE STRASBOURG

ÉCOLE DOCTORALE des Sciences Chimiques

[ UMR 7006 ]

THÈSE présentée par :

[ Ye WANG ] soutenue le : 10 Juin 2021 pour obtenir le grade de : Docteur de l"université de Strasbourg

Discipline/ Spécialité : Chimie Physique

Science moléculaire et matériaux bi-

dimensionnels : Système hybride pour opto

électroniques

THÈSE dirigée par : Prof. SAMORI Paolo Professeur, Université de Strasbourg, Strasbourg ; France

RAPPORTEURS : Prof. PALERMO Vincenzo Professeur, Institute for Organic Synthesis and Photoreactivity,

CNR Italie, Bologne, Italie

Prof. BRATINA Gvido

AUTRES MEMBRES DU JURY :

Prof. ERSEN Ovidiu Professeur, Institut de Physique et Chimie des Matériaux de

Strasbourg (IPCMS), Strasbourg, France

Be less curious about people

and more curious about ideas."

Marie Sklodowska Curie

To my parents

Résumé de Thèse

Le 1 13 Le 3 6 ĝP 3 5 11 3 5 Le 5 ) Abstract of Thesis 10 13 6 3 5 11 5 unfolded

References

1 3 5 6 8 XV

Symbols and Abbreviations

Symbols

Symbols English Français

°C C e A- J J 0 L 0 C XVI p 0

A ̵

A-

A ̵

XVII

A ̵

G XVIII

Abbreviations

Abbrevitions English Français

1 1 1 3 - 3- 3- XIX G ʹO 3 XX PL

P- P-

R XXI

List of Figures and Tables

Figure 2.1:

Figure 3.1: ͷ

Figure 3.3:

Figure 3.4:

d

Figure 3.7:

Figure 3.7:

Figure 3.8:

Figure 3.9: -ȋȌȋȌ

Figure 3.10:

Figure 3.11: ȋȌ-

XXII

Figure 4.1: -Ȁ

Figure 4.2:

Figure 4.4: ǡ-

Figure 4.7: -

Figure 4.10:

Figure 4.13:

Figure 4.14:

Figure 4.16:

Figure 4.17:

Figure 4.20: ǡ

Figure 4.22:

Figure 4.23:

Figure 4.25: -ʹ

Scheme 5.1: ǡ-ǡ-ǡͳǡ͵-

Table 5.1:

Figure 5.1:

Figure 5.2ǣ

XXIII

Figure 5.3. ʹ ͹ͺ

Figure 5.4: -

Figure 5.5: ǡȀ Ȁ

Figure 5.8:

Figure 5.9:

Figure 5.6:

Figure 5.7:

Figure 5.10:

Table 5.2: ȋȁȁȌ

Figure 5.11:

Table 5.3:

Figure 5.12: ȋȌȋͳǡ͵-Ȍ

Figure 5.13:

Figure 5.14:

Figure 5.15:

Figure 5.16

Figure 5.17:

Figure 5.18:

Figure 5.19

Figure 6.1: --

Figure 6.2:

XXIV

Figure 6.3:

Figure 6.4: ȋ

Figure 6.4 (continued): ȋ

Table 6.2:

Figure 6.5:

Figure 6.6: ȋȌ

Figure 6.7:

Table 6.4: δͳ

Figure 6.10: -

Figure 6.11: -

Figure 7.3:

Figure 7.5: ȋȌ-

Figure 7.6:

Figure 7.8: ͳ

Figure 7.9: Ȁ

XXV

Figure 7.10: -͵ΨȀ

Figure 7.11:

Figure 7.12:

Table 7.1: ǡǡ

Figure 7.13:

Figure 7.17:

Figure 7.18:

Figure 7.20:

Figure 7.21: ͵ͲͲ͸ͻͲ

Figure 7.23:

Figure 7.24:

Figure 7.25

Table 7.2: ߬

Figure 7.28: --Ȁ-

Figure 7.30:

XXVI

Figure 7.33:

5000Ȁ

Figure 7.34:

D* Ȁ-

Figure 7.35: ͵͸ͷ

Figure 7.39:

Figure 7.40: -

Figure 7.41:

Figure 7.42:

Figure 7.43: -Ȁ

ʹ Ȁ=0

Figure 7.44: -Ȁ

=0 αͳ

Figure 7.46:

Figure 7.47:

Figure 7.48: -ȀȀ-ȀȀ-Ȁ

Figure 7.49: Ȁ-

Figure 7.50: ͵ͲͲ͸ͻͲ

Figure 7.51: ͷȀ

Scheme 8.1. - -

Figure 8.1:

Figure 8.2: ͵ʹ

Figure 8.3:

Figure 8.4:

Figure 8.5:

XXVII

Figure 8.6: ʹ

Figure 8.7.

Figure 8.8:

Figure 8.9:

Figure 8.10:

Figure 8.11:

Figure 8.12:

Table 8.1:

Figure 8.13

Figure 8.14:

Figure 8.14:

Figure 8.16:

Table 8.2:

Figure 8.17:

Figure 8.18:

1ʹ

Figure 9.3:

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