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5-13-09

Material Safety Data Sheet

Dry Ice

Identity: Carbon Dioxide - Solid

General Information

Date MSDS Prepared: May 13, 2009 Haz Mat Identification System Safety Data Review Date: May 13, 2012 H 1

Company Identification: F 0

Continental Carbonic Products, Inc. R 1

3985 East Harrison Avenue PPE B

Decatur, IL 62526

800-DRY ICE2

Ingredients/Identity Information

CAS# Chemical Name Percent EINECS/ELINCS

124-38-9 Carbon Dioxide 100

Proprietary:

No

NIOSH (RTECS) Number: FF6400000

Exposure Limits:

Carbon Dioxide:

5000 ppm (9000 mg/m3) OSHA TWA

5000 ppm (9000 mg/m3) ACGIH TWA: 30,000 ppm (54,000 mg/me) ACGIH STREL

5000 ppm (9000 mg/m3) NIOSH recommended 10 hour TWA:

30,000 ppm (54,000 mg/m3) NIOSH recommended STEL

5000 ppm (9000 mg/m3) DFG MAK TWA:

10,000 ppm (18,000 mg/m3) DFG MAK 60 minute peak, momentary value

Measurement method: Gas collection bag: Gas chromatography with thermal conductivity Detector: (NIOSH III #S2491)

Physical/Chemical Characteristics

Appearance and Odor: colorless, odorless to slightly pungent

Boiling Point: -109.4 F

Melting Point:

-109.3 F Vapor Pressure (MM hg/70F): 831 PSIA

Solubility In Water: APPRECIABLE

Fire Fighting Measures

FLASH POINT (test method): Not applicable AUTOIGNITION TEMPERATURE Not applicable FLAMMABLE LIMITS IN AIR, % by volume LOWER: Not applicable UPPER: Not applicable

EXTINGUISHING MEDIA: Carbon dioxide cannot catch fire: Use media appropriate for surrounding fire SPECIAL FIRE FIGHTING PROCEDURES: WARNING! Frozen carbon dioxide - extremely cold

solid. Vapor can cause rapid suffocation. Evacuate all personnel from danger area. Do not discharge sprays

onto solid carbon dioxide. Solid carbon dioxide will freeze water rapidly. Never handle solid carbon dioxide with your

bare hands. Use insulated, loose-fitting gloves and dry ice tongs, or use a dry shovel or scoop. Move packages away

from fire area if without risk. Self-contained breathing apparatus may be required by rescue workers. On-site fire

brigades must comply with OSHA 29 CFR 1910.156.

5-13-09

UNUSUAL FIRE AND EXPLOSION HAZARDS:

None Known

HAZARDOUS COMBUSTION PRODUCTS: Not applicable. Thermal decomposition releases carbon monoxide and oxygen.

Reactivity Data

Dry ice sublimes; if confined in a gas tight container, it will build up a pressure of 850 psig at

70º F. Do not put dry ice in an airtight container or confined space

Stability: Yes

Conditions To Avoid (Stability): Moisture

Materials to Avoid: Carbonic acid/salt/corrosive chemicals

Hazardous Polymerization Occurrence: No

Health Hazard Data

Route of Entry-Inhalation: Yes

Route of Entry-Skin: No

Route of entry-Ingestion:

No Health Hazard Acute and Chronic: Concentration in excess of 1.5% carbon dioxide may cause death. At higher concentrations, displaces oxygen in air below levels necessary to support life.

Carcinogenicity-NTP:

No

Carcinogenicity-IARC:

No

Carcinogenicity-OSHA: No

Explanation Carcinogenicity: None

Signs/Symptoms of Overexposure:

At concentrations 1.5%: Hyperventilation/headaches/ dyspnea/perspiration. At 6-10%: Headaches/dyspnea/perspiration, tremors, visual disturbances.

10%: Unconsciousness without warning. Cryogenic burns.

Emergency/first Aid Procedures: Inhalation: Remove to fresh air. Assisted respirant and supplemental

oxygen should be given if not breathing. Frozen tissues should be flooded/soaked with tepid water. Don't

use hot water. Obtain medical attention in all cases.

Precautions for Safe Handling and Use

Steps if Material Released/Spill: Ventilate indoor areas well to avoid hazardous CO 2 concentrations. Ventilate area well and avoid contact with cold vapors/dry ice. CO 2 is heavy gas and will remain in low spots without assisted ventilation. Special Precautions for Handling of Solid Carbon Dioxide:

Do not handle solid Carbon Dioxide with

bare hands. Use heavy gloves, dry ice tongs or plastic scoop or shovel. Handle blocks of dry ice carefully,

as injuries can occur if one is accidentally dropped on the feet. Containers of solid Carbon Dioxide should

be stored upright and be firmly secured to prevent falling or being knocked over. Containers should be

vented, to prevent the build-up of Carbon Dioxide gas. Carbon Dioxide sublimates at -78.5ºC (-109.3ºF);

containers should be thermally insulated and kept at the lowest possible temperature to maintain the solid and

avoid generation of Carbon Dioxide gas. Storage containers and equipment used with Carbon Dioxide should not be located in sub-surface or enclosed areas , unless engineered to maintain a concentration of

Carbon Dioxide below the TLV (TLV=5000 ppm) in the event of a release. Solid consignment of dry ice in

a gas-tight vessel can lead to catastrophic failure of the vessel by over-pressurization. Storage of dry ice

should never occur in a gas-tight container.

5-13-09

Control Measures

Respiratory Protection: SCBA in oxygen deficient atmospheres where CO 2

1.5%. Do not use air

purifying respirators.

Ventilation:

Local Exhaust: At point sources of CO

2 vapors. Mechanical (general): Low lying area are not naturally ventilated.

Protective Gloves:

Impermeable/loose fitting (leather)

Eye Protection: Safety glasses

Transportation Data

Shipping information: Packages should be transported in a secure position in a well ventilated vehicle.

Product transported in an enclosed, non ventilated compartment of a vehicle can present serious safety

hazards.

Disposal Data

WASTE DISPOSAL METHOD: Place outside in a protected area with good ventilation and allow to

sublime. Prevent waste from contaminating the surrounding environment. Keep personnel away. Discard

any product, residue, disposable container, or liner in an environmentally acceptable manner, in full

compliance with federal, state and local regulations. If necessary, call your local supplier for assistance

Label Data

Label Required: Yes

Technical Review Date: September 1, 2004

Label Date: September 1, 2004

Common Name: Solid Carbon Dioxide/Dry Ice

Chronic Hazard: Yes

Acute Health Hazard-

Severe

Contact Hazard-Slight

Fire Hazard- Minimal

Reactivity Hazard-None

Special Hazard Precautions: Concentration in excess of 1.5% carbon dioxide may cause death. At higher

concentrations, displaces oxygen in air below levels necessary to support life.

Target organs: Respiratory system, skin

Protect Eye: Y

Protect Skin

: Y

Protect Respiratory

: Y

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier

nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information

contained herein.

Final determination or suitability of any material is the sole responsibility of the user. All materials may present

unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee

that these are the only hazards that exist.quotesdbs_dbs5.pdfusesText_10