Chapter 5 Carboxylic Acids and Esters
Learn the important physical properties of the carboxylic acids and esters. • Learn the major chemical reaction of carboxylic acids and esters and learn
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Chapter 5 Carboxylic Acids and Esters
Learn the important physical properties of the carboxylic acids and esters. •. Learn the major chemical reaction of carboxylic acids and esters
Chapter 5 Carboxylic Acids and Esters
Mr. Kevin A. Boudreaux
Angelo State University
CHEM 2353 Fundamentals of Organic Chemistry
Organic and Biochemistry for Today (Seager & Slabaugh) www.angelo.edu/faculty/kboudreaChapter Objectives:
•Learn to recognize the carboxylic acid, ester, and related functional groups. •Learn the IUPAC system for naming carboxylic acids and esters. •Learn the important physical properties of the carboxylic acids and esters. •Learn the major chemical reaction of carboxylic acids and esters, and learn how to predict the products of ester synthesis and hydrolysis reactions. •Learn some of the important properties of condensation polymers, especially the polyesters.Chapter 5Carboxylic Acids and Esters2
Carboxylic Acids
•Carboxylic acids are weak organic acids which contain the carboxyl group (RCO 2 H): • The tart flavor of sour-tasting foods is often caused by the presence of carboxylic acids. RCOH a carboxylic acid O C O O H the carboxyl group COHORCOOH RCO
2 H condensed ways of writing the carboxyl group 3Nomenclature of
Carboxylic Acids
4Nomenclature of Carboxylic Acids
• Select the longest carbon chain containing the carboxyl group. The -eending of the parent alkane name is replaced by the suffix -oic acid.
• The carboxyl carbon is always numbered "1" but the number is not included in the name. • Name the substituents attached to the chain in the usual way. • Aromatic carboxylic acids (i.e., with a CO2 H directly connected to a benzene ring) are named after the parent compound, benzoic acid. C OHOBenzoic acid
5Examples: Naming Carboxylic Acids
• Name the following compounds:HCOHOCH 3 COHO CH 3 CH 2COHOCCH
2 CH 2 CH 3 HOO 6Examples: Naming Carboxylic Acids
• Name the following compounds:CH 3 CHCH 2 COHB rO CH 3 CHCH 2 COH CH 2 CH 2 CH 3 CH 3 O COHO CH 3 CH 2 CHCH 3Chapter 5 Carboxylic Acids and Esters
7Examples: Naming Carboxylic Acids
• Name the following compounds: CH 3 CCH 3 COHO CH 2 CH 2 CHCH 3 CH 3CH C OHOCH
3 8Examples: Naming Carboxylic Acids
• Name the following compounds: COHO CH 3 CH 3 CO 2 H Cl CO OH CH 3 CHCH 3 9More Complicated Acids
• For molecules with two carboxylic acid groups the carbon chain in between the two carboxyl groups (including the carboxyl carbons) is used as the longest chain; the suffix -dioic acidis used.
• For molecules with more than two carboxylic acid groups, the carboxyl groups are named as carboxylic acid substituents.
CO HO CO OH ethanedioic acid CCH 2 CO HOO OH propanedioic acid CHCH 2 CH 2 CO CO COOHOHHO
propane-1,2,3-tricarboxylic acid 10Examples: Drawing Carboxylic Acids
• Draw structural formulas for the following molecules: - 2-methylpropanoic acid - 2,2,5-trimethylhexanoic acid - 4,5-dimethyl-3-nitrooctanoic acid 11Examples: Drawing Carboxylic Acids
• Draw structural formulas for the following molecules: -para-bromobenzoic acid - 2,4,6-trinitrobenzoic acid - 4-ethylpentanedioic acid (what's wrong with this name?) 12Chapter 5 Carboxylic Acids and Esters
13Physical Properties of
Carboxylic Acids
14Physical Properties of Carboxylic Acids
• Carboxylic acids hydrogen bond to themselves to form a dimer: RC OO H RCOH O RC OO H HOH OH H • Carboxylic acids also form hydrogen bonds towater molecules: 15Physical Properties of Carboxylic Acids
• Since carboxylic acids can form more than one set of hydrogen bonds, their boiling points are usually higher than those of other molecules of the same molecular weight (MW).
• Low-MW carboxylic acids are generally liquids at room temp. (often, they are somewhat oily); higher-MW carboxylic acids are generally waxy solids.
• Carboxylic acids with 12 to 20 carbon atoms are often referred to as fatty acids, since they are found in the triglycerides in fats and oils (more later).
• Short-chain carboxylic acids are also generally more soluble in water than compounds of similar MW, since they can hydrogen bond to more than one water molecule.
16Physical Properties of Carboxylic Acids
• As the number of carbons in a carboxylic acid series becomes greater, the boiling point increases and the solubility in water decreases.
• Many carboxylic acids that are liquids at room temperature have characteristically sharp or unpleasant odors.
- Ethanoic acid/acetic acid is the main ingredient in vinegar. - Butanoic acid is partially responsible for the odor of locker rooms and unwashed socks. - Hexanoic acid is responsible for the odor of Limburger cheese.• Like most acids, carboxylic acids tend to have a sour taste (e.g., vinegar, citric acid, etc.)
17 Common NameStructural FormulaBP (°C)MP (°C)Solubility (g/100 mL H 2 O)Formic acid H - CO
2H 101 8 Infinite
Acetic acid CH
3 - CO 2H 118 17 Infinite
Propionic acid CH
3 CH 2 - CO 2H 141 -21 Infinite
Butyric acid CH
3 (CH 2quotesdbs_dbs9.pdfusesText_15[PDF] 5 components of fitness
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